[2,4-二(1,1-二甲基丙基)苯氧基]乙酰氯 | 88-34-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [2,4-二(1,1-二甲基丙基)苯氧基]乙酰氯
• 英文名称: 2,4-di(tert-pentyl)phenoxyacetyl chloride
• 英文别名: (2,4-di-tert-pentyl-phenoxy)-acetyl chloride；(2,4-Di-tert-pentyl-phenoxy)-acetylchlorid；(2,4-bis(1,1-dimethylpropyl)phenoxy)acetyl chloride；2-(2,4-di-t-amylphenoxy)acetyl chloride；2,4-Di-tert-amyl-phenoxy-essigsaeure-chlorid；Acetyl chloride, [2,4-bis(1,1-dimethylpropyl)phenoxy]-；2-[2,4-bis(2-methylbutan-2-yl)phenoxy]acetyl chloride
• CAS: 88-34-6
• 化学式: C₁₈H₂₇ClO₂
• 分子量: 310.864
• InChiKey: KSYTWDUNKAIFLK-UHFFFAOYSA-N

物化性质

• 沸点：
  143-146 °C(Press: 2.0 Torr)
• 密度：
  1.019±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2918990090

反应信息

• 作为反应物：
  描述：

  [2,4-二(1,1-二甲基丙基)苯氧基]乙酰氯 在 镍 氢气 、 sodium acetate 作用下， 以 乙醇 、 溶剂黄146 为溶剂， 生成 N-(3-氨基-4-氯苯基)-2-(2,4-二-叔-戊基苯氧基)乙酰胺
  参考文献：
  名称：

  DE1124356

  摘要：

  公开号：
• 作为产物：
  描述：

  2,4-二叔戊基苯酚 在 sodium hydroxide 、 氯化亚砜 作用下， 生成 [2,4-二(1,1-二甲基丙基)苯氧基]乙酰氯
  参考文献：
  名称：

  Diacylaminophenol couplers

  摘要：

  公开号：

  US02772162A1

文献信息

• Synthesis of 3-(3″-Aminobenzoylamido)-1-(2′,4′,6′-trichlorophenyl)pyrazol-5-one, an Intermediate in the Synthesis of the Purple Component of Color Photographic Materials
  作者：Yu. M. Yutilov、N. N. Smolyar、L. V. Minkina

  DOI：10.1007/s11167-005-0274-3

  日期：2005.2

  Catalytic reduction of 3-(3″-nitrobenzoylamido)-1-(2′,4′,6′-trichlorophenyl)pyrazol-5-one with hydrogen and hydrazine hydrate to 3-(3″-aminobenzoylamido)-1-(2′,4′,6′-trichlorophenyl)pyrazol-5-one, the key intermediate in the synthesis of the purple component of color photographic and motion-picture materials, was studied.

  用氢气和水合肼对3-(3″-硝基苯甲酰胺)-1-(2′,4′,6′-三氯苯基)吡唑-5-酮进行催化还原，以合成紫色成分的关键中间体3-(3″-氨基苯甲酰胺)-1-(2′,4′,6′-三氯苯基)吡唑-5-酮，该成分用于彩色摄影和电影材料的合成。
• Process for producing aromatic amide compounds
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05442114A1

  公开（公告）日：1995-08-15

  There is disclosed a process for producing an aromatic amide compound of the general formula (4), including the steps of subjecting an o-nitrophenol compound of the general formula (1) to catalytic reduction in acetone or an aromatic hydrocarbon solvent under the presence of a nickel catalyst to give an o-aminophenol compound of the general formula (2); and (b) subjecting the o-aminophenol compound of the general formula (2) to condensation with an acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) in acetone or an aromatic hydrocarbon solvent under an atmosphere of an inert gas having an oxygen concentration of 1% or less. The acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) may be obtained by allowing a carboxylic acid compound of the general formula (5) to react with thionyl chloride and by concentrating the reaction mixture. Also disclosed is another process for producing an aromatic amide compound of the general formula (4), including the step of subjecting an o-aminophenol hydrochloride salt of the general formula (6) to condensation with an acid chloride compound having a sulfur content of 0.8% or less, based on the weight of the acid chloride compound, of the general formula (3) in an inert solvent.

  本发明公开了一种生产通式（4）的芳香酰胺化合物的方法，包括以下步骤：将通式（1）的邻硝基酚化合物在丙酮或芳香烃溶剂中，在存在镍催化剂的条件下进行催化还原，得到通式（2）的邻氨基酚化合物；以及（b）将通式（2）的邻氨基酚化合物与含有硫含量不超过0.5%的酸氯化合物的通式（3）在丙酮或芳香烃溶剂中，在氧气浓度不超过1%的惰性气体氛围下，进行缩合反应。含有硫含量不超过0.5%的酸氯化合物的通式（3）可通过让通式（5）的羧酸化合物与亚砜氯反应，并浓缩反应混合物来获得。还公开了另一种生产通式（4）的芳香酰胺化合物的方法，包括以下步骤：将通式（6）的邻氨基酚盐酸盐与含有硫含量不超过0.8%的酸氯化合物的通式（3）在惰性溶剂中进行缩合反应。
• Color photographic light-sensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US03933500A1

  公开（公告）日：1976-01-20

  A color photographic silver halide light-sensitive material which comprises a support having thereon at least two light-sensitive layers, at least one of said layers containing a compound capable of coupling with an oxidation product of a color developing agent and in which splitable hetero aromatic ring containing a triazole or diazole ring is connected to the carbon atom in the coupling position, through the nitrogen atom in the 1-position of said triazole or diazole ring.

  一种彩色摄影银卤光敏材料，其包括至少两个光敏层的支撑体，其中至少一层含有一种化合物，该化合物能够与彩色显影剂的氧化产物偶联，其中可分裂的杂环芳香环包含三唑或二唑环，并通过1-位置的氮原子连接到偶联位置的碳原子上。
• Light-sensitive silver halide photographic materials
  申请人：Konishiroku Photo Industry Co., Ltd.

  公开号：US04200466A1

  公开（公告）日：1980-04-29

  A light-sensitive silver halide photographic material comprising a m-aminophenol type coupler of the structure particularly defined therein is disclosed, which can successfully yield an excellent image stable against oxidation.

  本发明揭示了一种光敏银卤化物摄影材料，其中包括一种特别定义的m-氨基酚型偶合剂结构，能够成功产生一种稳定抗氧化的优秀图像。
• Erysimum plant named ‘Balcherissam’
  申请人：Ball Horticultural Company

  公开号：USPP029379P2

  公开（公告）日：2018-06-12

  A new and distinct cultivar of Erysimum plant named ‘Balcherissam’, characterized by its medium yellow-orange and lavender colored flowers, dark green-colored foliage, and moderately vigorous, mounded-upright growth habit, is disclosed.

  一种新的、独特的鼠尾草属植物品种，命名为“Balcherissam”，其特征为中等黄橙色和薰衣草色的花朵，深绿色的叶子，以及适度有活力、呈丘状直立生长习性。