[2,3,4,5,6-五(羟甲基)苯基]甲醇 | 2715-91-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [2,3,4,5,6-五(羟甲基)苯基]甲醇
• 英文名称: hexa(hydroxymethyl)benzene
• 英文别名: HHMB；hexakis-hydroxymethyl-benzene；Hexakis-hydroxymethyl-benzol；[2,3,4,5,6-Pentakis(hydroxymethyl)phenyl]methanol
• CAS: 2715-91-5
• 化学式: C₁₂H₁₈O₆
• mdl: MFCD00182549
• 分子量: 258.271
• InChiKey: XPOHJXHLJGTWRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.4
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  121
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [2,3,4,5,6-五(羟甲基)苯基]甲醇 在 potassium permanganate 作用下， 生成 苯六甲酸
  参考文献：
  名称：

  Laparoscopic transperitoneal hernia repair of incarcerated hernias: Is it feasible?

  摘要：

  Background: Laparoscopic transperitoneal hernia repair (TAPP) has proved its efficiency in elective surgery. However, TAPP results with incarcerated hernias still are unknown.Methods: Data from a prospective study were evaluated with regard to TAPP repair for both chronically and acutely incarcerated hernias.Results: During a 6-year period, 220 incarcerated hernias were repaired (194 via TAPP). The median operation time for TAPP was 55 min. An accompanying resection therapy became necessary for only four of the emergency cases (11.1%) and two of the chronically incarcerated cases (1.3%) in the TAPP group. Postoperative morbidity was 2.8% in the emergency group and 3.8% in the chronically incarcerated group, which does not differ from the rate for TAPP used on reducible hernias. One recurrence was found 26 months after TAPP reconstruction (0.5%).Conclusion: Laparoscopic inguinal. hernia repair (TAPP) represents an efficient therapeutic concept in the treatment of both chronically and acutely incarcerated inguinal hernias.

  DOI：

  10.1007/s004640090073
• 作为产物：
  描述：

  丁炔二醇 在 (((3-hydroxypropyl)carbonylcyclopentadienyl)cobalt)-η⁴-cyclooctadiene 作用下， 以 甲醇 、 水 为溶剂， 生成 [2,3,4,5,6-五(羟甲基)苯基]甲醇
  参考文献：
  名称：

  钴催化炔烃在水溶液中的环三聚反应

  摘要：

  华盛顿州立大学化学系 P.O. Box 644630, Pullman, Washington 99164-4630NeXstar Pharmaceuticals, 2860 Wilderness PlaceBoulder, Colorado 80301 收到，1998 年 3 月 5 日许多用于组装环状有机分子的最有用的方法涉及过渡金属催化的环加成。由于芳环是许多生物、药物和聚合物分子的核心，因此炔烃环三聚是一种重要的方法。Vollhardt 是第一个意识到钴催化环三聚在有机合成中的潜力的人。

  DOI：

  10.1021/ja9807284

文献信息

• Flexible and rigid core molecules in the synthesis of poly(lactic acid) star polymers
  作者：Mitchell R. Perry、Michael P. Shaver

  DOI：10.1139/v11-002

  日期：2011.4

  This study presents the synthesis and physical characterization of a series of structurally well-defined star-shaped poly(lactic acids). Polymer stars are prepared from a series of multifunctional ...

  本研究介绍了一系列结构明确的星形聚乳酸的合成和物理表征。聚合物星是由一系列多功能...
• Radially multi-branched polymer and porous film using the same
  申请人：Cheong Ho Jae

  公开号：US20050182202A1

  公开（公告）日：2005-08-18

  Described is a radially multi-branched polymer represented by the following formula (I): ABi (I), which includes a central molecule (A) to which side-branches (B) are bonded in at least three positions (i≧3). Also described are methods for preparing a multi-branched polymer as well as a porous insulating film including a multi-branched polymer.

  所述径向多支链聚合物由下式（I）表示：ABi (I)，其中包括一个中心分子（A），侧支链（B）至少在三个位置（i≧3）上与之键合。此外，还描述了制备多支链聚合物以及包括多支链聚合物的多孔绝缘膜的方法。
• Hexamethyl benzene compounds
  申请人：GEN ANILINE &

  公开号：US02542417A1

  公开（公告）日：1951-02-20
• Backer, Recueil des Travaux Chimiques des Pays-Bas, 1935, vol. 54, p. 833,834
  作者：Backer

  DOI：——

  日期：——
• Backer, Recueil des Travaux Chimiques des Pays-Bas, 1936, vol. 55, p. 591
  作者：Backer

  DOI：——

  日期：——