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三(2-噻吩基)膦硫化物 | 24111-71-5

中文名称
三(2-噻吩基)膦硫化物
中文别名
——
英文名称
Tri-[2]thienyl-phosphinsulfid
英文别名
tri-[2]thienyl-phosphine sulfide;Tri(2-thienyl)phosphine sulphide;sulfanylidene(trithiophen-2-yl)-λ5-phosphane
三(2-噻吩基)膦硫化物化学式
CAS
24111-71-5
化学式
C12H9PS4
mdl
——
分子量
312.441
InChiKey
VJXPPEHCZFCFOB-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    5.8
  • 重原子数:
    17
  • 可旋转键数:
    3
  • 环数:
    3.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    117
  • 氢给体数:
    0
  • 氢受体数:
    4

安全信息

  • 海关编码:
    2934999090

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为产物:
    描述:
    三(2-噻吩基)膦甲醇 、 sulfur 作用下, 生成 三(2-噻吩基)膦硫化物
    参考文献:
    名称:
    Darstellung des Tri-?-pyrrylphosphins und des Tri-?-thienylphosphins
    摘要:
    AbstractTripyrrylphosphin wird durch Umsetzen des Pyrrolkaliums mit PCl3 in Äther unter N2 hergestellt. Seine Struktur als Tri‐α‐pyrrylphosphin wird durch vergleichende Betrachtungen mit Tris‐indoly(1)‐phosphin und Tris‐indoyl(3)‐phosphin sowie auf Grund seiner Hydrolysebeständigkeit sehr wahrscheinlich gemacht.Während aus (C4H4N)3P und Schwefel das Tri‐α‐pyrrylphosphinsulfid resultiert, führen Versuche zur Darstellung des Tri‐α‐pyrrylphosphinoxyds zur Zersetzung der Molekel.(C4H4N)3P vermag als 3‐zähliger Ligand zu fungieren und bildet sehr beständige monomere Kupfer(I)‐komplexe der Zusammensetzung (C4H4N)3P · CuX.Tri‐α‐thienylphosphin ist nach der GRIGNARD‐Methode aus Thienylmagnesiumbromid und PCl3 oder PBr3 erhältlich. Sein chemisches Verhalten ist jenem tertiärer aromatischer Phosphine analog; so reagiert es z. B. nicht mit CS2 und wird weder in geschmolzenem noch gelöstem Zustand durch Sauerstoff oxydiert.Das Tri‐α‐thienylphosphinoxyd und ‐sulfid werden aus (C4H3S)3P mit CrO3 oder Schwefel gewonnen.Es wurden lediglich Komplexverbindungen der allgemeinen Zusammensetzung CuX · 2 (C4H3S)3P oder HgCl2 · 2 (C4H3S)3P mit Kupfer‐ und Quecksilbersalzen gebildet.
    DOI:
    10.1002/zaac.19572920410
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文献信息

  • Non-toxic corrosion-protection pigments based on manganese
    申请人:——
    公开号:US20040011252A1
    公开(公告)日:2004-01-22
    Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
    以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子,从而形成一种可少量溶解、溶解度低或不溶于水的化合物,具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率,并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合,其性能与传统的六价铬或四价铅体系相当。需要强调的是,提供本摘要是为了符合要求提供摘要的规则,以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是,本摘要不用于解释或限制权利要求的范围或含义。
  • Non-toxic corrosion-protection pigments based on rare earth elements
    申请人:——
    公开号:US20040104377A1
    公开(公告)日:2004-06-03
    A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.
    一种缓蚀颜料,由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合,至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子,以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率,并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合,其性能可与传统的六价铬体系媲美。
  • NON-TOXIC CORROSION PROTECTION PIGMENTS BASED ON COBALT
    申请人:UNIVERSITY OF DAYTON
    公开号:EP1472319A1
    公开(公告)日:2004-11-03
  • Non-toxic corrosion-protection rinses and seals based on rare earth elements
    申请人:——
    公开号:US20040016910A1
    公开(公告)日:2004-01-29
    Rinsing or sealing solutions comprising a rare earth element and a valence stabilizer for barrier films. The treated films contain a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, praseodymium, terbium, or combinations thereof, and at least one rare earth element is in the tetravalent oxidation state. The rinsing or sealing solution may also contain an optional preparative or solubility control agent. The oxidized rare earth element is present in the coating in a “sparingly soluble” form. The valence stabilizers can be either inorganic or organic in nature. A number of rare earth/valence stabilizer combinations that match the performance of conventional hexavalent chromium systems are presented.
  • NON-TOXIC CORROSION-PROTECTION PIGMENTS BASED ON MANGANESE
    申请人:Sturgill A. Jeffrey
    公开号:US20070149673A1
    公开(公告)日:2007-06-28
    Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 C.F.R. § 1.72(b).
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表征谱图

