N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)pivalamide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)pivalamide
• 英文别名: N-[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]-2,2-dimethylpropanamide
• 化学式: C₉H₁₉NO₄
• 分子量: 205.254
• InChiKey: CYVOZVLWADJEEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  89.8
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)pivalamide 、 2,2-二甲氧基丙烷 在 4-甲基苯磺酸吡啶 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 15.0h， 以65%的产率得到tert-butyl N-[5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxan-5-yl]carbamate
  参考文献：
  名称：

  WO2008/30118

  摘要：

  公开号：
• 作为产物：
  描述：

  二碳酸二叔丁酯 、 三羟甲基氨基甲烷 以 甲醇 、 水 为溶剂， 反应 72.0h， 以100%的产率得到N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)pivalamide
  参考文献：
  名称：

  WO2008/30118

  摘要：

  公开号：

文献信息

• POLYMERISATION USING CHAIN TRANSFER AGENTS
  申请人：Perrier Sebastian

  公开号：US20090215965A1

  公开（公告）日：2009-08-27

  The invention provides a process for synthesising functionalised chain transfer polymers of Formula (1) or Formula (2) using thiocarbonyl thio compounds as chain transfer agents. Why R1 is a moiety comprising a functional group; Q is obtained from an olefinically unsaturated monomer; R′ is selected from the group consisting of alkyl, substituted alkyl, alkoxy, substituted alkoxy, an aromatic saturated or unsaturated carbocyclic or heterocyclic ring, optionally substituted with one or more substituents, amino alkyl, cyanoalkyl, hydroxylalkyl, saturated and unsaturated amido; an organometallic species, a polymer chain and any of the foregoing substituted with one or more CN or OH groups; q=an integer of at least 2; p=an integer of at least 1. Chain transfer agents and polymers produced by the method are also provided.

  该发明提供了一种合成功能化链转移聚合物的方法，使用硫代羰基硫化合物作为链转移剂，其化学式为(1)或(2)。其中，R1是包含功能基团的基团；Q是从烯烃不饱和单体获得的；R′选自包括烷基、取代烷基、烷氧基、取代烷氧基、芳香饱和或不饱和碳环或杂环环，可选地取代一个或多个取代基，氨基烷基、氰基烷基、羟基烷基、饱和和不饱和酰胺的基团；有机金属物种、聚合物链和上述任何一种基团，其中取代有一个或多个CN或OH基团；q至少为2的整数；p至少为1的整数。该方法还提供了链转移剂和由该方法产生的聚合物。
• PHOTO-DESTROYABLE QUENCHER AND ASSOCIATED PHOTORESIST COMPOSITION, AND DEVICE-FORMING METHOD
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：US20150346599A1

  公开（公告）日：2015-12-03

  A photo-destroyable quencher has the structure wherein X, n, and R 1 -R 6 are defined herein, and at least one of R 2 , R 3 , R 4 , R 5 , and R 6 is halogen, nitro, C 1-12 fluorinated alkyl, cyano, aldehyde, C 2-20 ester, C 2-20 ketone, C 1-20 sulfoxyl hydrocarbyl, C 1-20 sulfonyl hydrocarbyl, or sulfonamide. The photo-destroyable quencher exhibits improved solution stability and reduced hygroscopic properties relative to triphenylsulfonium phenolate. A photoresist composition including an acid-sensitive polymer, a photoacid generator, and the photo-destroyable quencher exhibits increased contrast and/or critical dimension uniformity relative to corresponding photoresist compositions comparative photo-destroyable quenchers.

  一种可被光破坏的猝灭剂具有以下结构，其中X、n和R1-R6如本文所定义，且R2、R3、R4、R5和R6中至少有一个是卤素、硝基、C1-12氟化烷基、氰基、醛基、C2-20酯、C2-20酮、C1-20烷基磺氧基、C1-20烷基磺酰基或磺胺基。该可被光破坏的猝灭剂相对于三苯基砜酚酚酚酚具有改善的溶液稳定性和减少的亲湿性能。包括酸敏感聚合物、光酸发生剂和可被光破坏的猝灭剂的光刻胶组合物相对于相应的光刻胶组合物比较照片破坏性猝灭剂具有增加的对比度和/或临界尺寸均匀性。
• PHOTOACID GENERATING COMPOUND AND PHOTORESIST COMPOSITION COMPRISING SAME, COATED ARTICLE COMPRISING THE PHOTORESIST AND METHOD OF MAKING AN ARTICLE
  申请人：Aqad Emad

