9-Butyl-3,6-bis[2-methyl-2-(morpholin-4-YL)propyl]-9H-carbazole | 141420-64-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-Butyl-3,6-bis[2-methyl-2-(morpholin-4-YL)propyl]-9H-carbazole
• 英文别名: 4-[1-[9-butyl-6-(2-methyl-2-morpholin-4-ylpropyl)carbazol-3-yl]-2-methylpropan-2-yl]morpholine
• CAS: 141420-64-6
• 化学式: C₃₂H₄₇N₃O₂
• 分子量: 505.7
• InChiKey: SGYCHGMRIKWWKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  37
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  29.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Energy-curable composition for making a pressure sensitive adhesive
  申请人：——

  公开号：US20030069323A1

  公开（公告）日：2003-04-10

  An energy-curable polymer-forming composition for making a pressure sensitive adhesive includes an unsaturated oligomer resin and an adhesive promoter which increases the peel strength of the adhesive without reducing its tack. The composition also includes a tackifier and various other optional components such as photoinitiator, chain extender, reactive diluent and the like.

  一种用于制造压敏胶的可固化聚合物形成组合物，包括不饱和低聚物树脂和一种粘合促进剂，该促进剂可以增加胶粘剂的剥离强度而不降低其粘性。该组合物还包括粘合剂和各种其他可选组分，例如光引发剂、链延长剂、反应性稀释剂等。
• A photocurable resin composition and a method for producing the same
  申请人：TAKEDA CHEMICAL INDUSTRIES, LTD.

  公开号：EP0849296A2

  公开（公告）日：1998-06-24

  The invention provides a photocurable resin composition which inhibits the deactivation of a bisacylphosphine oxide-series photopolymerization initiator and is useful for coating optical fibers. The photocurable resin composition comprises (A) a polyurethane (meth)acrylate oligomer, (B) an ethylenically unsaturated compound, (C) a bisacylphosphine oxide-series photopolymerization initiator, and (D) a tertiary amine and no tin component. Incorporation of the component (D) inhibits the decomposition and deactivation of the component (C). The component (A) may contain an aliphatic C14-40 polyol (hydrogenated dimerdiol, 12-hydroxystearyl alcohol) as a polyol component. This resin composition is used for a primary coating of a glass fiber or an indirect coating of an optical fiber through the primary layer, the coating layer being cured by light irradiation to provide an optical fiber coated with the resin composition.

  本发明提供了一种光固化树脂组合物，可抑制双酰氧化膦系列光聚合引发剂的失活，并可用于光纤涂层。这种光固化树脂组合物包括：(A) 一种聚氨酯（甲基）丙烯酸酯低聚物；(B) 一种乙烯基不饱和化合物；(C) 一种双基氧化膦系列光聚合引发剂；(D) 一种叔胺和无锡成分。组分（D）的加入可抑制组分（C）的分解和失活。组分（A）可含有脂肪族 C14-40 多元醇（氢化二聚二醇、12-羟基硬脂醇）作为多元醇组分。这种树脂组合物可用于玻璃纤维的初级涂层或通过初级涂层对光纤进行间接涂层，涂层通过光照射固化，从而得到涂有该树脂组合物的光纤。
• Coating composition for optical fiber
  申请人：TAKEDA CHEMICAL INDUSTRIES, LTD.

  公开号：EP0874012A1

  公开（公告）日：1998-10-28

  In the coating composition for a optical fiber of the present invention, a polyurethane (meth)acrylate oligomer (A), which is based on a urethane prepolymer having an equivalent ratio of NCO group in a polyisocyanate (a) to OH group in a polyol (b) of more than 3.0, is used and the oligomer (A) has a mixing weight ratio of an oligomer (d) having a number average molecular weight of 800 or less to an oligomer (e) having a number average molecular weight of 1,000 or more of 30/70 - 70/30. The coating composition of this invention has a low viscosity, and therefore, is suitable for a rapid fiber-drawing in a production of an optical fiber. Further, a cured material obtained from the coating composition of the present invention has both a high elastic modulus and a high elongation, which properties are required for a hard material, and has a slight change of elastic modulus with a change of temperature to improve a long-term reliability of an optical fiber.

