亚甲基双(硫乙醇酸)二丁酯 | 14338-82-0

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 亚甲基双(硫乙醇酸)二丁酯
• 中文别名: 亚甲基双(硫代乙醇酸二-n-丁酯)；2,2’-(亚甲基双(硫代)二乙酸二丁酯；2,2"-(亚甲基双(硫代)二乙酸二丁酯
• 英文名称: Acetic acid, 2,2'-[methylenebis(thio)]bis-, dibutyl ester
• 英文别名: butyl 2-[(2-butoxy-2-oxoethyl)sulfanylmethylsulfanyl]acetate
• CAS: 14338-82-0
• 化学式: C₁₃H₂₄O₄S₂
• 分子量: 308.5
• InChiKey: QCWRDNFBMVSDEY-UHFFFAOYSA-N

物化性质

• 沸点：
  178 °C / 1mmHg
• 密度：
  1.09
• 闪点：
  167 °C
• LogP：
  4.27 at 30℃

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2930909090

文献信息

• (METH)ACRYLOYL-TERMINATED POLYISOBUTYLENE POLYMER, METHOD FOR PRODUCING THE SAME, AND ACTIVE ENERGY RAY-CURABLE COMPOSITION
  申请人：KANEKA CORPORATION

  公开号：US20140243444A1

  公开（公告）日：2014-08-28

  The purpose of the present invention is to provide a polymer having a low halogen atom content remaining in the polymer, a simple production method thereof, an active energy ray-curable composition that can be rapidly cured by an irradiation of a small amount of light, and a cured product thereof. These purpose can be achieved by an active energy ray-curable composition, including a polyisobutylene polymer (A) represented by the following general formula (1) (wherein R 1 represents a monovalent or polyvalent aromatic hydrocarbon group, or a monovalent or a polyvalent aliphatic hydrocarbon group; A represents a polyisobutylene polymer; R 2 represents a divalent saturated hydrocarbon group having 2-6 carbon atoms, which contains no hetero atoms; R 3 and R 4 each represent hydrogen, a monovalent hydrocarbon group having 1-20 carbon atoms, or an alkoxy group having 1-20 carbon atoms; R 5 represents hydrogen or a methyl group; and n denotes a natural number), and an active energy ray polymerization initiator (B).

  本发明的目的是提供一种聚合物，其聚合物中保留有较低的卤素原子含量，以及其简单的生产方法，一种能够通过少量光辐照快速固化的活性能量射线固化组合物以及其固化产物。这些目的可以通过一种活性能量射线固化组合物来实现，包括以下通式（1）所表示的聚异丁烯聚合物（A）（其中R1表示单价或多价芳香烃基或单价或多价脂肪烃基；A表示聚异丁烯聚合物；R2表示含有2-6个碳原子的二价饱和碳氢基团，不含杂原子；R3和R4分别表示氢、具有1-20个碳原子的单价碳氢基团或具有1-20个碳原子的烷氧基；R5表示氢或甲基基团；n表示自然数），以及活性能量射线聚合引发剂（B）。
• A mult-component copolymer rubber, a process for producing the same, and a rubber composition containing the multi-component copolymer rubber
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0160399A2

  公开（公告）日：1985-11-06

  A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyanosubstituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. These properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.

  一种多组分共聚橡胶主要由以下物质组成：(A) 20 至 69.5%（按重量计）氰基取代的烷基（甲基）丙烯酸酯；(B) 30 至 79.5%（按重量计）丙烯酸烷基酯；(C) 0.5 至 10%（按重量计）可交联单体；(D) 0 至 10%（按重量计）可与(A)、(B)和(C)共聚的其他乙烯基不饱和单体，该橡胶具有优异的耐热性、耐臭氧性、耐酸汽油性和耐酸汽油醇性。通过在共聚橡胶中加入交联剂、金属盐、偏氟乙烯聚合物、氯乙烯树脂或其他多组分共聚橡胶，可进一步改善所述多组分共聚橡胶的上述性能。
• Vulcanizable rubber compositions and applications thereof
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0194030A2

