1-Acetyl-2-ethyl-1,2-dimethylhydrazin | 50599-39-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-Acetyl-2-ethyl-1,2-dimethylhydrazin
• 英文别名: N'-ethyl-N,N'-dimethylacetohydrazide
• CAS: 50599-39-8
• 化学式: C₆H₁₄N₂O
• 分子量: 130.19
• InChiKey: JIJCSZFESBBHHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,N'-Diacetyl-N,N'-dimethyl-hydrazin 在 硼烷 作用下， 以 四氢呋喃 为溶剂， 生成 1-Acetyl-2-ethyl-1,2-dimethylhydrazin
  参考文献：
  名称：

  Chemistry of hydrazides. X. The reduction of cyclic and acyclic hydrazides with diborane

  摘要：

  DOI：

  10.1021/jo00830a045

文献信息

• Process for modifying conjugated diene polymers
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0150479A2

  公开（公告）日：1985-08-07

  A process for modifying a polymer of a conjugated diene, which comprises reacting a polymer of a conjugated diene containing at least one metal selected from alkali metals and alkaline earth metals with a compound having a linkage of the following formula wherein X represents an oxygen or sulfur atom, in the molecule.

  一种改性共轭二烯聚合物的工艺，包括使含有至少一种选自碱金属和碱土金属的金属的共轭二烯聚合物与具有下式连接的化合物反应 其中 X 代表分子中的氧原子或硫原子。
• Tire tread composition
  申请人：BRIDGESTONE CORPORATION

  公开号：EP0572792A1

  公开（公告）日：1993-12-08

  The present invention relates to a composition comprising an elastomeric polymer functionally modified by a terminal group, and carbon black particles dispersed therein, with at least 10 percent by weight of said carbon black being oxidized carbon black.

  本发明涉及一种组合物，该组合物包含一种经末端基团功能改性的弹性聚合物，以及分散在其中的炭黑颗粒，按重量计，所述炭黑中至少有 10% 为氧化炭黑。
• A process for producing a diolefin polymer or copolymer and a rubber composition containing such a diolefin polymer or copolymer
  申请人：BRIDGESTONE CORPORATION

  公开号：EP0609010A2

  公开（公告）日：1994-08-03

  A process for producing a diolefin polymer or copolymer, comprising the steps of polymerizing 55-100 wt% of a conjugated diolefin with 0-45 wt% of an aromatic vinyl compound as monomers in a hydrocarbon as a solvent, by using initiators: a reaction product [a1] between at least one secondary amine compound (A) and an organic lithium compound and/or a lithium amide compound [a2] of the at least one secondary amine compound (A) as well as a reaction product [b1] between at least one alcohol (B) and an organic lithium compound and/or a lithium alkoxide compound of the at least one alcohol (B). A rubber composition containing not less than 30 wt% of such a diolefin polymer or copolymer with respect to an entire rubber component is also disclosed. This rubber composition exhibits excellent abrasion resistance, high tensile strength, steering stability and low rolling resistance, and is suitable for tires, particularly, as treads of low fuel consumption tires.

  一种生产二烯烃聚合物或共聚物的工艺，包括以下步骤：以烃类为溶剂，使用引发剂使 55-100 wt%的共轭二烯烃与 0-45 wt%的芳香乙烯基化合物作为单体聚合：至少一种仲胺化合物（A）与有机锂化合物和/或至少一种仲胺化合物（A）的锂酰胺化合物[a2]之间的反应产物[a1]，以及至少一种醇（B）与有机锂化合物和/或至少一种醇（B）的锂烷氧基化合物之间的反应产物[b1]。此外，还公开了一种橡胶组合物，其中二烯烃聚合物或共聚物的含量不低于整个橡胶组分的 30%。这种橡胶组合物具有优异的耐磨性、高拉伸强度、转向稳定性和低滚动阻力，适用于轮胎，特别是低油耗轮胎的胎面。
• Butadiene polymer, and process for producing conjugated diene polymer
  申请人：JAPAN as Represented by DIRECTOR GENERAL OF AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY

  公开号：EP1520862A2

  公开（公告）日：2005-04-06

  A coupled butadiene polymer composition is provided characterized by comprising: (i) 0 to 90 parts by weight of a polymer (I) which is a homopolymer of butadiene or a copolymer of butadiene witha monomer copolymerizable therewith, and has at least 50% by weight of butadiene units, and in which the content of butadiene units having a cis bond in the total butadiene units is at least 50%, the number average molecular weight (Mn) is in the range of 1, 000 to 10,000,000, and a relationship represented by the formula:log(Mw/Mn) < 0.162 × log(Mw) - 0.682 is satisfied between the weight average molecular weight (Mw) and the ratio (Mw/Mn); and (ii) 100 to 10 parts by weight of a polymer (II) composed of at least two molecules of the above-mentioned polymer (I), bonded through a coupling agent.

  提供了一种耦合丁二烯聚合物组合物 其特征是包括 (i) 0 至 90 份(重量)聚合物(I)，其为丁二烯均聚物或丁二烯与可与之共聚的单体的共聚物，且具有至少 50%(重量)的丁二烯单元，其中具有顺式键的丁二烯单元在丁二烯单元总量中的含量至少为 50%，数均分子量(Mn)在 1,000 至 10,000,000 之间，且由式:log(Mw/Mn)< 0.162 × log(Mw) - 0.682 的关系；以及 (ii) 100 至 10 重量份的聚合物 (II)，该聚合物 (II) 由至少两个上述聚合物 (I) 分子通过偶联剂结合而成。
• METHOD FOR PRODUCING RADIAL CONJUGATED DIENE POLYMER
  申请人：Zeon Corporation

  公开号：EP2431395A1

  公开（公告）日：2012-03-21

  An alkali metal-reacted aromatic compound which has three or more carbon atoms which are directly bonded to alkali metal atoms and aromatic rings in one molecule is used as a polymerization initiator to polymerize a monomer mixture which is contains at least one conjugated diene compound to thereby produce a radial conjugated diene polymer. Further, active ends of the polymer having active ends which is obtained by this method is made to react with a modifier which can react with the active ends to thereby produce an end-modified radial conjugated diene polymer. According to the present invention, it is possible to provide a method of production of the radial conjugated diene polymer which gives a high degree of freedom of polymer design and easy control of the polymer structure.

  碱金属反应的芳香族化合物在一个分子中具有三个或三个以上与碱金属原子和芳香环直接键合的碳原子，将其用作聚合引发剂，使含有至少一种共轭二烯化合物的单体混合物聚合，从而生成径向共轭二烯聚合物。此外，通过该方法得到的具有活性末端的聚合物的活性末端与改性剂反应，改性剂可与活性末端反应，从而生成末端改性的径向共轭二烯聚合物。根据本发明，有可能提供一种径向共轭二烯聚合物的生产方法，该方法可提供较高的聚合物设计自由度，并易于控制聚合物结构。