[1-(4-乙氧基苯基)环丙基]甲醇 | 88934-81-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: [1-(4-乙氧基苯基)环丙基]甲醇
• 英文名称: 1-(4-Ethoxyphenyl)-1-hydroxymethylcyclopropane
• 英文别名: 1-(4'-ethoxyphenyl)cyclopropane-1-methanol；1-(4-ethoxyphenyl)cyclopropyl-1-carbinol；[1-(4-Ethoxyphenyl)cyclopropyl]methanol
• CAS: 88934-81-0
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.258
• InChiKey: SBQVQHUIRHTNFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-苄基-3-(溴甲基)苯 、 [1-(4-乙氧基苯基)环丙基]甲醇 在 sodium hydroxide 、 四正辛基溴化铵 作用下， 反应 3.0h， 以31%的产率得到1-(3-Benzylbenzyloxymethyl)-1-(4-ethoxyphenyl)cyclopropane
  参考文献：
  名称：

  The Pyrethrins and Related Compounds. Part XLI. Structure-Activity Relationships in Non-ester Pyrethroids against Resistant Strains of Housefly (Musca domesticaL.)

  摘要：

  DOI：

  10.1002/(sici)1096-9063(199610)48:2<175::aid-ps456>3.0.co;2-t
• 作为产物：
  描述：

  ethyl 2,2-dibromo-1-(4'-ethoxyphenyl)cyclopropane-1-carboxylate 在 lithium aluminium tetrahydride 、 三正丁基氢锡 作用下， 以 乙醚 、 Petroleum ether 为溶剂， 反应 4.0h， 生成 [1-(4-乙氧基苯基)环丙基]甲醇
  参考文献：
  名称：

  Johnson, Wynona M. P.; Holan, George; Jarvis, Karen E., Australian Journal of Chemistry, 1986, vol. 39, # 2, p. 271 - 280

  摘要：

  DOI：

文献信息

• Certain phenoxy-benzyloxy ether derivatives and an insecticidal and/or
  申请人：Sumitomo Chemical Company, Limited

  公开号：US04562213A1

  公开（公告）日：1985-12-31

  Ether compounds of the general formula, ##STR1## wherein W represents CH group or nitrogen atom, and (1) when W is the CH group, R.sub.1 represents hydrogen atom, fluorine atom, chlorine atom, bromine atom or methyl group, R.sub.2 represents hydrogen atom or fluorine atom, R.sub.3 and R.sub.4 are same or different and represent hydrogen atom, a halogen atom, a C.sub.1-4 alkyl, a C.sub.1-4 alkoxyl, difluoromethoxy or 2,2,2-trifluoroethoxy group, or represent, taken together, methylenedioxy group, A represents oxygen atom, methylene group or imino group, and when the A represents oxygen atom or methylene group, X and Y represent, taken together, ethylene group or 1,1-difluoroethylene group and when the A represents imino group, both X and Y represent methyl group or represent, taken together, ethylene group or 1,1-difluoroethylene group, and (2) when W is the nitrogen atom, both R.sub.1 and R.sub.2 represent hydrogen atom, R.sub.3 and R.sub.4 are as define above, A represents oxygen atom, and both X and Y represent methyl group or represent, taken together, ethylene group or 1,1-difluoroethylene group. The ether compounds of the present invention are useful as an active ingredient of an insecticidal and/or acaricidal composition.

  通用公式为##STR1##的醚化合物，其中W代表CH基团或氮原子，(1) 当W为CH基团时，R.sub.1代表氢原子、氟原子、氯原子、溴原子或甲基基团，R.sub.2代表氢原子或氟原子，R.sub.3和R.sub.4相同或不同，代表氢原子、卤素原子、C.sub.1-4烷基、C.sub.1-4烷氧基、二氟甲氧基或2,2,2-三氟乙氧基，或者代表一起取的亚甲二氧基基团，A代表氧原子、亚甲基团或亚胺基团，当A代表氧原子或亚甲基团时，X和Y代表一起取的乙烯基或1,1-二氟乙烯基，当A代表亚胺基团时，X和Y都代表甲基基团或一起取的乙烯基或1,1-二氟乙烯基，(2) 当W为氮原子时，R.sub.1和R.sub.2都代表氢原子，R.sub.3和R.sub.4如上定义，A代表氧原子，X和Y都代表甲基基团或一起取的乙烯基或1,1-二氟乙烯基。本发明的醚化合物可作为杀虫剂和/或杀螨剂组合物的活性成分。
• Ether compounds, their production and an insecticidal and/or acaricidal composition containing the same
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0094085A1

  公开（公告）日：1983-11-16

  Ether compounds of the general formula, wherein W represents methine group or nitrogen atom, and (1) when W is the methine group, R1 represents hydrogen atom, fluorine atom, chlorine atom, bromine atom or methyl group, R2 represents hydrogen atom or fluorine atom, R3 and R4 are same or different and represent hydrogen atom, a halogen atom, a C1-4 alkyl, a C1-4 alkoxyl, difluoromethoxy or 2,2,2-trifluoroethoxy group, or represent, taken together, methylenedioxy group, A represents I oxygen atom, methylene group or imino group, and when the A represents oxygen atom or methylene group, X and Y represent, taken together, ethylene group or 1,1-difluoroethylene group and when the A represents imino group, both X and Y represent methyl group or represent, taken together, ethylene j group or 1,1-difluoroethylene group, and (2) when W is the nitrogen atom, both R1 and R2 represent hydrogen atom, R3 and R4 are as defined above, A represents oxygen atom, and both X and Y represent methyl group or represent, taken together, ethylene group or 1,1-difluoroethylene group. The ether compounds of the present invention are useful as an active ingredient of an insecticidal and/or acaricidal composition.

  通式如下的醚化合物 其中 W 代表甲基或氮原子，(1) 当 W 为甲基时、 R1 代表氢原子、氟原子、氯原子、溴原子或甲基，R2 代表氢原子或氟原子，R3 和 R4 相同或不同并代表氢原子、卤素原子、C1-4 烷基、C1-4 烷氧基、二氟甲氧基或 2,2,2-三氟乙氧基，或共同代表亚甲二氧基，A 代表 I 氧原子、亚甲基或亚氨基，当 A 代表氧原子或亚甲基时，X 和 Y 代表、(2) 当 W 为氮原子时，R1 和 R2 均代表氢原子，R3 和 R4 如上定义，A 代表氧原子，X 和 Y 均代表甲基或代表乙烯基或 1，1-二氟乙烯基。 本发明的醚化合物可用作杀虫和/或杀螨剂组合物的活性成分。
• NISHIDA, SUMIO;MATSUO, NORITADA;TSUSHIMA, KAZUNORI;HATAKOSHI, MAKOTO;HIRA+
  作者：NISHIDA, SUMIO、MATSUO, NORITADA、TSUSHIMA, KAZUNORI、HATAKOSHI, MAKOTO、HIRA+

  DOI：——

  日期：——
• ARYLCYCLOALKYL ETHER DERIVATIVES, THEIR USE AND PREPARATION
  申请人：A/S CHEMINOVA

  公开号：EP0143806A1

  公开（公告）日：1985-06-12
• JPH04234829A
  申请人：——

  公开号：JPH04234829A

  公开（公告）日：1992-08-24