3-nitroperylene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-nitroperylene
• 英文别名: 2-Nitroperylene；2-nitroperylene
• 化学式: C₂₀H₁₁NO₂
• 分子量: 297.313
• InChiKey: VYNIKSMFVARLLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-nitroperylene 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 以95%的产率得到3-aminoperylene
  参考文献：
  名称：

  Immobilized Amino Aromatics for Solid-Phase Detection Using Imidazole-Mediated Bis(trichlorophenyl) Oxalate Chemiluminescence

  摘要：

  This investigation examines six amino polycyclic aromatic hydrocarbons, covalently immobilized onto nonporous and porous methacrylate, controlled-pore glass, and Merrifield (S-DVB) beads, for their suitability in solid phase peroxyoxalate chemiluminescence detection, The solid phase luminophores were packed in a now cell mounted adjacent to a photomultiplier tube, and the properties of the different reagents were evaluated by injecting aqueous hydrogen peroxide into a stream of premixed bis(trichlorophenyl) oxalate and imidazole in acetonitrile, The highest sensitivity was obtained with 3-aminoperylene and 3-aminofluoranthene, A high degree of functionalization as well as a large surface area of the support increased the efficiency, The porous methacrylate material was found to give better sensitivity and precision than a nonporous material of similar composition, In this respect, the porous methacrylate support was also superior to controlled-pore glass, although these materials gave similar detection limits. The microporous S-DVB copolymer with the same overall degree of functionalization as the porous methacrylate support showed a lower sensitivity, since its subsurface functionalization did not contribute to the efficiency.

  DOI：

  10.1021/ac00119a016