二苯基二硫代磷酸铵 | 34669-05-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二苯基二硫代磷酸铵
• 英文名称: ammonium diphenyldithiophosphinate
• 英文别名: ammonium diphenylphosphinodithioate；Azanium;diphenyl-sulfanylidene-sulfido-lambda5-phosphane；azanium;diphenyl-sulfanylidene-sulfido-λ5-phosphane
• CAS: 34669-05-1
• 化学式: C₁₂H₁₀PS₂*H₄N
• 分子量: 267.356
• InChiKey: GWJPQJFVRQRBSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.95
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二苯基二硫代磷酸铵 以 氘代氯仿 、 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Protodemetallation of pyridinephenylmercury(II) compounds by diphenyldithiophosphinic acid. The molecular and crystal structure of [Hg2(S2PPh2)4]

  摘要：

  The reactions of [2-(pyridin-2'-yl)-phenyl]mercury(II) acetate [Hg(PhPy)(OAc)] and [2-(pyridin-2'-yl)-phenyl]mercury(II)diphenyldithiophosphinate [Hg(PhPy)(S2PPh2)] with diphenyldithiophosphinic acid in chloroform at room temperature both led to the cleavage of the C-Hg bond, giving phenylpyridine and [Hg-2(S2PPh2)(4)]. The [Hg(PhPy)(S2PPh2)] reaction was monitored by H-1 NMR spectroscopy. Although the process went smoothly at the beginning, the protodemetallation reaction slowed down as more acid was added. A hypothesis is put forward as to the cause of this loss of effectiveness as protodemetallation progresses. The crystal structure of [Hg-2(S2PPh2)(4)] was solved by X-ray diffraction. This compound crystallizes in the triclinic space group (No. 2) with a=9.150(3), b=10.560(4), c=13.717(5) Angstrom, alpha=93.46(2), beta=102.44(2), gamma=105.34(2)degrees, Z=1. Its structure comprises centrosymmetric dimers, each forming an eight-membered ring in a twisted chair conformation. Each mercury atom is coordinated to one chelating and two bridging ligands, giving rise to a distorted tetrahedral arrangement around the metal, with two short Hg-S bonds of 2.428(2) and 2.467(2) Angstrom and two long ones of 2.678(2) and 2.761(2) Angstrom. Each Hg is also involved in a 3.338 Angstrom long secondary bond across the eight-membered ring. IR, Raman and H-1, P-31 and Hg-199 NMR data for [Hg(PhPy)(S2PPh2)] and [Hg-2(S2PPh2)(4)] are also discussed.

  DOI：

  10.1016/s0020-1693(96)05442-4
• 作为产物：
  描述：

  cyclohexa-2,4-dien-1-yl-phenyl-sulfanyl-sulfanylidene-λ5-phosphane 在 ammonium hydroxide 作用下， 以 甲苯 为溶剂， 反应 18.0h， 以73%的产率得到二苯基二硫代磷酸铵
  参考文献：
  名称：

  三价镧系元素（Ce，Nd，Sm，Eu，Gd，Dy，Yb）与二苯基二硫代次膦酸酯阴离子的配位化学

  摘要：

  鉴于在先进的核燃料循环中使用二硫代次膦酸酯配体从镧系元素中分离出三价次act系元素的前景，了解镧系元素与二硫代次膦酸酯配体之间的配位化学非常重要。此处报道的是一系列镧系元素（Ce，Nd，Sm，Eu，Gd，Dy和Yb）与二苯基二硫代次膦酸酯阴离子S 2 PPh 2 1-的配位化学。在所有情况下，LnCl 3与4当量的S 2 PPh 2 1-进行反应。大镧系元素（Ce 3+，Nd 3+，Sm 3+，Eu 3+）形成了八个通式为Ln（S2 PPh 2）4 1−，并通过1 H和31 P NMR，IR，UV-Vis，元素分析和单晶X射线晶体学进行了表征。对于稍小的Gd 3+和Dy 3+离子，观察到反应性中断。在此，通过1 H和31 P NMR光谱分析反应溶液表明，形成了复杂的混合物，由该混合物形成了8个配位和中性的Gd（S 2 PPh 2）3（NCMe）2和Dy（S 2 PPh 2）3单晶。（NCMe）分离出2种复合物。涉及更小的Yb

  DOI：

  10.1016/j.poly.2013.09.019

文献信息

• Di- and tri-organotin(IV) diphenyldithiophosphinates
  作者：Cristian Silvestru、Florin Illieş、Ionel Haiduc、Marcel Gielen、J.J. Zuckerman

