1-((4-bromobenzyl)oxy)-2,4-dichlorobenzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-((4-bromobenzyl)oxy)-2,4-dichlorobenzene
• 英文别名: 4-Bromobenzyl-(2,4-dichlorophenyl)ether；1-[(4-bromophenyl)methoxy]-2,4-dichlorobenzene
• 化学式: C₁₃H₉BrCl₂O
• mdl: MFCD07782585
• 分子量: 332.024
• InChiKey: BEZRPCXXOSWFOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.076
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,4-二氯酚 、 alkaline earth salt of/the/ methylsulfuric acid 在 caesium carbonate 、 sodium iodide 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以98%的产率得到1-((4-bromobenzyl)oxy)-2,4-dichlorobenzene
  参考文献：
  名称：

  Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents

  摘要：

  The syntheses of silica-supported oligomeric benzyl phosphates (Si-OBPn) and triazole phosphates (Si-OTPn) using ring-opening metathesis polymerization (ROMP) for use as efficient alkylating reagents is reported. Ease of synthesis and grafting onto the surface of norbornenyl-tagged (Nb-tagged) silica particles has been demonstrated for benzyl phosphate and triazole phosphate monomers. It is shown that these silica polymer hybrid reagents, Si-OBPn and Si-OTPn, can be used to carry out alkylation reactions with an array of different nudeophiles to afford the corresponding benzylated and (triazolyl)methylated products in good yield and high purity.

  DOI：

  10.1021/acs.joc.5b01456

文献信息

• CEOSSLINKED AROMATIC POLYMER, POLYMER ELECTROLYTE,CATALYST INK, POLYMER ELECTROLYTE MEMBRANE, MEMBRANE-ELECTRODE ASSEMBLY AND FUEL CELL
  申请人：Masui Kentaro

  公开号：US20100129729A1

  公开（公告）日：2010-05-27

  A crosslinked aromatic polymer which is produced by a process comprising a reaction step of reacting an aromatic monomer having an ion exchange group of the following general formula (1) and a poly-functional aromatic monomer of the following general formula (2) in a solvent, thereby generating a gel swollen with the solvent: wherein, in the formulae, Ar 1 represents a (2+n)-valent aromatic group, Ar 2 represents a (3+p)-valent aromatic group, Q represents an ion exchange group, X 1 represents a functional group condensable with X 1 or X 2 , X 2 represents a functional group condensable with X 1 or X 2 , n represents an integer of 1 or more, p represents an integer of 0 or more, and in this connection a plurality of X 1 's and X 2 's may be the same as or different from each other, respectively.
• Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents
  作者：Pradip K. Maity、Saqib Faisal、Alan Rolfe、Diana Stoianova、Paul R. Hanson

  DOI：10.1021/acs.joc.5b01456

  日期：2015.10.16

  The syntheses of silica-supported oligomeric benzyl phosphates (Si-OBPn) and triazole phosphates (Si-OTPn) using ring-opening metathesis polymerization (ROMP) for use as efficient alkylating reagents is reported. Ease of synthesis and grafting onto the surface of norbornenyl-tagged (Nb-tagged) silica particles has been demonstrated for benzyl phosphate and triazole phosphate monomers. It is shown that these silica polymer hybrid reagents, Si-OBPn and Si-OTPn, can be used to carry out alkylation reactions with an array of different nudeophiles to afford the corresponding benzylated and (triazolyl)methylated products in good yield and high purity.