1-butylimidazolium methanesulfonate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-butylimidazolium methanesulfonate
• 英文别名: 1-butylimidazolium methylsulfonate；[HBIM](1+)*MS(1-)；1-butyl-1H-imidazol-1-ium;methanesulfonate
• 化学式: CH₄O₃S*C₇H₁₂N₂
• 分子量: 220.293
• InChiKey: MUUXTGOYWCEUEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.65
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  82.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N-丁基咪唑 、 甲烷磺酸 以 甲醇 为溶剂， 生成 1-butylimidazolium methanesulfonate
  参考文献：
  名称：

  质子离子液体作为微波辅助提取大黄中大黄酸和大黄素的高效溶剂。

  摘要：

  鸡掌大黄（R. palmatum L.）是一种传统中药材和食品，其中大黄酸和大黄素是主要生物活性成分。因此，从掌叶红中提取这两种化合物非常重要。本工作将质子离子液体（PILs）应用于微波辅助提取（MAE）掌叶大黄酸和大黄素，避免了有机溶剂的毒性。本研究的结果表明，具有较高极性的PIL由于其对微波辐射的吸收能力较强而表现出较高的提取能力。与传统溶剂（例如甲醇、三氯甲烷和低共熔溶剂（DES））相比，本文报道的 PIL、1-丁基-3-咪唑甲磺酸盐（[BHim]MeSO3）更有效。选取的液固比、微波辐射时间、微波辐射功率和PIL浓度的提取条件分别为40 g·g−1、50 s、280 W和80%。在此条件下，大黄酸和大黄素的提取率分别为7.8和4.0 mg·g−1。这些结果表明，PIL 是从天然产物中分离活性成分的有效提取溶剂。

  DOI：

  10.3390/molecules24152770
• 作为试剂：
  描述：

  5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin 在 1-butylimidazolium methanesulfonate 、 1-butyl-3-methylimidazolium Tetrafluoroborate 作用下， 生成 H4TPPS(2-)
  参考文献：
  名称：

  Investigation on solvation and protonation of meso-tetrakis(p-sulfonatophenyl)porphyrin in imidazolium-based ionic liquids by spectroscopic methods

  摘要：

  The solvation and protonation of the meso-tetrakis(p-sulfonatophenyl)porphyrin (TPPS) were investigated by spectroscopic methods in pure or mixed imidazolium-based ionic liquids: 1-butyl-3-methyl-imidazolium terafluoroborate([MBIM]BF4), 1-butylimidazolium terafluoroborate([HBIM]BF4), 1-butyl-imidazolium dodecylalkylbenzenesulfonate ([HBIM]DS), 1-butyl-imidazolium p-toluenesulfonate ([HBIM]TS) and 1-butyl-imidazolium methylsulfonate ([HBIM]MS). Compared with absorption properties of TPPS in aqueous solution, Soret band of TPPS monomer was obviously red-shifted in the ionic liquids, while special absorption of TPPS J-aggregates was located at higher energy level, 483 nm and 702 nm, in protonic ionic liquids (PILs) [HBIM]BF4. Next, the protonation of TPPS in aprotonic ionic liquids (AILs, i.e., [MBIM]BF4) is dependent not only on the concentration of protonic ionic liquids as proton sources, but also on the characteristic of anion and viscosity of PILs. The proton transfer constants between TPPS and four protonic ionic liquids are (2.32 +/- 0.23) x 10(2) for [HBIM]BF4, (1.52 +/- 0.08) x 10(2) for [HBIM]MS, (1.12 +/- 0.21) x 10(2) for [HBIM]DS and (0.84 +/- 0.45) x 10(2) for [HBIM]TS, respectively. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2009.06.057

文献信息

• Method for producing haloalkanes from alcohols
  申请人：Stegmann Viet

  公开号：US20070055084A1

  公开（公告）日：2007-03-08

  The invention relates to a process for preparing haloalkanes by reaction of alcohol with hydrogen halide, wherein the reaction of the alcohol with the hydrogen halide occurs in the presence of an ionic liquid at a temperature which is above 100° C. for at least part of the time and, at least at the time of the commencement of the reaction, the water content is not more than 25 mol % based on the amount of liquid, where the ionic liquid is not octyltrimethylammonium chloride.

  该发明涉及一种通过醇与氢卤化物反应制备卤代烷的方法，其中醇与氢卤化物的反应在存在离子液体的条件下进行，反应温度在100°C以上至少一部分时间，并且至少在反应开始时，水含量不超过液体总量的25摩尔％，其中所述离子液体不是辛基三甲基铵氯化物。
• Superhigh purity ionic liquid
  申请人：DAI-ICHI KOGYO SEIYAKU CO., LTD.

  公开号：EP1707265A1

  公开（公告）日：2006-10-04

  An ionic liquid with an extremely low content of an impurity such as halogen ions which can be obtained easily at a relatively reduced cost, the ionic liquid comprising a pair of a cation K+ and an anion A- represented by the general formula (1) in which the content of an alkali metal as an impurity is 5 ppm or less and the content of a halogen ion is 1 ppm or less, the cation being preferably selected from the group represented by the following general formula (2) obtained by quarternizing a tertiary amine compound or a tertiary phosphine compound by using an acid ester represented by the following general formula (3) and then conducting salt exchange: General formula (2): General formula (3): ROY in which R1 to R4 in the formula (2) each independently represents a linear or branched alkyl group of 1 to 8 carbon atoms, X represents a hetero atom and R in the formula (3) represents a linear or branched alkyl group of 1 to 8 carbon atoms.

  含有极低含量杂质（如卤素离子）的离子液体可以以相对较低的成本轻松获得，该离子液体包括一对由一般式（1）表示的阳离子K+和阴离子A-，其中碱金属杂质的含量为5 ppm或更少，卤素离子的含量为1 ppm或更少，首选选择的阳离子来自以下一般式（2）所代表的组，该组是通过使用以下一般式（3）所代表的酸酯对三级胺化合物或三级膦化合物进行季铵化，然后进行盐交换：一般式（2）：一般式（3）：ROY，其中一般式（2）中的R1至R4各自独立地表示1至8个碳原子的直链或支链烷基基团，X表示杂原子，一般式（3）中的R表示1至8个碳原子的直链或支链烷基基团。
• Method for Separating Hydrogen Chloride and Phosgene
  申请人：Wolfert Andreas

  公开号：US20070293707A1

  公开（公告）日：2007-12-20

  The invention relates to a process for separating hydrogen chloride and phosgene, which comprises bringing a mixture of hydrogen chloride and phosgene into contact with an ionic liquid in which at least part of the hydrogen chloride is dissolved in a step a) and then separating off the hydrogen chloride dissolved in the ionic liquid in a step b).

  本发明涉及一种分离氯化氢和光气的方法，包括将氯化氢和光气的混合物在离子液体中接触，其中至少部分氯化氢在步骤a）中溶解，然后在步骤b）中分离出溶解在离子液体中的氯化氢。
• VERFAHREN ZUR HERSTELLUNG VON HALOGENALKANEN AUS ALKOHOLEN
  申请人：BASF Aktiengesellschaft

  公开号：EP1663921A2

  公开（公告）日：2006-06-07
• VERFAHREN ZUR HERSTELLUNG EINES POLYBENZAZOLPOLYMERS (P)
  申请人：BASF SE

  公开号：EP3512905A1

  公开（公告）日：2019-07-24