二(苯基)碘鎓四氟硼酸盐 | 313-39-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二(苯基)碘鎓四氟硼酸盐
• 英文名称: Diphenyliodonium tetrafluoroborate
• 英文别名: diphenyliodanium;tetrafluoroborate
• CAS: 313-39-3
• 化学式: C12H10BF4I
• 分子量: 367.92
• InChiKey: TWLPOQNWSLYHQW-UHFFFAOYSA-N

物化性质

• 熔点：
  136 °C

计算性质

• 辛醇/水分配系数(LogP)：
  1.11
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  二(苯基)碘鎓四氟硼酸盐 以5%的产率得到
  参考文献：
  名称：

  KIM, T. L.;PTITSYNA, O. A.;REUTOV, O. A., BECTH. MGU. XIMIYA, 1982, 23, N 3, 301-302

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-1-dimethyl(phenyl)silyldec-1-ene 、 亚碘酰苯 以6%的产率得到
  参考文献：
  名称：

  OCHIAI, MASAHITO;SUMI, KENZO;TAKAOKA, YOSHIKAZU;KUNISHIMA, MUNETAKA;NAGAO+, TETRAHEDRON, 44,(1988) N 13, 4095-4112

  摘要：

  DOI：

文献信息

• Agent for Treatment of Eye Diseases
  申请人：Kakizuka Akira

  公开号：US20140148416A1

  公开（公告）日：2014-05-29

  The present invention provides agents effective to treat eye diseases, pharmaceutical compositions comprising them, methods for preparing pharmaceuticals for treatment of eye diseases comprising using the agents, use of the agents in manufacture of pharmaceuticals for treatment of eye diseases and methods for treating eye diseases comprising administering the agents or the pharmaceutical compositions. The eye diseases treated by the present invention include particularly glaucoma, especially normal tension glaucoma, or retinitis pigmentosa. The present invention provides the compound of formula (I) wherein R is as defined in the description.

  本发明提供了治疗眼部疾病的有效药剂，包括它们的制药组合物，制备用于治疗眼部疾病的药物的方法，包括使用这些药剂，以及在制造用于治疗眼部疾病的药物时使用这些药剂的方法，以及通过给药这些药剂或药物组合物来治疗眼部疾病的方法。本发明治疗的眼部疾病包括青光眼，特别是正常张力青光眼，或色素性视网膜病变。本发明提供了式（I）的化合物，其中R在说明中定义。
• Ternary photoinitiator system for cationically polymerizable resins
  申请人：——

  公开号：US20030166737A1

  公开（公告）日：2003-09-04

  Photopolymerizable compositions comprise a cationically polymerizable resin and a photoinitiator system comprising: (i) an iodonium salt; (ii) a visible light sensitizer; and (iii) an electron donor compound having an oxidation potential less than that of 1,4-dimethoxybenzene when measured versus a saturated calomel electrode, wherein the photoinitiator system has a photoinduced potential of less than that of 3-dimethylaminobenzoic acid in a standard solution of 2.9×10 −5 moles/g diphenyl iodonium hexafluoroantimonate and 1.5×10 −5 moles/g camphorquinone in 2-butanone. The compositions polymerize on exposure to light in the visible spectrum and are useful in a variety of applications, including dental adhesives and dental composites.

  光聚合组合物包括一个阳离子聚合树脂和一个光引发剂体系，其中包括：（i）碘化物盐；（ii）可见光敏化剂；和（iii）电子给体化合物，其氧化电位小于1,4-二甲氧基苯与饱和卡洛美电极相比时的氧化电位，其中光引发剂体系在2.9×10−5mol/g二苯基碘化物六氟合锑酸盐和1.5×10−5mol/g樟脑醌的2-丁酮标准溶液中的光诱导电位小于3-二甲基氨基苯甲酸。这些组合物在可见光照射下聚合，并可用于各种应用，包括牙科粘合剂和牙科复合材料。
• Photopolymerizable compositions
  申请人：Minnesota Mining and Manufacturing Company

  公开号：US04394403A1

  公开（公告）日：1983-07-19

  Photopolymerizable compositions which comprise cationically polymerizable organic material and photosensitive aromatic iodonium salt of a halogen-containing complex ion are described as are coated substrates and methods for bonding materials together using such compositions.

  本文描述了包含阳离子聚合有机物和含卤素复合离子的芳香碘盐的光敏光聚合物组合物，以及使用这种组合物进行粘合材料的涂层基板和方法。
• Photoinitiator systems with anthracene-based electron donors for curing cationically polymerizable resins
  申请人：Oxman D. Joel

  公开号：US20050113477A1

  公开（公告）日：2005-05-26

  The invention features a photopolymerizable composition that comprises a cationically polymerizable resin, and a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and one or more anthracene-based compounds as electron donors. Electron donor combinations used in the invention include multiple substituted anthracene compounds or a combination of at least one substituted anthracene compound with unsubstituted anthracene.

  这项发明涉及一种光聚合组合物，包括一个阳离子聚合树脂和一个光引发剂体系，该体系包括一个碘离子盐、一个可见光敏化剂和一个或多个基于蒽的化合物作为电子供体。在该发明中使用的电子供体组合包括多个取代蒽化合物或至少一个取代蒽化合物与未取代蒽化合物的组合。
• Multidirectional photoreactive absorption method
  申请人：——

  公开号：US20040223385A1

  公开（公告）日：2004-11-11

  A method for enhancing photoreactive absorption in a specified volume element of a photoreactive composition. In one embodiment, the method includes: providing a photoreactive composition: providing a source of light (preferably, a pulsed laser) sufficient for simultaneous absorption of at least two photons by the photoreactive composition, the light source having a beam capable of being divided: dividing the light beam into a plurality of equal path length exposure beams: and focusing the exposure beams in a substantially non-counter propagating manner at a single volume element of the photoreactive composition simultaneously to react at least a portion of the photoreactive composition. In another embodiment, a method includes: providing a photoreactive composition capable of photoreactive absorption: and exposing the photoreactive composition to laser light from a plurality of substantially non-counter propagating directions simultaneously, wherein the light overlaps in time and space at a predetermined focus spot.

  一种增强光敏反应组分中特定体积元素的光敏吸收的方法。在一种实施例中，该方法包括：提供光敏反应组分；提供一种光源（最好是脉冲激光器），足以使光敏反应组分同时吸收至少两个光子，光源具有可分割的光束；将光束分成多个相等的光程曝光光束；并将曝光光束以相当不相反的方式聚焦在光敏反应组分的单个体积元素上，以同时反应光敏反应组分的至少一部分。在另一种实施例中，该方法包括：提供一种能够进行光敏吸收的光敏反应组分；并将光敏反应组分同时暴露于来自多个相当不相反的方向的激光光线下，其中光线在时间和空间上重叠在预定的聚焦点。