  DOI：10.1016/s0022-328x(00)99045-4

  日期：1987.8

  Di- and tri-organotin(IV) diphenyldithiophosphinates, R2Sn(S2PPh2)2 (R  Me, n-Bu, Bz, Ph) and R3SnS2PPh2 (R  Me, Cy, Bz, Ph) were prepared by reaction of the corresponding organotin chlorides or oxides with diphenyldithiophosphinic acid or its ammonium salt. All the compounds were characterized by IR and 1H NMR spectra. For R2Sn(S2PPh2)2 (R  Me, Ph) and Ph3SnS2PPh2 mass spectra and tin-119m Mössbauer

  二和三有机锡（IV）二苯基二硫代次膦酸酯盐，R 2 Sn（S 2 PPh 2）2（RMe，n-Bu，Bz，Ph）和R 3 SnS 2 PPh 2（RMe，Cy，Bz， Ph）是通过使相应的有机锡氯化物或氧化物与二苯基二硫代次膦酸或其铵盐反应制备的。所有化合物均通过IR和1 H NMR光谱表征。对于R 2 Sn（S 2 PPh 2）2（RMe，Ph）和Ph 3 SnS 2 PPh 2还记录了质谱和119 m锡穆斯堡尔谱。对于三有机锡衍生物，提出了二硫代膦配体和四面体结构的单齿键合，而在二有机锡化合物中，锡周围的八面体几何形状似乎是畸变的，具有异二叉二硫代膦配体。
• Synthesis and structural characterization of diphenldithiophosphinates of methyl- and phenylmercury(II). Crystal structure of MeHgS2PPh2
  作者：J. Zukerman-Schpector、E.M. Vázquez-López、A. Sánchez、J.S. Casas、J. Sordo

  DOI：10.1016/0022-328x(91)83157-y

  日期：1991.3

  Methyl- and phenyl-mercury(II) derivatives of diphenyldithiophosphinic acid (HS2PPh2) have been prepared. The structure of crystalline MeHgS2PPh2 has been determined by X-ray diffraction and shown to consists of MeHgS2PPh2 molecules in which the mercury atom is bound to the methyl group and to one sulphur atom of the ligand, with a further weak intermolecular interaction (secondary bond) with the other

  已经制备了二苯基二硫代次膦酸（HS 2 PPh 2）的甲基和苯基汞（II）衍生物。结晶的MeHgS 2 PPh 2的结构已通过X射线衍射确定，并显示由MeHgS 2 PPh 2分子组成，其中的汞原子与配体的甲基和一个硫原子结合，并且进一步弱与相邻配体的另一个硫原子的分子间相互作用（二级键），使分子成对存在于晶格中。RHgS 2 PPh 2（IR，Raman and 1 H，13 C，31的光谱性质根据X射线结果讨论了P和119 Hg NMR）。
• Metal complexes of sulphur ligands. Part 10. Reaction of mer-trichlorotris(dimethylphenylphosphine)osmium(III) with dimethyldithiocarbamate, dimethyl- and diphenyl-phosphinodithioate, and O-ethyl dithiocarbonate ligands
  作者：David J. Cole-Hamilton、T. Anthony Stephenson

  DOI：10.1039/dt9760002396

  日期：——

  whereas in cold CH2Cl2–C6H13 a different isomeric form of [Os(CO)(PMe2Ph)2(S2PMe2)2](17) is produced. In contrast, reaction of (1) with K[S2COEt] under all conditions gives only mer-[OsCl(PMe2Ph)3(S2COEt)](18). The complexes have been characterised by elemental analyses and mass, i.r., and n.m.r. spectroscopy (1H and 31P), and detailed mechanisms for the overall reaction and the carbonylation of (7) are postulated