  • 氢谱
    1HNMR
  • 质谱
    MS
  • 碳谱
    13CNMR
  • 红外
    IR
  • 拉曼
    Raman
hnmr
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  • 峰位数据
  • 峰位匹配
  • 表征信息
Shift(ppm)
Intensity
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Assign
Shift(ppm)
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测试频率
样品用量
溶剂
溶剂用量
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同类化合物

香薷二醇 顺式-1-(2-呋喃基)-1-戊烯 顺-1,2-二氰基-1,2-双(2,4,5-三甲基-3-噻吩基)乙烯 顺-1,2-(2-噻嗯基)二乙烯 雷尼替丁-N,S-二氧化物 雷尼替丁-N-氧化物 西拉诺德 螺[环氧乙烷-2,3'-吡咯并[1,2-a]吡嗪] 萘并[2,1,8-def]喹啉 苯硫基溴化镁 苯甲酸,2-[[[7-[[(3.β.)-3-羟基-28-羰基羽扇-20(29)-烯-28-基]amino]庚基]氨基]羰基] 苍术素 缩水甘油糠醚 紫苏烯 糠醛肟 糠醇-d2 糠醇 糠基硫醇-d2 糠基硫醇 糠基甲基硫醚 糠基氯 糠基氨基甲酸异丙酯 糠基丙基醚 糠基丙基二硫醚 糠基3-巯基-2-甲基丙酸酯 糠基-异戊基醚 糠基-异丁基醚 糠基 2-甲基-3-呋喃基二硫醚 磷杂茂 硫酸异丙基糠酯 硫代磷酸O-糠基O-甲基S-(2-丙炔基)酯 硫代磷酸O-乙基O-糠基S-(2-丙炔基)酯 硫代甲酸S-糠酯 硫代噻吩甲酰基三氟丙酮 硫代乙酸糠酯 硫代丙酸糠酯 硅烷,三(1-甲基乙基)[(3-甲基-2-呋喃基)氧代]- 硅烷,(1,1-二甲基乙基)(2-呋喃基甲氧基)二甲基- 砷杂苯 甲酸糠酯 甲氧亚胺基呋喃乙酸铵盐 甲基糠基醚 甲基糠基二硫 甲基呋喃-2-基甲基氨基甲酸酯 甲基丙烯酸糠酯 甲基5-(羟基甲基)-2-呋喃甲亚氨酸酯 甲基(2Z)-3-甲基-2-(甲基亚胺)-4-氧代-3,4-二氢-2H-1,3-噻嗪-6-羧酸酯 甲基(2Z)-3-氨基-2-(甲基亚胺)-4-氧代-3,4-二氢-2H-1,3-噻嗪-6-羧酸酯 甲基(2Z)-3-异丙基-2-(异丙基亚胺)-4-氧代-3,4-二氢-2H-1,3-噻嗪-6-羧酸酯 甲基(2-甲基-3-呋喃基)二硫