2,6-dimethyl-9-phenyl-9H-carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2,6-dimethyl-9-phenyl-9H-carbazole
• 英文别名: 2,6-Dimethyl-9-phenylcarbazole；2,6-dimethyl-9-phenylcarbazole
• 化学式: C₂₀H₁₇N
• 分子量: 271.362
• InChiKey: XDMFAVRDLVWLFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  苯基脲 、 4-甲基环己酮 在 碘 、 氧气 、 对甲苯磺酸 、 potassium iodide 作用下， 以 水 、 甲苯 为溶剂， 反应 40.0h， 以73%的产率得到2,6-dimethyl-9-phenyl-9H-carbazole
  参考文献：
  名称：

  芳基脲和环己酮合成无过渡金属咔唑

  摘要：

  已经开发了一种在无过渡金属的条件下由芳基脲和环己酮合成咔唑的有效策略。碘化钾和碘的组合使用可以显着提高反应效率，以中等至良好的产率提供2,6-二取代的9-芳基咔唑。在这种转化中，整个咔唑部分（氮原子除外）都来自两个当量的环己酮。

  DOI：

  10.1002/adsc.201600673

文献信息

• SILICON-CONTAINING ELECTRON TRANSPORTING MATERIAL AND ITS APPLICATION
  申请人：BEIJING SUMMER SPROUT TECHNOLOGY CO., LTD.

  公开号：US20200131204A1

  公开（公告）日：2020-04-30

  A silicon-containing electron transporting material and its application are disclosed. The silicon-containing electron transporting material employs a silicon-containing compound with a novel structure containing one or more silicon atoms and a specific group. The compound can be used as an electron transporting layer of an electroluminescent device, which can effectively improve the lifetime of the device and improve device performance. An electroluminescent device and compound formulation are also disclosed.

  揭示了一种含硅的电子传输材料及其应用。这种含硅的电子传输材料采用了一种具有新颖结构的含硅化合物，其中含有一个或多个硅原子和一个特定基团。该化合物可用作电致发光器件的电子传输层，可以有效提高器件的寿命和性能。同时还公开了一种电致发光器件和化合物配方。
• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170125688A1

  公开（公告）日：2017-05-04

  An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a condensed cyclic compound of Formula 1: An organic light-emitting device including the condensed cyclic compound of Formula 1 may have high efficiency, low driving voltage, high luminance, and a long lifespan.

  一种有机发光器件包括：第一电极；面向第一电极的第二电极；以及位于第一电极和第二电极之间的有机层，该有机层包括一个发射层，其中该有机层包括化学式1的缩合环化合物。包括化学式1的缩合环化合物的有机发光器件可能具有高效率、低驱动电压、高亮度和长寿命。
• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE COMPRISING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20160285011A1

  公开（公告）日：2016-09-29

  An organic light-emitting device including a first electrode as an anode; a second electrode as a cathode and facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, a hole transport region between the first electrode and the emission layer, and an electron transport region between the emission layer and the second electrode, where at least one selected from the emission layer and the electron transport region includes at least one selected from condensed cyclic compounds represented by Formula 1: A 2 -(A 1 ) n1 .  Formula 1

  一种有机发光器件，包括第一电极作为阳极；第二电极作为阴极，且与第一电极相对；以及位于第一电极和第二电极之间的有机层，该有机层包括一个发射层，在第一电极和发射层之间的一个空穴传输区域，以及在发射层和第二电极之间的一个电子传输区域，其中发射层和电子传输区域中的至少一个包括由Formula 1：A2-(A1)n1表示的至少一个紧缩环化合物中的至少一个。
• MATERIALS FOR ELECTRONIC DEVICES
  申请人：Merck Patent GmbH

  公开号：US20210147375A1

  公开（公告）日：2021-05-20

  The present application relates to fluorenylamine compounds, to the use thereof in electronic devices, and to synthesis methods for preparing the fluorenylamine compounds.

  本申请涉及氟烯基胺化合物，其在电子设备中的使用，以及制备氟烯基胺化合物的合成方法。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATION DEVICE, AND DISPLAY DEVICE
  申请人：Konica Minolta, Inc.

  公开号：EP2930762A1

  公开（公告）日：2015-10-14

  An organic electroluminescent element material characterized in being a compound represented by general formula (1). (In general formula (1), each of R1-R3 individually represents a substituent group. At least one of R1-R3 is a group represented by general formula (2). If a plurality of each of R1-R3 are present, each of R1-R3 may be the same or different, and may also be boned to each other to form a ring. n1 represents an integer of 0-8, n2 represents an integer of 0-3, and n3 represents an integer of 0-4. n1+n2+n3 is 1 or greater. Cbz represents a carbazolyl group. X represents an oxygen atom or a sulfur atom. L1 represents a single bond or a divalent linking group.)

  一种有机电致发光元件材料，其特征在于它是通式(1)所代表的化合物。(在通式（1）中，R1-R3 各自代表一个取代基。R1-R3 中至少有一个是通式（2）所代表的基团。n1 代表 0-8 的整数，n2 代表 0-3 的整数，n3 代表 0-4 的整数。n1+n2+n3 为 1 或更大。Cbz 代表咔唑基团。X 代表氧原子或硫原子。L1 代表单键或二价连接基团）。