1,3-di(λ⁴-azanyl)propane dimethacrylate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,3-di(λ⁴-azanyl)propane dimethacrylate
• 英文别名: 2-Methylprop-2-enoic acid;propane-1,3-diamine；2-methylprop-2-enoic acid;propane-1,3-diamine
• 化学式: C₃H₁₀N₂*2C₄H₆O₂
• 分子量: 246.307
• InChiKey: KKDZXMAQPYCBJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.06
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  89.3
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-di(λ⁴-azanyl)propane dimethacrylate 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 反应 2.0h， 以43%的产率得到[Cu(pn)(MAA)(μ-CH₃COO)]₂
  参考文献：
  名称：

  Synthesis, X-ray Structural Characterization, and DFT Calculations of Binuclear Mixed-ligand Copper(II) Complexes Containing Diamine, Acetate and Methacrylate Ligands

  摘要：

  The dinuclear Cu(II) complexes [ Cu(en)(MAA)(mu-CH3COO)](2) (1) and [Cu(pn)(MAA)(mu-CH3COO)](2) (2) where MAA, en and pn are methacrylate, ethylendiamine and 1,3-propylendiamine, respectively, have been synthesized and characterized by elemental analysis, FT-IR and UV-Vis spectroscopy. The structures of the complexes have been determined by single-crystal X-ray diffraction analyses. In the dinuclear complexes 1 and 2 the two copper centers are five-coordinated and exhibit distorted square pyramidal geometries. The theoretical geometries of the studied compounds have been calculated by means of density functional theory (DFT) at the B3LYP/6-311+G(d, p)/LanL2DZ level considering effective core potential (ECP).

  DOI：

  10.17344/acsi.2017.3401
• 作为产物：
  描述：

  甲基丙烯酸 、 1,3-丙二胺 以 甲醇 为溶剂， 反应 2.0h， 以61%的产率得到1,3-di(λ⁴-azanyl)propane dimethacrylate
  参考文献：
  名称：

  含二胺和甲基丙烯酸酯配体的单核镍（II）配合物的合成，X射线结构表征和DFT计算。

  摘要：

  单核Ni（II）络合物[Ni（en）2（H2O）2]（MAA）2（1）和[Ni（pn）2（MAA）2]（2），其中MAA，en和pn是甲基丙烯酸酯，分别合成了乙二胺和1,3-丙二胺，并通过元素分析，FT-IR和UV-Vis spectroskopy对其进行了表征。配合物的结构已经通过单晶X射线衍射分析确定。在镍（II）配合物1和2中，镍（II）离子为六坐标，并且具有扭曲的八面体几何形状。Ni（II）与1中的两个二胺的四个氮原子键合，另外与2中的水配体的两个氧原子键合，以及2中与甲基丙烯酸酯的2个氧原子键合。所研究化合物的理论几何结构是通过密度计算的B3LYP / 6-311 + G（d，p）/ LanL2DZ级别的功能理论（DFT），并考虑有效核心电势（ECP）。

  DOI：

  10.17344/acsi.2017.4096

文献信息

• Aqueous ink composition, and ink jet recording method and recorded matter using the same
  申请人：Ota Hitoshi

  公开号：US20060173096A1

  公开（公告）日：2006-08-03

  The present invention provides n aqueous ink composition comprising a coloring component, an acetylene glycol-based surfactant, water, and a urea derivative, wherein the coloring component is a dispersion substance in which a colorant is enclosed with a dispersing polymer thereby being rendered dispersible in water, wherein the dispersing polymer comprises a hydrophobic part and a hydrophilic part, wherein at least a part of the hydrophilic part is a neutralized group obtained by neutralizing an unneutralized group constituting a part of the hydrophilic part, and wherein the neutralized groups are present within an amount range of from 20% to less than 60% in terms of molar ratio based on the sum of the neutralized groups and the unneutralized groups.

