[4-(溴甲基)苯基]-三苯基硅烷 | 18765-69-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [4-(溴甲基)苯基]-三苯基硅烷
• 中文别名: [4-(溴甲基)苯基](三苯基)硅烷
• 英文名称: 4-(triphenylsilyl)benzyl bromide
• 英文别名: (4-bromomethyl-phenyl)-triphenyl-silane；(4-Brommethyl-phenyl)-triphenyl-silan；(4-(Bromomethyl)phenyl)triphenylsilane；[4-(bromomethyl)phenyl]-triphenylsilane
• CAS: 18765-69-0
• 化学式: C₂₅H₂₁BrSi
• 分子量: 429.431
• InChiKey: IHEIGHIJXJBEQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.96
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  [4-(溴甲基)苯基]-三苯基硅烷 在 silver nitrate 作用下， 生成 4-triphenylsilanyl-benzyl alcohol
  参考文献：
  名称：

  Some Tetraarylsilanes Containing Functional Groups

  摘要：

  DOI：

  10.1021/ja01589a055
• 作为产物：
  描述：

  三苯基氯硅烷 在 N-溴代丁二酰亚胺(NBS) 、 正丁基锂 、 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 2.0h， 生成 [4-(溴甲基)苯基]-三苯基硅烷
  参考文献：
  名称：

  Nonlinear Optical Chromophores Having Short-Chain Bridge Structures, Low Optical Loss Materials Containing the Same, and Methods for Preparing the Same

  摘要：

  Nonlinear optical chromophores are provided that have a short chain bridging group between donor and acceptor, which chromophores exhibit lowered λ max values and narrow absorption bands. Electro-optic films prepared from nonlinear optical chromophores provided have enhanced transparency to wavelengths outside of the narrow absorption bands, as well as low optic loss, high thermal stability, and high photostability.

  公开号：

  US20230212399A1

文献信息

• MOLECULAR GLASSES WITH FUNCTIONALIZABLE GROUPS
  申请人：Minister of National Defence Her Majesty the Queen in right of Canada as represented by the

  公开号：US20140005370A1

  公开（公告）日：2014-01-02

  Disclosed herein is a compound having Formula I: or a salt thereof, in which R 1 , R 2 and R 3 are as defined herein. Also disclosed are processes to prepare compounds of Formula I and use of compounds of Formula I to prepare stable glassy phases.

  本文披露了具有化学式I的化合物：或其盐，其中R1、R2和R3如本文所定义。还披露了制备化合物I的方法以及利用化合物I制备稳定玻璃相的用途。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 27, page 82 - 85
  作者：

  DOI：——

  日期：——
• BBrannen, C. G., Iowa State College Journal of Science, 1952, vol. 26, p. 170 - 172
  作者：BBrannen, C. G.

  DOI：——

  日期：——
• Nonlinear Optical Chromophores Having Short-Chain Bridge Structures, Low Optical Loss Materials Containing the Same, and Methods for Preparing the Same
  申请人：Lightwave Logic, Inc.

  公开号：US20230212399A1

  公开（公告）日：2023-07-06

  Nonlinear optical chromophores are provided that have a short chain bridging group between donor and acceptor, which chromophores exhibit lowered λ max values and narrow absorption bands. Electro-optic films prepared from nonlinear optical chromophores provided have enhanced transparency to wavelengths outside of the narrow absorption bands, as well as low optic loss, high thermal stability, and high photostability.
• The Preparation of Some Aryl Silanes¹
  作者：M. Maienthal、M. Hellmann、C. P. Haber、L. A. Hymo、S. Carpenter、A. J. Carr

  DOI：10.1021/ja01653a043

  日期：1954.12