(3-chlorobenzyloxy)triethylsilane | 51276-63-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-chlorobenzyloxy)triethylsilane
• 英文别名: (3-Chlorophenyl)methoxy-triethylsilane；(3-chlorophenyl)methoxy-triethylsilane
• CAS: 51276-63-2
• 化学式: C₁₃H₂₁ClOSi
• 分子量: 256.848
• InChiKey: CYQWFIVFKCKIOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.86
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三乙基硅烷 、 3-氯苯甲醇 在 Rh/AlO(OH) 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以88%的产率得到(3-chlorobenzyloxy)triethylsilane
  参考文献：
  名称：

  Silylation of primary alcohols with recyclable ruthenium catalyst and hydrosilanes

  摘要：

  The silylation of primary alcohols was achieved using hydrosilanes and a recyclable ruthenium catalyst without additives under mild conditions. Notably, this catalyst system is effective for the silylation of alcohols having haloaryl groups, which were intact during the silylation. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.119

文献信息

• Silylative Dimerization of Aromatic Aldehydes Catalyzed by a Thiolate-Bridged Diruthenium Complex
  作者：Hitoshi Shimada、Jing-Ping Qü、Hiroyuki Matsuzaka、Youichi Ishii、Masanobu Hidai

  DOI：10.1246/cl.1995.671

  日期：1995.8

  A cationic thiolate-bridged diruthenium complex [Cp*RuCl-(μ2-SPri)2RuCp*][OTf] (Cp* = η5-C5Me5, OTf = OSO2CF3) was found to be an efficient catalyst for the reaction of aromatic aldehydes with hydrosilanes in acetonitrile to give 1,2-diaryl-1,2-disiloxyethanes as the major products.

  一种阳离子硫醇桥联的双钌配合物 [Cp*RuCl-(μ2-SPri)2RuCp*][OTf]（Cp* = η5-C5Me5，OTf = OSO2CF3）被发现是一种高效催化剂，可以在乙腈中催化芳香醛与氢硅烷的反应，主要产物为1,2-二芳基-1,2-二硅氧烷乙烷。
• Hydrosilylation of carbonyl compounds catalysed by ruthenium complexes
  作者：C. Eaborn、K. Odell、A. Pidcock

  DOI：10.1016/s0022-328x(73)80022-1

  日期：1973.12
• Silylation of primary alcohols with recyclable ruthenium catalyst and hydrosilanes
  作者：Sungjin Kim、Min Serk Kwon、Jaiwook Park

  DOI：10.1016/j.tetlet.2010.06.119

  日期：2010.8

  The silylation of primary alcohols was achieved using hydrosilanes and a recyclable ruthenium catalyst without additives under mild conditions. Notably, this catalyst system is effective for the silylation of alcohols having haloaryl groups, which were intact during the silylation. (C) 2010 Elsevier Ltd. All rights reserved.