tetramethylphosphonium acetate | 52987-83-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 四烷基鏻化合物
• 英文名称: tetramethylphosphonium acetate
• 英文别名: Tetramethylphosphanium acetate；tetramethylphosphanium;acetate
• CAS: 52987-83-4
• 化学式: C₂H₃O₂*C₄H₁₂P
• 分子量: 150.158
• InChiKey: HYVDRSVZYMKTKG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.28
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  tetramethylphosphonium carbonate 、 溶剂黄146 以 丙酮 为溶剂， 反应 3.0h， 以96%的产率得到tetramethylphosphonium acetate
  参考文献：
  名称：

  一种室温季鏻盐离子液体及其制备方法

  摘要：

  一种室温季鏻盐离子液体的结构式如下：式中R1、R2、R3为碳原子数为1‑22的烷基、苯基或芳基，R1、R2或R3是相同的基团或不同的基团；为酸根。本发明具有无毒性、无污染和无设备腐蚀性高的优点。

  公开号：

  CN108440595A

文献信息

• Process for the production of fluorinated organic compounds and fluorinating agents
  申请人：——

  公开号：US20030176747A1

  公开（公告）日：2003-09-18

  A process for the production of a fluorinated organic compound, characterized by fluorinating an organic compound having a hydrogen atoms using IF 5 ; and a novel fluorination process for fluorinating an organic compound having a hydrogen atoms by using a fluorinating agent containing IF 5 and at least one member selected from the group consisting of acids, bases, salts and additives.

  一种用IF5对含有氢原子的有机化合物进行氟化的生产过程；以及一种新颖的氟化过程，通过使用含有IF5和来自酸、碱、盐和添加剂组成的至少一种成员的氟化剂对含有氢原子的有机化合物进行氟化。
• METHOD FOR PURIFICATION OF AN AROMATIC DIACID OR THE CORRESPONDING ANHYDRIDE
  申请人：SABIC Global Technologies B.V.

  公开号：US20180079705A1

  公开（公告）日：2018-03-22

  A method of purifying a stream having an aromatic carboxy-aldehyde and an aromatic acid or the corresponding anhydride is described. The method includes reacting a hydroxylamine-containing compound with the aromatic carboxy-aldehyde in the stream to form a reaction mixture including the corresponding nitrone; adding an aqueous solvent to the reaction mixture, in an amount and under conditions effective to solubilize the nitrone but not the organic acid or the corresponding anhydride; and separating the solubilized nitrone from the non-solubilized organic acid. The nitrone is a water soluble nitrone.

  描述了一种净化含有芳香羧醛和芳香酸或相应酐的流体的方法。该方法包括将含有羟胺的化合物与流体中的芳香羧醛反应，形成包含相应亚胺的反应混合物；向反应混合物中加入水溶剂，以有效溶解亚胺但不溶解有机酸或相应酐；并将溶解的亚胺与未溶解的有机酸分离。该亚胺是水溶性亚胺。
• METHOD FOR ALCOHOLYSIS OF POLYCARBONATE COMPOSITIONS CONTAINING FLAME RETARDANT OR ACRYLONITRILE-BUTADIENE-STYRENE
  申请人：SAUDI BASIC INDUSTRIES CORPORATION

  公开号：US20140179892A1

  公开（公告）日：2014-06-26

  The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70° C. to 200° C., and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.

  本公开提供了一种用于醇解含有聚碳酸酯和含有磷系阻燃剂、丙烯腈-丁二烯-苯乙烯或磷系阻燃剂和丙烯腈-丁二烯-苯乙烯组合物的组合物的方法。该方法包括将该组合物与形成该组分的溶剂接触，该溶剂形成该组分的溶液或可过滤悬浮液但不形成聚碳酸酯的溶液或可过滤悬浮液；将溶液或可过滤悬浮液与聚碳酸酯分离；在醇和催化剂的存在下，在70℃至200℃的温度和5毫巴至40巴的压力下加热聚碳酸酯，足以使聚碳酸酯去聚合并产生二羟基芳香化合物和二烷基碳酸酯。
• Liquid crystal polycarbonates and methods of preparing same
  申请人：Shafer Sheldon

