1,2,3-trideoxy-D-mann-non-1-enitol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,2,3-trideoxy-D-mann-non-1-enitol
• 英文别名: (2S,3S,4S,5S)-non-8-ene-1,2,3,4,5,6-hexol
• 化学式: C₉H₁₈O₆
• 分子量: 222.238
• InChiKey: KOOBOEHYNRNKGC-UFHRUUPSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.4
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  121
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  D-甘露糖 、 二烯丙基二溴锡 以 水 为溶剂， 以71%的产率得到1,2,3-trideoxy-D-mann-non-1-enitol
  参考文献：
  名称：

  Organometallic Reactions in Aqueous Media. The Nature of the Organotin Intermediate in the Tin-Mediated Allylation of Carbonyl Compounds

  摘要：

  Allyl bromide and tin reacted in aqueous media to give first allyltin(II) bromide (5) and then diallyltin dibromide (4). Either organotin intermediate can react with carbonyl compounds to give the corresponding homoallylic alcohols. Competitive experiment showed that 5 was more reactive than 4.

  DOI：

  10.1021/jo9901337

文献信息

• Organometallic Reactions in Aqueous Media. The Nature of the Organotin Intermediate in the Tin-Mediated Allylation of Carbonyl Compounds
  作者：Tak Hang Chan、Yang、Chao Jun Li

  DOI：10.1021/jo9901337

  日期：1999.6.1

  Allyl bromide and tin reacted in aqueous media to give first allyltin(II) bromide (5) and then diallyltin dibromide (4). Either organotin intermediate can react with carbonyl compounds to give the corresponding homoallylic alcohols. Competitive experiment showed that 5 was more reactive than 4.