adamantane monoacrylate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: adamantane monoacrylate
• 英文别名: adamantane;prop-2-enoic acid
• 化学式: C₃H₄O₂*C₁₀H₁₆
• 分子量: 208.301
• InChiKey: WIJGTIIKQPGTSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.09
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  samarium diiodide 、 丙烯酸乙烯酯 、 1-金刚烷醇 以 1,4-二氧六环 为溶剂， 以99%的产率得到adamantane monoacrylate
  参考文献：
  名称：

  POLYMERIZABLE ADAMANTANE DERIVATIVES AND PROCESS FOR PRODUCING THE SAME

  摘要：

  公开号：

  EP0915077B1

文献信息

• SILICON-CONTAINING COMPOUND, URETHANE RESIN, STRETCHABLE FILM, AND METHOD FOR FORMING THE SAME
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190106528A1

  公开（公告）日：2019-04-11

  The present invention provides a silicon-containing compound shown by the following formula ( 1 ): wherein R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 each independently represent a linear, branched, or cyclic alkyl group having 1 to 6 carbon atoms, a phenyl group, a 3,3,3-trifluoropropyl group, or a group shown by —(OSiR 7 R 8 ) n —OSiR 9 R 10 R 11 ; R 7 , R 8 , R 9 , R 10 , and R 11 have the same meanings as R 1 to R 6 ; X represents a linear or branched alkylene group having 3 to 7 carbon atoms optionally having an ether group; and “n” is an integer in the range of 0 to 100. This provides a stretchable film that hats excellent stretchability and strength, with the film surface having excellent repellency, and a method for forming the same; as well as a urethane resin used for the stretchable film; and a silicon-containing compound to be a material of the urethane resin.

  本发明提供了一种含硅化合物，其化学式如下（1）所示：其中R1、R2、R3、R4、R5和R6分别独立地表示具有1至6个碳原子的直链、支链或环烷基基团，苯基，3,3,3-三氟丙基基团，或者由—(OSiR7R8)n—OSiR9R10R11所示的基团；R7、R8、R9、R10和R11具有与R1至R6相同的含义；X表示具有3至7个碳原子的直链或支链烷基基团，可选地具有醚基；“n”是0至100范围内的整数。这提供了一种具有优异的延展性和强度的可拉伸薄膜，薄膜表面具有优异的防水性，以及形成该薄膜的方法；以及用于可拉伸薄膜的聚氨酯树脂；以及用于聚氨酯树脂的硅含量化合物。
• Polymerizable adamantane derivatives and process for producing the same
  申请人：Daicel Chemical Industries, Ltd.

  公开号：US06235851B1

  公开（公告）日：2001-05-22

  A compound shown by the following formula: wherein each of R1a, R2a, R3a and R4a represents a substituent selected from a non-reactive atom, a non-reactive group, a hydroxyl group and an amino group, and at least two members selected from R1a, R2a, R3a and R4a are a hydroxyl group, a carboxyl group or an amino group; is subjected to an esterification reaction or an amidation reaction with a polymerizable unsaturated compound (e.g., an alcohol, a carboxylic acid, an amine) in the presence of a catalyst comprising an element selected from the Group 3 elements, such as a samarium compound, to obtain a polymerizable adamantane derivative having at least one polymerizable unsaturated group in high yield.

  以下化学式所示的化合物：其中R1a、R2a、R3a和R4a中的每一个代表从非反应性原子、非反应性基团、羟基和氨基中选择的取代基，且在R1a、R2a、R3a和R4a中至少有两个成员是羟基、羧基或氨基；在催化剂的存在下，与可聚合的不饱和化合物（例如醇、羧酸、胺）进行酯化反应或酰胺化反应，所述催化剂包括从第三族元素中选择的元素，如钐化合物，以高产率获得至少具有一个可聚合不饱和基团的可聚合性金刚烷衍生物。
• CURABLE RESIN COMPOSITION, CURABLE RESIN MOLDED BODY, CURED RESIN MOLDED BODY, METHOD FOR PRODUCING EACH OF SAME, AND LAMINATE BODY
  申请人：LINTEC CORPORATION

  公开号：US20140350187A1

  公开（公告）日：2014-11-27

  Provided is a curable resin composition comprising a thermoplastic resin (A) that includes a cyclic structure in its main chain, and has a glass transition temperature (Tg) of 140° C. or more, and a monofunctional curable monomer (B). The present invention provides: a cured resin formed article that has heat resistance and low birefringence, a method for producing the same, a curable resin composition and a curable resin formed article that are useful as a raw material for producing the cured resin formed article, and a laminate that includes a layer formed of a cured resin.

  提供的是一种可治愈树脂组合物，包括热塑性树脂（A），其主链中包含环状结构，并具有140℃或更高的玻璃化转变温度（Tg），以及单官能团可固化单体（B）。本发明提供了具有耐热性和低双折射率的固化树脂成型品，其生产方法，作为生产固化树脂成型品的原材料有用的可固化树脂组合物和可固化树脂成型品，以及包括由固化树脂形成的层的层压板。
• Polysiloxane with polycyclic modifier composition and biomedical devices
  申请人：BAUSCH & LOMB INCORPORATED

  公开号：EP0059528A1

  公开（公告）日：1982-09-08

  Monomeric polysiloxanes endcapped with activated unsaturated groups are copolymerized with polycyclic modulus modifiers and tear film stabilizers to form hard, gas permeable, polysiloxane contact lenses and other biomedical devices.

  内含活化不饱和基团的单体聚硅氧烷与多环改性剂和泪膜稳定剂共聚，可形成坚硬、透气的聚硅氧烷隐形眼镜和其他生物医学设备。
• Polysiloxane with cycloalkyl modifier composition and biomedical devices
  申请人：BAUSCH & LOMB INCORPORATED

  公开号：EP0060015A1

  公开（公告）日：1982-09-15

  Monomeric polysiloxanes endcapped with activated unsaturated groups are copolymerized with cycloalkyl modulus modifiers and tear film stabilizers to form hard, gas permeable, polysiloxane contact lenses and other biomedical devices.

  内含活化不饱和基团的单体聚硅氧烷与环烷基改性剂和泪膜稳定剂共聚，形成坚硬、透气的聚硅氧烷隐形眼镜和其他生物医学设备。