  公开号：US20050192424A1

  公开（公告）日：2005-09-01

  Liquid crystal polycarbonates are made by forming a reaction mixture containing (a) an activated diaryl carbonate; (b) at least two species of aromatic diols selected from among resorcinol, 4,4′-biphenol, hydroquinone, methylhydroquinone, 4,4′-dihydroxyphenylether, dihydroxynaphthalene, including in particular the 2,6, 1,5, and 2,7 isomers, 4,4′-dihydroxybenzophenone and 2,6-dihydroxyanthraquinone (anthraflavic acid); and (c) optionally bisphenol A in a maximum amount of 10 mole %; and processing the reaction mixture in a melt transesterification reaction to form a liquid crystal polycarbonate. While the product composition has the same overall characteristics as compositions made using diphenyl carbonate as the donor moiety for the carbonate linkage, they are analytically distinguishable because of limited incorporation of intermediate or end-cap residues derived from the activated diaryl carbonate.

  液晶聚碳酸酯是通过形成反应混合物来制备的，其中包含(a)活化的二苯基碳酸酯；(b)至少两种从间苯二酚、4,4'-联苯酚、对苯二酚、甲基对苯二酚、4,4'-二羟基苯醚、二羟基萘、特别是2,6、1,5和2,7异构体、4,4'-二羟基苯酮和2,6-二羟基蒽醌（蒽黄酸）中选择的芳香族二酚；以及（c）可选的双酚A，最大量不超过10摩尔％；并在熔融酯交换反应中处理反应混合物以形成液晶聚碳酸酯。虽然该产品组成具有使用二苯基碳酸酯作为碳酸酯键供体制成的组成物相同的总体特性，但由于活化的二苯基碳酸酯中间体或端基残留的有限结合，它们在分析上是可区分的。
• Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof
  申请人：Kennedy Joseph

  公开号：US20080206690A1

  公开（公告）日：2008-08-28

  Compositions for use in tri-layer applications are described herein, wherein the composition has a matrix and includes: a formulated polymer comprising at least one type of silicon-based moiety forming the matrix of the polymer, a plurality of vinyl groups coupled to the matrix of the polymer, and a plurality of phenyl groups coupled to the matrix of the polymer, at least one condensation catalyst, and at least one solvent. Tri-layer structures are also contemplated herein that comprise an organic underlayer (first layer), antireflective compositions and/or films contemplated herein (second layer) and a photoresist material (third layer) that are coupled to one another. Methods of producing a composition for tri-layer patterning applications includes: providing a formulated polymer comprising at least one type of silicon-based moiety forming the matrix of the polymer, a plurality of vinyl groups coupled to the matrix of the polymer, and a plurality of phenyl groups coupled to the matrix of the polymer, providing at least one condensation catalyst, providing at least one solvent, providing at least one pH modifier, blending the formulated polymer and part of the at least one solvent in a reaction vessel to form a reactive mixture; and incorporating the at least one pH modifier, the at least one condensation catalyst and the remaining at least one solvent into the reactive mixture to form the composition.

  本文描述了用于三层应用的组合物，其中该组合物具有一个基质，包括：一种经过配制的聚合物，该聚合物的基质包含至少一种硅基基团，与基质相偶联的多个乙烯基和多个苯基，至少一种缩合催化剂和至少一种溶剂。本文还考虑了三层结构，包括有机底层（第一层）、反射率组合物和/或膜（第二层）以及与其相偶联的光阻材料（第三层）。制备用于三层图案应用的组合物的方法包括：提供一种经过配制的聚合物，该聚合物的基质包括至少一种硅基基团，与基质相偶联的多个乙烯基和多个苯基，提供至少一种缩合催化剂，提供至少一种溶剂，提供至少一种pH调节剂，将经过配制的聚合物和至少一部分溶剂混合在反应容器中形成反应混合物；并将至少一种pH调节剂、至少一种缩合催化剂和剩余的至少一种溶剂混入反应混合物中形成组合物。