1,8-bisimidazolyl anthracene | 1276031-36-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,8-bisimidazolyl anthracene
• 英文别名: 1-(8-Imidazol-1-ylanthracen-1-yl)imidazole；1-(8-imidazol-1-ylanthracen-1-yl)imidazole
• CAS: 1276031-36-7
• 化学式: C₂₀H₁₄N₄
• 分子量: 310.358
• InChiKey: PTMZGTHUYAQPJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,8-bisimidazolyl anthracene 、 碘甲烷 以 乙腈 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Unique X-ray Sheet Structure of 1,8-Bis(imidazolium) Anthracene and Its Application as a Fluorescent Probe for DNA and DNase

  摘要：

  A new imidazolium anthracene derivative 1 was synthesized, and its unique X-ray crystal structure was examined. In aqueous solutions, probe 1 exhibited a selective fluorescent quenching effect only with DNA among various anions including the nucleotides investigated. This probe was further applied to monitor the activity of DNase.

  DOI：

  10.1021/ol103166q
• 作为产物：
  描述：

  咪唑 、 1,8-二溴蒽 在 copper(l) iodide 、 N,N-二乙基乙二胺 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 以17%的产率得到1,8-bisimidazolyl anthracene
  参考文献：
  名称：

  Unique X-ray Sheet Structure of 1,8-Bis(imidazolium) Anthracene and Its Application as a Fluorescent Probe for DNA and DNase

  摘要：

  A new imidazolium anthracene derivative 1 was synthesized, and its unique X-ray crystal structure was examined. In aqueous solutions, probe 1 exhibited a selective fluorescent quenching effect only with DNA among various anions including the nucleotides investigated. This probe was further applied to monitor the activity of DNase.

  DOI：

  10.1021/ol103166q

文献信息

• AIR-STABLE, BLUE LIGHT EMITTING CHEMICAL COMPOUNDS
  申请人：Hollis Thedford Keith

  公开号：US20120205554A1

  公开（公告）日：2012-08-16

  We report the synthesis and characterization of four novel CCC—NHC pincer platinum(II) and palladium(II) complexes, which adopt a distorted square planar configuration. These complexes emit bright blue light in the solid state under UV irradiation with emissions that are stable in ambient atmosphere (O2 and H2O) for extended periods. We also report the synthesis and characterization of CCC—NHC pincer ligand nickel complexes, and solid state fluorescence spectra have been collected for two of the complexes reported. X-ray structural analysis of a representative compound exhibits a distorted square planar geometry. Finally, we report the synthesis and characterization of CCC—NHC pincer ligand complexes for abnormal carbens, triazole, and BIA.

  我们报告了四种新型CCC-NHC钯（II）和铂（II）夹心配合物的合成和表征，这些配合物采用了畸变的正方形平面构型。这些配合物在固态下在紫外照射下发出明亮的蓝光，发射光谱在常温常压（氧气和水）环境下具有稳定性，并且持续时间较长。我们还报告了CCC-NHC夹心配体镍配合物的合成和表征，并且已经收集了两种配合物的固态荧光光谱。代表性化合物的X射线结构分析展示了畸变的正方形平面几何构型。最后，我们报告了CCC-NHC夹心配体配合物的合成和表征，其中包括异常碳、三唑和BIA。
• US9029804B2
  申请人：——

  公开号：US9029804B2

  公开（公告）日：2015-05-12
• [EN] AIR-STABLE, BLUE LIGHT EMITTING CHEMICAL COMPOUNDS<br/>[FR] COMPOSÉS CHIMIQUES STABLES À L'AIR, ÉMETTANT DE LA LUMIÈRE BLEUE
  申请人：UNIV MISSISSIPPI

  公开号：WO2011050003A2

  公开（公告）日：2011-04-28

  We report the synthesis and characterization of four novel CCC-NHC pincer platinum(II) and palladium(II) complexes, which adopt a distorted square planar configuration. These complexes emit bright blue light in the solid state under UV irradiation with emissions that are stable in ambient atmosphere (O2 and H2O) for extended periods. We also report the synthesis and characterization of CCC-NHC pincer ligand nickel complexes, and solid state fluorescence spectra have been collected for two of the complexes reported. X-ray structural analysis of a representative compound exhibits a distorted square planar geometry. Finally, we report the synthesis and characterization of CCC-NHC pincer ligand complexes for abnormal carbenes, triazole, and BIA.
• Unique X-ray Sheet Structure of 1,8-Bis(imidazolium) Anthracene and Its Application as a Fluorescent Probe for DNA and DNase
  作者：Ha Na Kim、Jisoo Lim、Han Na Lee、Ju-Woo Ryu、Min Jung Kim、Joohee Lee、Dong-Ung Lee、Youngmee Kim、Sung-Jin Kim、Kap Duk Lee、Hee-Seung Lee、Juyoung Yoon

  DOI：10.1021/ol103166q

  日期：2011.3.18

  A new imidazolium anthracene derivative 1 was synthesized, and its unique X-ray crystal structure was examined. In aqueous solutions, probe 1 exhibited a selective fluorescent quenching effect only with DNA among various anions including the nucleotides investigated. This probe was further applied to monitor the activity of DNase.