3-(1-acetoxyethoxy)prop-1-ene

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-(1-acetoxyethoxy)prop-1-ene
• 英文别名: 1-Prop-2-enoxyethyl acetate
• 化学式: C₇H₁₂O₃
• 分子量: 144.17
• InChiKey: AJIOTEDUDWNHHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  烯丙基乙烯酯 、 溶剂黄146 在 对甲苯磺酸 作用下， 以 乙醚 为溶剂， 反应 3.5h， 以33%的产率得到3-(1-acetoxyethoxy)prop-1-ene
  参考文献：
  名称：

  Formation of Some Oxygen-Containing Heterocycles by Radical Cyclization:  The Stereochemical Influence of Anomeric Effects

  摘要：

  The influence of the anomeric effect on radical cyclization has been examined by determining the stereochemical outcome of the ring closure of 10 suitably substituted radicals. The stereochemistry of the products formed from the acyclic precursors 4a-f indicates that for suitably constituted radicals anomeric interactions stabilize pseudoaxially substituted transition structures 14 thus affording products with stereochemistry the reverse of that normally observed.

  DOI：

  10.1021/jo980359u

文献信息

• GATE INSULATOR LAYER FOR ORGANIC ELECTRONIC DEVICES
  申请人：Mueller David Christoph

  公开号：US20120056183A1

  公开（公告）日：2012-03-08

  Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as gate insulator layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin gate insulator and processes for preparing such polycycloolefin gate insulator layers and electronic devices encompassing such layers.

  本发明实施例提供了在电子设备中使用多环烯烃的方法，更具体地，提供了使用此类多环烯烃作为电子设备制造中用于制造栅绝缘层的栅绝缘层的方法，以及包括此类多环烯烃栅绝缘层的电子设备和制备此类多环烯烃栅绝缘层和包括此类层的电子设备的工艺。
• INTERLAYER FOR ELECTRONIC DEVICES
  申请人：Mueller David Christoph

  公开号：US20120056249A1

  公开（公告）日：2012-03-08

  Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as interlayers applied to fluoropolymer layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin interlayers and processes for preparing such polycycloolefin interlayers and electronic devices.

  本发明的实施例提供了在电子设备中使用多环氧烷烃的方法，更具体地，是将这种多环氧烷烃用作在制造电子设备时应用于氟聚合物层的中间层，包括这种多环氧烷烃中间层的电子设备以及制备这种多环氧烷烃中间层和电子设备的方法。
• Liquid organic polyisocyanate composition for use in reaction injection molding in presence of siloxane mold release agent
  申请人：ICI AMERICAS INC.

  公开号：EP0122743A2

  公开（公告）日：1984-10-24

  Polyurethane products are made by reaction injection molding in the presence of a defined polysiloxane mold release agent which includes isocyanate reactive groups. The polysiloxane may be included in the polyol or in the isocyanate, and in the latter case, an additional silicone surfactant is present to prevent premature reaction with the isocyanate.

  聚氨酯产品是在含有异氰酸酯反应基团的聚硅氧烷脱模剂存在下，通过反应注塑成型制成的。聚硅氧烷可以包含在多元醇中，也可以包含在异氰酸酯中，在后一种情况下，还需要额外的有机硅表面活性剂，以防止与异氰酸酯过早发生反应。
• Load-bearing article having surface lubricity
  申请人：ICI AMERICAS INC.

  公开号：EP0283172A1

  公开（公告）日：1988-09-21

  A load bearing article fabricated from the reaction of reactants comprising (i) a polyisocyanate, (ii) an active hydrogen-containing compound having an average functionality of at least 2.0, and (iii) a slip agent compound containing a moiety which imparts lubricity to said article, said slip agent compound also having at least one active hydrogen-containing group which is reactive with isocyanate groups, said slip agent compound being present in an amount between about 0.5 and about 5 weight percent based on the weight of (i) and (ii),     the ratio of (i) to the total of (ii) plus (iii) being such that the reaction is conducted at an isocyanate index between about 0.90 and about 1.30.

  一种由反应物反应制得的承重物品，反应物包括：(i) 聚异氰酸酯；(ii) 平均官能度至少为 2.0 的活性含氢化合物；(iii) 滑剂化合物，该滑剂化合物含有可赋予所述物品润滑性的分子，所述滑剂化合物还含有至少一个可与异氰酸酯基团反应的活性含氢基团，所述滑剂化合物的存在量为(i)和(ii)重量的约 0.5%至约 5%，(i)与(ii)加(iii)的总和之比，使反应在异氰酸酯指数约 0.90 至约 1.30 之间进行。
• Interlayer for electronic devices
  申请人：Merck Patent GmbH

  公开号：EP2676978A1

  公开（公告）日：2013-12-25

  The invention relates to the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as interlayers applied to insulating layers used in electronic devices, the electronic devices that encompass such polycycloolefin interlayers and processes for preparing such polycycloolefin interlayers and electronic devices.

  本发明涉及聚环烯烃在电子设备中的应用，更具体地说，涉及将这种聚环烯烃用作电子设备中绝缘层的夹层、包含这种聚环烯烃夹层的电子设备以及制备这种聚环烯烃夹层和电子设备的工艺。