  公开号：US20140120471A1

  公开（公告）日：2014-05-01

  A compound having the formula (I): wherein a is an integer of from 1 to 10, and x is an integer of from 1 to 3, X 1 comprises a fluoroalcohol, fluorinated ester, or fluorinated anhydride, Y is a single bond, C 1-20 alkylene group, O, S, NR, ester, carbonate, sulfonate, sulfone, or sulfonamide, wherein R is H or C 1-20 alkyl, and wherein the C 1-20 alkylene group is structurally only carbon, or one or more structural carbon atoms in the C 1-20 alkylene group is replaced by oxygen, carbonyl, ester, or a combination comprising at least one of the foregoing, Ar is a substituted or unsubstituted, C 5 or greater monocyclic, polycyclic, or fused polycyclic cycloalkyl; or a substituted or unsubstituted, C 5 or greater monocyclic, polycyclic, or fused polycyclic aryl group, wherein the cycloalkyl or aryl is a carbocycle or comprises a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing, each R 1 is independently a substituted C 5-40 aryl, substituted C 5-40 heteroaryl, C 1-40 alkyl, a C 3-40 cycloalkyl, wherein when x is 1, the two groups R 1 are separate or bonded to each other to form a C 4-40 ring structure, and Z − is a carboxylate, sulfate, sulfonate, sulfamate, or the anion of a sulfonimide, wherein when Y is a single bond, Z − is not sulfonate.

  化合物的化学式为（I）：其中a是1到10的整数，x是1到3的整数，X1包括氟醇，氟酯或氟酸酐，Y是单键，C1-20烷基，O，S，NR，酯，碳酸酯，磺酸盐，磺酮或磺酰胺，其中R为H或C1-20烷基，C1-20烷基仅由碳构成，或C1-20烷基中的一个或多个结构碳原子被氧，羰基，酯或至少包括其中一种的组合所取代，Ar是取代或未取代的C5或更大的单环，多环或融合多环环烷基；或取代或未取代的C5或更大的单环，多环或融合多环芳基，其中环烷基或芳基是碳环或包含O，S，N，F或至少包括其中一种的杂原子，每个R1独立地是取代的C5-40芳基，取代的C5-40杂芳基，C1-40烷基，C3-40环烷基，当x为1时，两个R1基团可以分离或结合形成C4-40环状结构，Z-是羧酸盐，硫酸盐，磺酸盐，磺酰胺或磺酰胺的阴离子，当Y为单键时，Z-不是磺酸盐。
• PHOTOACID GENERATOR
  申请人：ROHM AND HAAS ELECTRONIC MATERIALS LLC

  公开号：US20170192352A1

  公开（公告）日：2017-07-06

  A photoacid generator compound having Formula (I): wherein, EWG, Y, R, and M + are the same as described in the specification.

  一种具有式(I)的光酸发生剂化合物：其中，EWG、Y、R和M+与规范中描述的相同。
• PHOTOACID GENERATOR AND PHOTORESIST COMPRISING SAME
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：US20130171567A1

  公开（公告）日：2013-07-04

  A photoacid generator includes those of formula (I): wherein each R a in formula 1 is independently H, F, a C 1-10 nonfluorinated organic group, C 1-10 fluorinated organic group, or a combination comprising at least one of the foregoing, provided at least one R a is F or a C 1-10 fluorinated organic group, the C 1-10 fluorinated and nonfluorinated organic groups each optionally comprising O, S, N, or a combination comprising at least one of the foregoing heteroatoms; L 1 is a linking group comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing; G + is an onium salt of the formula (II): wherein in formula (II), X is S or I, each R 0 is independently C 1-30 alkyl group; a polycyclic or monocyclic C 3-30 cycloalkyl group; a polycyclic or monocyclic C 4-30 aryl group; or a combination comprising at least one of the foregoing, provided at least one R 0 is substituted where each R 0 is a C 6 monocyclic aryl group, and wherein when X is I, a is 2, and where X is S, a is 3, p is 0 or 1, and q is an integer of from 1 to 10.

  一种光酸发生剂包括以下公式(I)中的化合物：其中，每个公式1中的Rai独立地为H、F、C1-10非氟化有机基团、C1-10氟化有机基团或包含上述至少一种的组合物，至少一个Rai为F或C1-10氟化有机基团，C1-10氟化和非氟化有机基团各自可以包含O、S、N或包含上述至少一种杂原子的组合物；L1是一个连接基团，包括一个包含O、S、N、F或包含上述至少一种的杂原子；G+是公式(II)的阳离子盐：其中，在公式(II)中，X为S或I，每个R0独立地为C1-30烷基、多环或单环C3-30环烷基、多环或单环C4-30芳基或包含上述至少一种的组合物，至少一个R0被取代，每个R0为C6单环芳基，当X为I时，a为2，当X为S时，a为3，p为0或1，q为1到10的整数。