CTPYR

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: CTPYR
• 英文别名: 7-(Diethylamino)-3-[5-[3,6-di(pyren-1-yl)carbazol-9-yl]thiophen-2-yl]chromen-2-one；7-(diethylamino)-3-[5-[3,6-di(pyren-1-yl)carbazol-9-yl]thiophen-2-yl]chromen-2-one
• 化学式: C₆₁H₄₀N₂O₂S
• 分子量: 865.067
• InChiKey: AQRJMQALKAXKSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17
• 重原子数：
  66
• 可旋转键数：
  7
• 环数：
  14.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  62.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-噻吩乙腈 在 哌啶 、 potassium phosphate 、 N-溴代丁二酰亚胺(NBS) 、 copper(l) iodide 、 (1S,2S)-(+)-1,2-环己二胺 、 溶剂黄146 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 0.5h， 生成 CTPYR
  参考文献：
  名称：

  Synthesis, characterization, and properties of novel bis(aryl)carbazole-containing N-coumarin derivatives

  摘要：

  A series of novel N-coumarin derivatives containing oligothiophene-substituted N-coumarins as the core and bis(aryl)carbazoles as the substituent were synthesized and characterized. Their optical, electrochemical, and thermal properties were investigated. The electroluminescence (EL) properties of the selected materials were also studied. Solution-processed OLEDs with green and yellow light emission, turn-on voltages of 2.7-2.9 V, and maximum luminance efficiencies of up to 3.94 cd A(-1) at 17.6 mA cm(-2) (maximum power efficiency of 1.62 lm W-1) were prepared. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.10.056