  在本发明的光纤涂层组合物中，使用了一种聚氨酯（甲基）丙烯酸酯低聚物（A），该低聚物基于聚氨酯预聚物，其多异氰酸酯（a）中的NCO基团与多元醇（b）中的OH基团的当量比大于3.0，并且低聚物 (A) 的平均分子量为 800 或以下的低聚物 (d) 与平均分子量为 1,000 或以上的低聚物 (e) 的混合重量比为 30/70 - 70/30。 本发明的涂层组合物粘度低，因此适用于光纤生产中的快速拉丝。此外，用本发明的涂层组合物制成的固化材料具有硬质材料所需的高弹性模量和高伸长率，并且弹性模量随温度变化而略有变化，从而提高了光纤的长期可靠性。
• Selectively reflective shaped articles
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1002849A1

  公开（公告）日：2000-05-24

  A shaped article is obtained by polymerizing a selectively reflective solution comprising a cellulose derivative and a polymerizable solvent. The cellulose derivative is a cellulose derivative having an alkyl degree of substitution of about 2.2 to 3, an acyl degree of substitution of about 0 to 0.8, and a total degree of alkyl and acyl substitution of about 2.8 to 3 [e.g., a highly substituted alkyl cellulose (ethy cellulose) or an acylated alkyl cellullose]. Moreover, the polymerizable solvent may be a (meth)acrylic monomer (e.g., (meth)acrylic acid)]. According to the present invention, there is provided a shaped article having selective reflectivity with respect to wavelength and circularly polarized light.

  通过聚合由纤维素衍生物和可聚合溶剂组成的选择性反射溶液，可获得定型制品。纤维素衍生物是一种纤维素衍生物，其烷基取代度约为 2.2 至 3，酰基取代度约为 0 至 0.8，烷基和酰基的总取代度约为 2.8 至 3[例如，高取代烷基纤维素（乙基纤维素）或酰化烷基纤维素]。此外，可聚合溶剂可以是（甲基）丙烯酸单体（如（甲基）丙烯酸）]。根据本发明，提供了一种对波长和圆偏振光具有选择反射性的成型物品。
• ORTHOPEDIC PHOTO-CURABLE FIXING MATERIAL
  申请人：Alcare Co., Ltd.

  公开号：EP1852134A1

  公开（公告）日：2007-11-07

  It is intended to obtain a photocurable fixture for orthopedic surgery for which required strength can be obtained in a short period of time with visible light. A photocurable resin containing a urethane (meth)acrylate oligomer of the following formula (I) and a photopolymerization initiator which absorbs a light of 400 to 700 nm is prepared. This photocurable resin 4 is retained in a base material 3 to form a support material 5. The inside of this support material 5 is covered with a buffer material 6 and the outside is covered with a cover material 2, to obtain a splint material 1 as a fixture for orthopedic surgery. The buffer material 6 side is put on affected parts, and a bandage is wound over it, and then molding is carried out under irradiation with visible light. As the curing proceeds, a splint is obtained and the affected parts can be fixed. (in the formula (I), A denotes a diisocyanate residue, and each of X and Y denotes a (meth)acrylate residue having a hydroxy group.)

  本发明的目的是获得一种光固化夹具，用于骨科手术，这种夹具可以在短时间内用可见光获得所需的强度。 本发明制备了一种光固化树脂，该树脂含有下式（I）的聚氨酯（甲基）丙烯酸酯低聚物和一种可吸收 400 至 700 纳米光的光聚合引发剂。这种光固化树脂 4 保存在基底材料 3 中，形成支撑材料 5。在支撑材料 5 的内侧覆盖缓冲材料 6，外侧覆盖覆盖材料 2，从而得到骨科手术夹板材料 1。将缓冲材料 6 的一侧放在受影响的部位，并在其上缠绕绷带，然后在可见光照射下进行成型。随着固化的进行，可获得夹板并固定受影响的部位。式（I）中，A 表示二异氰酸酯残基，X 和 Y 分别表示具有羟基的（甲基）丙烯酸酯残基）。