  本发明提供了一种包括着色组分、基于乙炔二醇的表面活性剂、水和脲衍生物的水性油墨组合物，其中着色组分是一种分散物质，其中颜料与分散聚合物一起封闭，从而使其能够在水中分散，其中分散聚合物包括疏水部分和亲水部分，其中至少部分亲水部分是通过中和构成亲水部分的未中和基团而获得的中和基团，其中中和基团在摩尔比例上基于中和基团和未中和基团的总和而在20%到小于60%的范围内存在。
• INK SET FOR INK-JET RECORDING
  申请人：SEIKO EPSON CORPORATION

  公开号：EP1291397A1

  公开（公告）日：2003-03-12

  The invention provides an ink set for ink jet recording which gives high color density with respect to plain paper and exclusive paper and satisfactory color reproducibility and which has excellent ejection stability and storage stability. An ink jet recording ink set, each ink comprising at least a colorant enclosing a pigment and/or a dye with a polymer, a penetrating agent and water, wherein the ink set comprises a combination of black, yellow, magenta and cyan, or a combination of "black inks, yellow inks, magenta inks, and cyan inks" each inks comprising at least one kind of ink having a different addition concentration, wherein the pigment for the black colorant is C.I. Pigment Black 7, the pigment for the yellow colorant is selected from C.I. Pigment Yellow 55, 74, 110, 128, 150, 155 and 180, the pigment for the magenta colorant is selected from C.I. Pigment Red 122, 202 and 209, and the pigment for the cyan colorant is selected from C.I. Pigment Blue 15, 15 : 1, 15 : 2, 15 : 3, 15 : 4, 15 : 6 and 16.

  本发明提供了一种用于喷墨记录的墨水组，该墨水组相对于普通纸和专用纸具有较高的色彩密度和令人满意的色彩再现性，并且具有出色的喷出稳定性和储存稳定性。 一种喷墨记录墨水组，每种墨水至少包括一种着色剂，其中包含颜料和/或染料以及聚合物、渗透剂和水，其中墨水组包括黑色、黄色、品红色和青色的组合，或 "黑色墨水、黄色墨水、品红色墨水和青色墨水 "的组合，每种墨水包括至少一种具有不同添加浓度的墨水，其中用于黑色着色剂的颜料为 C。颜料黑 7，黄色着色剂的颜料选自 C.I.颜料黄 55、74、110、128、150、155 和 180，品红色着色剂的颜料选自 C.I.颜料红 122、202 和 209，青色着色剂的颜料选自 C.I.颜料蓝 15、15:1、15:2、15:3、15:4、15:6 和 16。
• Ink set for ink jet-jet recording, method for ink-jet recording and recorded matter
  申请人：Seiko Epson Corporation

  公开号：EP1860161A1

  公开（公告）日：2007-11-28

  Provided are an ink set for ink jet recording and an ink jet recording process, which can provide not only high weather resistance but also images having a high printed density by using pigment inks, and have a wide color reproducing range. Also provided is an ink jet recording process capable of performing text printing at a high printing density and with excellent abrasion resistance. Furthermore, recorded matter having images formed at a high printed density and over a wide color reproducing range, and text printed matter (recorded matter) having a high printed density and being excellent in abrasion resistance are provided. The present invention relates to: an ink set for ink jet recording comprising a black ink containing at least "carbon black dispersible in an aqueous medium without a dispersing agent" and water; and at least one color ink containing at least "a colorant enclosing a color pigment with a polymer" and water; an ink jet recording process using the ink set, and recorded matter printed by the recording process.

  本发明提供了一种用于喷墨记录的墨水组和一种喷墨记录工艺，它不仅具有很高的耐候性，而且还能通过使用颜料墨水提供高印刷密度的图像，并具有很宽的色彩再现范围。此外，还提供了一种喷墨记录工艺，能够以高密度打印文字，并具有出色的耐磨性。此外，本发明还提供了以高印刷密度和宽色彩再现范围形成图像的记录材料，以及具有高印刷密度和优异耐磨性的文字印刷材料（记录材料）。 本发明涉及：一种用于喷墨记录的墨水组，包括至少含有 "可分散在水介质中而不含分散剂的炭黑 "的黑色墨水和水；以及至少含有 "包含有聚合物的彩色颜料的着色剂 "的彩色墨水和水；一种使用该墨水组的喷墨记录工艺，以及由该记录工艺打印的记录物。
• Ink set for ink jet-jet recording , method for ink-jet recording and recorded matter
  申请人：——

