Benzenesulfonic acid, butyl- | 31093-97-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzenesulfonic acid, butyl-
• 英文别名: 2-butylbenzenesulfonic acid
• CAS: 31093-97-7
• 化学式: C₁₀H₁₄O₃S
• 分子量: 214.28
• InChiKey: QFNSAOSWJSCHID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  62.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Benzenesulfonic acid, butyl- 、 三氯氧磷 生成 butylbenzene-1-sulfonyl chloride
  参考文献：
  名称：

  CESARZ, KATHRIN;PRITZKOW, W.;UHLIG, CORNELLA;VOERCKEL, V., J. PRAKT. CHEM., 331,(1989) N, C. 1011-1013

  摘要：

  DOI：
• 作为产物：
  描述：

  丁苯 、 三氧化硫 、 硫酸 以9%的产率得到
  参考文献：
  名称：

  CESARZ, KATHRIN;PRITZKOW, W.;UHLIG, CORNELLA;VOERCKEL, V., J. PRAKT. CHEM., 331,(1989) N, C. 1011-1013

  摘要：

  DOI：

文献信息

• SULFONAMIDE-BASED ORGANOCATALYSTS AND METHOD FOR THEIR USE
  申请人：Carter Rich Garrett

  公开号：US20100184986A1

  公开（公告）日：2010-07-22

  Organocatalysts, particularly proline sulfonamide organocatalysts, having a first general formula as follows are disclosed. Embodiments of a method for using these organocatalysts also are disclosed. The method comprises providing a disclosed organocatalyst, and performing a reaction, often an enantioselective or diastereoselective reaction, using the organocatalyst. Solely by way of example, disclosed catalysts can be used to perform aldol reactions, conjugate additions, Michael additions, Robinson annulations, Mannich reactions, α-aminooxylations, α-hydroxyaminations, α-aminations and alkylation reactions. Certain of such reactions are intramolecular cyclizations used to form cyclic compounds, such as 5- or 6-membered rings, having one or more chiral centers. Disclosed organocatalysts generally are much more soluble in typical solvents used for organic synthesis than are known compounds. Moreover, the reaction yield is generally quite good with disclosed compounds, as is their enantioselective and diastereoselective effectiveness.

  披露了具有如下一般公式之一的有机催化剂，尤其是脯氨酸磺酰胺有机催化剂。还披露了使用这些有机催化剂的方法的实施例。该方法包括提供一种披露的有机催化剂，并使用该有机催化剂进行反应，通常是立体选择性的反应或对映选择性反应。仅作为示例，披露的催化剂可用于进行aldol反应、共轭加成、Michael加成、Robinson环化反应、Mannich反应、α-氨基氧化、α-羟基胺化、α-胺化和烷基化反应。其中一些反应是分子内环化反应，用于形成具有一个或多个手性中心的环状化合物，例如5或6元环。披露的有机催化剂通常比已知的化合物更容易溶于用于有机合成的典型溶剂中。此外，使用披露化合物的反应收率通常相当好，它们的对映选择性和非对映选择性效果也很好。
• NOVEL EPISULFIDE COMPOUND AND OPTICAL MATERIAL COMPOSITION CONTAINING SAME
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20170247351A1

  公开（公告）日：2017-08-31

  According to the present invention, it is possible to provide an optical material composition that contains an episulfide compound represented by formula (1) and an episulfide compound represented by formula (2). According to this optical material composition, it is possible to suppress a reduction in the yield rate caused by molding defects, and possible to obtain an optical material having excellent dyeability. (In formula (1), m and p are each an integer between 0 and 4, and n and q are each an integer between 0 and 2.) (In formula (2), m is an integer between 0 and 4 and n is an integer between 0 and 2.)

  根据本发明，可以提供一种含有由式（1）表示的环硫醚化合物和由式（2）表示的环硫醚化合物的光学材料组合物。根据这种光学材料组合物，可以抑制由成型缺陷引起的产率降低，并且可以获得具有优异染色性能的光学材料。（在式（1）中，m和p分别是介于0和4之间的整数，n和q分别是介于0和2之间的整数。）（在式（2）中，m是介于0和4之间的整数，n是介于0和2之间的整数。）
• Electrochromic device
  申请人：——

  公开号：US20030206326A1

  公开（公告）日：2003-11-06

  An electrochromic device comprising a pair of glass or plastic plates or plastic films of which at least one plate or film, preferably both plates or films, are provided on in each case one side with an electrically conductive coating, of which at least one plate or film and its conductive coating are transparent, of which the other may be mirrored, and of which in the case of at least one of the two plates or films the electrically conductive layer can be divided into separate, individually contacted area segments, where the plates or films are joined together via a sealing ring on the sides of their conductive coating, and the volume formed by the two plates or films and the sealing ring is filled with an electrochromic medium which comprises at least one reducible electrochromic substance OX 2 and at least one oxidizable electrochromic substance RED 1 , characterized in that one OX 2 corresponds to the formula 1 in which R 201 and R 202 , independently of one another, are alkyl, cycloalkyl, alkenyl, aralkyl, aryl, —[C(PQ)] − or a bivalent bridge B, Z 201 is a bivalent radical of the formulae CR 210 R 211 , O, C═O or o-phenylene, R 210 and R 211 , independently of one another, are hydrogen, methyl or ethyl, or CR 210 R 211 is C 3 - to C 7 -cycloalkane- 1,1 -diyl, the rings C, D, E and F, independently of one another, may be substituted by up to 4 alkyl and/or alkoxy radicals, or the rings C and D or the rings E and F, respectively, may be linked via a —(CH 2 ) 4 — or —CH═CH—CH═CH— bridge, P and Q, independently of one another, are —CN or —COO-alkyl, and X— is an anion, has improved properties and comprises electrochromic compounds which are readily obtainable synthetically.

  一种电致变色装置，包括一对玻璃或塑料板或塑料薄膜，其中至少一块板或膜，优选两块板或膜，在每一侧上都提供有一层电导涂层，其中至少一块板或膜及其导电涂层是透明的，另一块则可以是镜面的，在至少两块板或膜中的一块上，导电层可以被分成单独的、可分别接触的区域段，这些板或膜通过密封环在它们的导电涂层的侧面连接在一起，而由这两块板或膜和密封环形成的体积被充满了一种电致变色介质，其包括至少一种可还原电致变色物质OX2和至少一种可氧化电致变色物质RED1，其特征在于，其中一个OX2对应于公式1，其中R201和R202独立地为烷基、环烷基、烯基、芳基、-C（PQ）-或双价桥B的-Z201，R210和R211独立地为氢、甲基或乙基，或CR210R211为C3-C7环烷基-1,1-二基，环C、D、E和F独立地可以被多达4个烷基和/或烷氧基取代，或环C和D或环E和F可以通过-（CH2）4-或-CH2CH-CH2CH-CH-桥连接，P和Q独立地为-CN或-COO-烷基，X-为阴离子，具有改进的性能，并包括可通过合成轻松获得的电致变色化合物。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Substituted Benzo-Condensed Cycloheptanone Derivatives and the Use Thereof for Medicament Production
  申请人：Frank Robert

  公开号：US20080161352A1

  公开（公告）日：2008-07-03

  The invention relates to substituted benzo-condensed cyclohexanone derivatives, to a method for the production thereof, to medicaments containing said derivatives and to the use of the inventive compounds for producing medicaments.

  本发明涉及取代的苯并环己酮衍生物，其制备方法，含有该衍生物的药物以及将本发明化合物用于制备药物的用途。