(Z)-6,2',β-trihydroxyaurone

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 橙酮类黄酮
• 英文名称: (Z)-6,2',β-trihydroxyaurone
• 化学式: C₁₅H₁₀O₅
• 分子量: 270.241
• InChiKey: BFDHLCPMMHTDDB-SQFISAMPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  20.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.99
• 氢给体数：
  3.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 (Z)-6,2',β-trihydroxyaurone 生成 6,2',β-trimethoxyaurone
  参考文献：
  名称：

  Studies in Cell Suspension Cultures of Cassia didymobotrya. Part VI. The Biotransformation of Chalcones to Aurones and Auronols

  摘要：

  Cell-free extracts derived from tissue cultures of Cassia didymobotrya, which previously had been reported to convert 4-hydroxychalcones to flavones and biflavanones, catalyze the biotransformation of 2-hydroxychalcones to aurones and auronols. The aurone was shown to be the direct precursor of auronol.

  DOI：

  10.3987/com-96-7414
• 作为产物：
  描述：

  isoliquiritigenin 在 polyphenol oxidase 、 双氧水 、 三羟甲基氨基甲烷盐酸盐 作用下， 以 乙二醇甲醚 为溶剂， 以26%的产率得到(Z)-6-hydroxy-2-(2-hydroxybenzylidene)benzofuran-3(2H)-one
  参考文献：
  名称：

  Studies in Cell Suspension Cultures of Cassia didymobotrya. Part VI. The Biotransformation of Chalcones to Aurones and Auronols

  摘要：

  Cell-free extracts derived from tissue cultures of Cassia didymobotrya, which previously had been reported to convert 4-hydroxychalcones to flavones and biflavanones, catalyze the biotransformation of 2-hydroxychalcones to aurones and auronols. The aurone was shown to be the direct precursor of auronol.

  DOI：

  10.3987/com-96-7414

文献信息

• Studies in Cell Suspension Cultures of Cassia didymobotrya. Part VI. The Biotransformation of Chalcones to Aurones and Auronols
  作者：Bruno Botta、Giuliano Delle Monache、Maria Cristina De Rosa、Rosalba Scurria、Alberto Vitali、Vittorio Vinciguerra、Pilar Menendez、Domenico Misiti

  DOI：10.3987/com-96-7414

  日期：——

  Cell-free extracts derived from tissue cultures of Cassia didymobotrya, which previously had been reported to convert 4-hydroxychalcones to flavones and biflavanones, catalyze the biotransformation of 2-hydroxychalcones to aurones and auronols. The aurone was shown to be the direct precursor of auronol.