  公开号：US20030078320A1

  公开（公告）日：2003-04-24

  Provided are an ink set for ink jet recording and an ink jet recording process, which can provide not only high weather resistance but also images having a high printed density by using pigment inks, and have a wide color reproducing range. Also provided is an ink jet recording process capable of performing text printing at a high printing density and with excellent abrasion resistance. Furthermore, recorded matter having images formed at a high printed density and over a wide color reproducing range, and text printed matter (recorded matter) having a high printed density and being excellent in abrasion resistance are provided. The present invention relates to: an ink set for ink jet recording comprising a black ink containing at least “carbon black dispersible in an aqueous medium without a dispersing agent” and water; and at least one color ink containing at least “a colorant enclosing a color pigment with a polymer” and water; an ink jet recording process using the ink set, and recorded matter printed by the recording process.

  本发明提供了一种用于喷墨记录的墨水组和一种喷墨记录工艺，它不仅具有很高的耐候性，而且还能通过使用颜料墨水提供高印刷密度的图像，并具有很宽的色彩再现范围。此外，还提供了一种喷墨记录工艺，能够以高密度打印文字，并具有出色的耐磨性。此外，本发明还提供了以高印刷密度和宽色彩再现范围形成图像的记录材料，以及具有高印刷密度和优异耐磨性的文字印刷材料（记录材料）。 本发明涉及：一种用于喷墨记录的墨水组，包括至少含有 "可分散在水介质中而不含分散剂的炭黑 "的黑色墨水和水；以及至少含有 "包含有聚合物的彩色颜料的着色剂 "的彩色墨水和水；一种使用该墨水组的喷墨记录工艺，以及由该记录工艺打印的记录物。
• Ink set for ink-jet recording
  申请人：——

  公开号：US20030097961A1

  公开（公告）日：2003-05-29

  The invention provides an ink set for ink jet recording which gives high color density with respect to plain paper and exclusive paper and satisfactory color reproducibility and which has excellent ejection stability and storage stability. An ink jet recording ink set, each ink comprising at least a colorant enclosing a pigment and/or a dye with a polymer, a penetrating agent and water, wherein the ink set comprises a combination of black, yellow, magenta and cyan, or a combination of “black inks, yellow inks, magenta inks, and cyan inks” each inks comprising at least one kind of ink having a different addition concentration, wherein the pigment for the black colorant is C.I. Pigment Black 7, the pigment for the yellow colorant is selected from C.I. Pigment Yellow 55, 74, 110, 128, 150, 155 and 180, the pigment for the magenta colorant is selected from C.I. Pigment Red 122, 202 and 209, and the pigment for the cyan colorant is selected from C.I. Pigment Blue 15, 15:1, 15:2, 15:3, 15:4, 15:6 and 16.

  本发明提供了一种用于喷墨记录的墨水组，该墨水组相对于普通纸和专用纸具有较高的色彩密度和令人满意的色彩再现性，并且具有出色的喷出稳定性和储存稳定性。 一种喷墨记录墨水组，每种墨水至少包括一种着色剂，其中包含颜料和/或染料以及聚合物、渗透剂和水，其中墨水组包括黑色、黄色、品红色和青色的组合，或 "黑色墨水、黄色墨水、品红色墨水和青色墨水 "的组合，每种墨水包括至少一种具有不同添加浓度的墨水，其中用于黑色着色剂的颜料为 C。颜料黑 7，黄色着色剂的颜料选自 C.I.颜料黄 55、74、110、128、150、155 和 180，品红色着色剂的颜料选自 C.I.颜料红 122、202 和 209，青色着色剂的颜料选自 C.I.颜料蓝 15、15:1、15:2、15:3、15:4、15:6 和 16。