9,10-bis-(4-methoxy-phenyl)-2-methyl-anthracene

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9,10-bis-(4-methoxy-phenyl)-2-methyl-anthracene
• 英文别名: 9,10-Bis-(4-methoxy-phenyl)-2-methyl-anthracen；9,10-Bis(4-methoxyphenyl)-2-methylanthracene
• 化学式: C₂₉H₂₄O₂
• 分子量: 404.508
• InChiKey: ATDKAHMYKXTVLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis-(4-methoxy-phenyl)-2-methyl-anthracene 在 氢溴酸 、 溶剂黄146 作用下， 以 水 为溶剂， 反应 24.0h， 以79%的产率得到2-methyl-9,10-di(p-hydroxyphenyl)anthracene
  参考文献：
  名称：

  Novel methoxy spirobifluorene and alkyl substituted diphenylacene based organic blue light emitting polymers for application in organic electronics

  摘要：

  We report on the synthesis and characterisation of a series of blue light emitting alkoxy substituted poly(spirobifluorenes) based on acene moiety. The obtained polymers had been fully characterised by FTIR, NMR, TGA, GPC techniques. The obtained polymers showed good photoluminescence and electroluminescence properties with blue fluorescence, obtained by supressing the excimer formation as a result of intermolecular interactions. The optical band gaps of all polymers were estimated to be in the range of 2.64-2.71 eV with good fluorescent quantum yield. The introduction of a spiro-structure in polymer backbone leads to its high thermal stability and good solubility in common organic solvents such as CH2Cl2, CH3Cl, toluene, tetrahydrofuran etc. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2017.07.034
• 作为产物：
  描述：

  9,10-bis-(4-methoxy-phenyl)-2-methyl-9,10-dihydro-anthracene-9,10-diol 在 溶剂黄146 、 锌 作用下， 生成 9,10-bis-(4-methoxy-phenyl)-2-methyl-anthracene
  参考文献：
  名称：

  Haller; Comtesse, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910, vol. 150, p. 1293

  摘要：

  DOI：

文献信息

• Novel methoxy spirobifluorene and alkyl substituted diphenylacene based organic blue light emitting polymers for application in organic electronics
  作者：Rhushirajeshwari M. Chalke、Vishwanath R. Patil

  DOI：10.1016/j.polymer.2017.07.034

  日期：2017.8

  We report on the synthesis and characterisation of a series of blue light emitting alkoxy substituted poly(spirobifluorenes) based on acene moiety. The obtained polymers had been fully characterised by FTIR, NMR, TGA, GPC techniques. The obtained polymers showed good photoluminescence and electroluminescence properties with blue fluorescence, obtained by supressing the excimer formation as a result of intermolecular interactions. The optical band gaps of all polymers were estimated to be in the range of 2.64-2.71 eV with good fluorescent quantum yield. The introduction of a spiro-structure in polymer backbone leads to its high thermal stability and good solubility in common organic solvents such as CH2Cl2, CH3Cl, toluene, tetrahydrofuran etc. (C) 2017 Elsevier Ltd. All rights reserved.
• Haller; Comtesse, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910, vol. 150, p. 1293
  作者：Haller、Comtesse

  DOI：——

  日期：——