1-ethyl-2-(4-methoxyphenyl)imidazo[4,5-f][1,10]-phenanthroline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1-ethyl-2-(4-methoxyphenyl)imidazo[4,5-f][1,10]-phenanthroline
• 英文别名: 3-ethyl-2-(4'-methoxy)phenylimidazo[4,5-f]-1,10-phenanthroline；3-Ethyl-2-(4-methoxyphenyl)imidazo[4,5-f][1,10]phenanthroline
• 化学式: C₂₂H₁₈N₄O
• 分子量: 354.411
• InChiKey: LRLLIBBGTFIRAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  52.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-ethyl-2-(4-methoxyphenyl)imidazo[4,5-f][1,10]-phenanthroline 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 2,2'-联吡啶-4,4'-二甲酸 、 ammonium thiocyanate 以 N,N-二甲基甲酰胺 为溶剂， 反应 13.0h， 以69%的产率得到cis-dithiocyanato-2,2'-bipyridyl-4,4'-dicarboxylate-3-ethyl-2-(4'-methoxyphenyl)imidazo[4,5-f]-1,10-phenanthroline
  参考文献：
  名称：

  WO2007/6026

  摘要：

  公开号：
• 作为产物：
  描述：

  2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline 、 溴乙烷 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.5h， 以55%的产率得到1-ethyl-2-(4-methoxyphenyl)imidazo[4,5-f][1,10]-phenanthroline
  参考文献：
  名称：

  WO2007/6026

  摘要：

  公开号：

文献信息

• A new carbazole-based phenanthrenyl ruthenium complex as sensitizer for a dye-sensitized solar cell
  作者：Xianghong Li、John Gui、Hong Yang、Wenjun Wu、Fuyou Li、He Tian、Chunhui Huang

  DOI：10.1016/j.ica.2008.02.027

  日期：2008.6

  Three new amphiphilic ruthenium complexes (Ru-1, Ru-2 and Ru-3) based on phenanthrenyl derivatives have been synthesized and used as photosensitizers for dye-sensitized solar cells (DSSCs). The ruthenium complex Ru-1 containing a carbazole group showed especially improved photophysical properties (red-shifted metal-to-ligand charge-transfer transition absorptions and enhanced molar extinction coefficients)and interesting electrochemical properties, resulting in its improved open circuit potential and high overall light-to-electric power conversion efficiency of 5.3% (AM1.5,75 mW/cm(2)). These facts indicate that the carbazole-based phenanthrenyl ruthenium complex is a promising candidate for improving the conversion efficiency of dye-sensitized solar cells. (c) 2008 Elsevier B.V. All rights reserved.
• Compositions and use thereof in dye sensitized solar cells
  申请人：Gui Yupeng John

  公开号：US20070000539A1

  公开（公告）日：2007-01-04

  The present invention provides in one aspect a composition having at least one metal complex, such that the metal complex comprises at least one metal atom, a phenanthroline-based first ligand and a second ligand comprising at least one acidic group, and at least two coordinative nitrogen atoms capable of simultaneous binding to the metal atom. This composition may be disposed on a semiconductor layer which is further disposed on an electrically conductive surface to provide a dye-sensitized electrode. The dye-sensitized electrode can be assembled together with a counter electrode and a redox electrolyte to provide a dye-sensitized solar cell.
• [EN] COMPOSITIONS AND USE THEREOF IN DYE SENSITIZED SOLAR CELLS<br/>[FR] COMPOSITIONS ET UTILISATION DE CELLES-CI DANS DES PILES SOLAIRES A COLORANT
  申请人：GEN ELECTRIC

  公开号：WO2007006026A1

  公开（公告）日：2007-01-11

  [EN] The present invention provides in one aspect a composition having at least one metal complex, such that the metal complex comprises at least one metal atom, a phenanthroline-based first ligand and a second ligand comprising at least one acidic group, and at least two coordinative nitrogen atoms capable of simultaneous binding to the metal atom. This composition may be disposed on a semiconductor layer which is further disposed on an electrically conductive surface to provide a dye- sensitized electrode. The dye-sensitized electrode can be assembled together with a counter electrode and a redox electrolyte to provide a dye-sensitized solar cell.
  [FR] La présente invention concerne une composition comprenant au moins un complexe métallique qui présente au moins un atome métallique, un premier ligand à base de phénanthroline et un second ligand comprenant au moins un groupe acide, ainsi qu'au moins deux atomes d'azote coordinatifs capables de se lier simultanément à l'atome métallique. Cette composition peut être placée sur une couche de semi-conducteur qui est ensuite placée sur une surface électroconductrice afin d'obtenir une électrode à colorant. Cette électrode à colorant peut alors être montée avec une contre-électrode et un électrolyte redox, afin d'obtenir une pile solaire à colorant.
• WO2007/6026
  申请人：——

  公开号：——

  公开（公告）日：——