propionic acid-(4-vinyl-phenyl ester)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: propionic acid-(4-vinyl-phenyl ester)
• 英文别名: Propionsaeure-(4-vinyl-phenylester)；4-vinylphenyl propionate；(4-Ethenylphenyl) propanoate
• 化学式: C₁₁H₁₂O₂
• 分子量: 176.215
• InChiKey: CSRKKLRDDUBYNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  propionic acid-(4-vinyl-phenyl ester) 、 H-B(dan) 在 bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 作用下， 以 dioxane 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

  摘要：

  苯乙烯衍生物在阳离子铑配合物存在下，与萘-1,8-二氨基硼烷[(dan)BH]进行脱氢硼化反应，以良好的产率得到了β-硼烷基苯乙烯衍生物。通过逐步交叉耦合反应，利用dan基团作为硼基的有效保护基，制备的具有氯或B(pin)基团的β-硼烷基苯乙烯能够用于合成高度共轭的分子。

  DOI：

  10.1246/cl.2010.558
• 作为产物：
  描述：

  4-香豆酸 在 喹啉 、 铜 作用下， 生成 propionic acid-(4-vinyl-phenyl ester)
  参考文献：
  名称：

  The Preparation of p-Acyloxystyrenes¹

  摘要：

  DOI：

  10.1021/ja01159a035

文献信息

• Polymerizable Fluorine-Containing Compound
  申请人：ISONO Yoshimi

  公开号：US20110098500A1

  公开（公告）日：2011-04-28

  A polymerizable fluorine-containing compound represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 2 represents an acid-labile protecting group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 2 , R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a resist composition capable of forming a pattern that is transparent to exposure light and superior in rectangularity.

  一种可聚合的含氟化合物，其化学式为（1），其中R1表示可聚合的双键含有基团，R2表示酸敏感保护基团，R3表示氟原子或含氟烷基团，W表示二价连接基团。该化合物可以提供一种含氟聚合物化合物，其重均分子量为1,000-1,000,000，并包含由式（2）表示的重复单元，其中R2、R3和W如上所述，R4、R5和R6中的每一个独立地表示氢原子、氟原子或一价有机基团，至少两个R4、R5和R6可以结合形成一个环。该聚合物化合物可以提供一种抗蚀剂组合物，能够形成透明的曝光光线图案，并具有优异的矩形度。
• Fluorine-Containing Compound, Fluorine-Containing Polymer, Negative-Type Resist Composition, and Patterning Process Using Same
  申请人：ISONO Yoshimi

  公开号：US20120226070A1

  公开（公告）日：2012-09-06

  A fluorine-containing unsaturated carboxylic acid represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a chemically amplified resist composition that is transparent to KrF or ArF excimer laser light and has a high resolution and is capable of forming a pattern having a rectangular section with no swelling.

  化学式（1）所表示的含氟不饱和羧酸，其中R1代表可聚合的双键含基团，R3代表氟原子或含氟烷基团，W代表二价连接基团。该化合物可提供一种分子量为1,000-1,000,000且含有化学式（2）所表示的重复单元的含氟聚合物化合物，其中R3和W如上所定义，R4、R5和R6中的每一个独立地代表氢原子、氟原子或一价有机基团，R4、R5和R6中至少有两个可以结合形成环。该聚合物化合物可提供一种化学增强型光刻胶组合物，该组合物对KrF或ArF准分子激光光线透明，具有高分辨率，并能够形成具有矩形截面且无膨胀的图案。
• Fluorine-Containing Compound, Fluorine-Containing Polymer, Postive-Type Resist Composition, And Patterning Process Using Same
  申请人：ISONO Yoshimi

  公开号：US20080311507A1

  公开（公告）日：2008-12-18

  Disclosed is a fluorine-containing compound represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 2 represents an acid-labile protecting group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 2 , R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a resist composition capable of forming a pattern that is transparent to exposure light and superior in rectangularity.

  本发明涉及一种含氟化合物，其化学式为（1），其中R1代表可聚合的双键含基团，R2代表酸易保护基，R3代表氟原子或含氟烷基团，W代表双价连结基团。该化合物可提供一种含氟聚合物化合物，其重均分子量为1,000-1,000,000，并含有由式（2）所表示的重复单元，其中R2、R3和W如上所定义，R4、R5和R6中的每一个独立地代表氢原子、氟原子或一价有机基团，其中至少两个R4、R5和R6可以组成环。该聚合物化合物可提供一种抗蚀剂组合物，能够形成对曝光光线透明且在矩形度方面优越的图案。
• Positive-Type Resist Composition
  申请人：ISONO Yoshimi

  公开号：US20090061353A1

  公开（公告）日：2009-03-05

  Disclosed is a fluorine-containing polymer compound containing first and second repeating units respectively represented by formulas (a-1) and (a-2), wherein R 3 represents a fluorine atom or fluorine-containing alkyl group, each of W and W 1 independently represents a bivalent linking group, R 2 represents an acid-labile protecting group, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, and at least two of R 4 , R 5 , R 6 and W or W 1 may be combined to form a cyclic structure in formula (a-1) or (a-2). This polymer compound has a weight-average molecular weight of 1,000 to 1,000,000 and can provide a resist composition capable of forming a pattern with no swelling and no pattern falling down.

  本发明涉及一种含氟聚合物化合物，其中包含第一和第二重复单元，分别由式（a-1）和（a-2）表示，其中R3表示氟原子或含氟烷基，W和W1各自表示双价连接基团，R2表示酸敏保护基团，R4、R5和R6各自表示氢原子、氟原子或单价有机基团，且式（a-1）或（a-2）中至少两个R4、R5、R6和W或W1可组成环状结构。该聚合物化合物具有1,000至1,000,000的重均分子量，并可提供一种抗膨胀和无图案脱落的光刻胶组合物。
• Electrophoretic Dispersion Liquid and Electrophoretic Display Device
  申请人：Minami Masato

  公开号：US20080136772A1

  公开（公告）日：2008-06-12

  An electrophoretic dispersion liquid for an electrophoretic display apparatus includes a plurality of electrophoretic particles each surface of which is modified by one of a basic group and an acidic group, a liquid for holding said electrophoretic particles to be dispersed therein; and a polydiene, having the other group, dissolved in said liquid.

  一种用于电泳显示装置的电泳分散液，包括多种电泳粒子，每个电泳粒子的表面都被一个基团或一个酸性团修饰，用于容纳所述电泳粒子以分散其中的液体；以及溶解在所述液体中的具有另一种团的聚二烯。