  复杂的反应聚体- [OSCL 3（PME 2 PH）3 ]（1）用过量的[S-S]的-离子（S-S - = S 2 CNME 2 -，S 2 PME 2 -小号2 PPH 2 –或S 2 COEt）已被彻底研究。对于[S 2 CNMe 2 ] –，在甲醇中回流90分钟可得到高产率的顺式-[Os（PMe 2 Ph）2（S 2 CNMe 2）2]（2）。而在甲醇中摇动使聚体- [OSCL（PME 2 PH）3 -（S 2 CNME 2）]（3）。（3）在回流的乙醇中与Na [S 2 CNMe 2 ]·2H 2 O反应，得到（2）以及少量的fac- [OsCl（PMe 2 Ph）3（S 2 CNMe 2）]（5）和fac- [Os（OEt）（PMe 2 Ph）3（S 2 CNMe 2）]（6）。而使用K [S 2 COEt]这三个复合物和顺式-[Os（PMe形成2 Ph） 2（S 2 CNMe 2）（S
• Metal complexes of sulphur ligands. Part 14. Reaction of palladium(II) and platinum(II) dithioacid complexes with tertiary phosphinites, and the crystal and molecular structure of dimethylphosphinodithioato(diphenylphosphinito)(diphenylphosphinous acid)palladium(II)
  作者：Margaret C. Cornock、Robert O. Gould、C. Lynn Jones、T. Anthony Stephenson

  DOI：10.1039/dt9770001307

  日期：——

  groups with O ⋯ O 2.41 Å. Similar complexes [M(S–S)(PPh2O)PPh2(OH)}](M = Pd, S–S–=[S2PPh2]– or [S2CNEt2]–; M = Pt, S–S–=[S2PMe2]– or [S2CNEt2]–) have been prepared by reaction of [M(S–S)2] with PPh2(OR) or, for M = Pd, by reaction of [PdCl(PPh2O)[PPh2(OH)]}2] with the appropriate dithioacid anion (1 : 2 molar ratio). A careful study of the [Pt(S2CNEt2)2]–PPh2(OMe) reaction has resulted in the isolation

  [Pd（S 2 PMe 2）2 ]与过量的PPh 2（OR）（R = Me或Et）在二氯甲烷或苯中的长时间反应，得到四配位络合物[Pd（S 2 PMe 2）（光谱证据和X射线结构分析表明，PPh 2 O）PPh 2（OH）}]（1a）含有对称氢键合的Ph 2 POHOPPh 2配体。（1a）的晶体是单斜晶体，空间群P 2 1 / m，a = 6.86（1），b = 22.12（2），c＝ 9.69（1）,，β＝ 111.5（2）°。酸性氢原子用O di O 2.41Å连接两个等效的二苯基亚膦酸酯基团。相似的配合物[M（S–S）（PPh 2 O）PPh 2（OH）}] [M = Pd，S–S – = [S 2 PPh 2 ] –或[S 2 CNEt 2 ] – ; M = Pt，S–S – = [S 2 PMe 2 ] –或[S 2 CNEt 2 ] –）是通过[M（S–S）2 ]与PPh
• Metal complexes of sulphur ligands. Part 15. Reaction of bis[(η-arene)dichlororuthenium] and bis[dichloro(η-pentamethylcyclopentadienyl)metal] complexes of rhodium and iridium with various dithioacid ligands
  作者：Donald R. Robertson、T. Anthony Stephenson

  DOI：10.1039/dt9780000486

  日期：——

  Reaction of the complexes [Ru(η-arene)Cl2}2](1)(arene = C6H6 or C6H3Me3) and [M(η-C5Me5)Cl2}2](2)(M = Rh or Ir) with excess of various dithioacid anions gives monomeric [Ru(η-arene)(S–S)2](3; S–S–=[S2PR2]–) and [M(η-C5Me5)(S–S)2](4: M = Rh, S–S–=[S2PR2]–, [S2CNR2]–, or [S2COR]–; M = Ir, S–S–=[S2CNMe2]– or [S2PMe2]–) respectively. Analytical data together with i.r. and 1H, 13C, and 31P n.m.r. studies

  配合物的反应[茹（η-芳烃）氯2 } 2 ]（1）（芳烃= C 6 H ^ 6或C 6 H ^ 3我3）和[M（η-C 5我5）氯2 } 2 ]（2）（M = Rh或Ir）与过量的各种二硫代酸根阴离子会生成单体[Ru（η-亚芳基）（S–S）2 ]（3; S–S – = [S 2 PR 2 ] –）和[M（η-C 5我5）（S-S）2 ]（4：M = RH，S-S - = [S 2 PR 2 ] -，[S 2 CNR 2 ] –或[S 2 COR] –；M = Ir，SS – = [S 2 CNMe 2 ] –或[S 2 PMe 2 ] –）。分析数据以及ir和1 H，13 C和31 P nmr研究表明，这些配合物在固态和溶液中均包含双齿和单齿二硫代酸基团。对于[M（η-C 5我5）（S 2 CNME 2）2 ]（M =铑或铱）和铑[Rh（η-C5 Me 5）（S 2 COEt） 2 ]