  公开（公告）日：1986-09-10

  A vulcanizable rubber composition comprises (1) 100 parts by weight of a polymer composition comprising (I) a vinylidene fluoride resin, (II) at least one acrylic rubber, a,p-unsaturated nitrile-conjugated diene copolymer rubber or hydride of an a,p-unsaturated nitrile-conjugated diene copolymer rubber, (III) another blendable polymer, wherein the weight ratio of (I)/[(II) + (III)] is from 5/95 to 60/ 40 and the weight ratio of (II)/(III) is from 100/0 to 50/50, and (2) from 0 to 40 by weight of a plasticizer. Said rubber composition excels not only in heat resistance, gasoline resistance and sour gasoline resistance but also in gasohol resistance and sour gasohol resistance and further has good tensile strength, elongation and balance between gasoline resistance and low-temperature resistance. Therefore, it can be used in the fluid-contacting surface of a diaphragm or as an inner tube of a fuel hose.

  一种可硫化橡胶组合物包括 (1) 100 重量份的聚合物组合物，其中包括 (I) 亚乙烯基氟化树脂、 (II) 至少一种丙烯酸橡胶、a,p-不饱和腈-共轭二烯共聚物橡胶或 a,p-不饱和腈-共轭二烯共聚物橡胶的氢化物、 (III) 另一种可混合聚合物、 其中(I)/[(II)+(III)]的重量比为 5/95 至 60/40，(II)/(III)的重量比为 100/0 至 50/50，以及 (2) 增塑剂的重量比为 0 至 40。上述橡胶组合物不仅在耐热性、耐汽油性和耐酸汽油性方面表现出色，而且在耐煤气醇性和耐酸煤气醇性方面也表现出色，并具有良好的拉伸强度、伸长率以及耐汽油性和耐低温性之间的平衡。因此，它可用于隔膜的流体接触面或作为燃油软管的内管。
• Rubber laminate
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0419218A2

  公开（公告）日：1991-03-27

  A rubber laminate wherein a rubber layer (1) consisting of the following rubber compound (a) and a rubber layer (2) consisting of the following rubber compound (b) have been strongly bonded to each other by vulcanization: (a) a rubber compound consisting essentially of 100 parts by weight of an acrylic blend rubber, 20-30 parts by weight of a plasticizer comprising at least a phosphate type plasticizer and, as a vulcanizing agent, a diamine carbamate compound and 1-orthotolylbiguanide, the acrylic blend rubber consisting of (I) an acrylic rubber composed of (A) 7.0-69.9% by weight of an alkyl acrylate, (B) 30.0-70.0% by weight of an alkoxy-substituted alkyl acrylate, (C) 0.1-3.0% by weight of an epoxy group-containing ethylenically unsaturated compound, and (D) 0-20.0% by weight of other ethylenically unsaturated compound copolymerizable with the (A), (B) and (C) componentsand (II) a vinylidene fluoride resin, the weight ratio of the acrylic rubber (I)/the vinylidene fluoride resin (II) in the acrylic blend rubber being 85/15 to 75/25, (b) a rubber compound consisting essentially of 100 parts by weight of an acrylic rubber (III) and 20-40 parts by weight of a plasticizer [the proportion of the plasticizer is equal to or larger than the proportion of the plasticizer in the rubber compound (a)], the acrylic rubber (III) being composed of (E) 1.0-49.9% by weight of an alkyl acrylate, (F) 50.0080.0% by weight of an alkoxy-substituted alkyl acrylate, (G) 0.1-3.0% by weight of an epoxy group-containing ethylenically unsaturated compound, and (H) 0-20.0% by weight of other ethylenically unsaturated compound copolymerizable with the (E), (F) and (G) components[the proportion of the (F) component is equal to or larger than the proportion of the (B) component in the acrylic rubber (I)]. The above laminate is superior in flexibility and has a high interlaminar strength. The laminate is also superior in heat resistance, sour gasoline resistance and resistance to alcohol-containing gasoline and accordingly is highly suited for use as a material for fuel hoses of automobiles.

  一种橡胶层压板，其中由以下橡胶化合物（a）组成的橡胶层（1）和由以下橡胶化合物（b）组成的橡胶层（2）已通过硫化牢固地粘合在一起： (a) 一种橡胶复合物，主要由 100 份（按重量计）丙烯酸混合橡胶、20-30 份（按重量计）增塑剂组成，增塑剂至少包括磷酸盐型增塑剂，以及作为硫化剂的氨基甲酸二胺化合物和 1-正甲苯基双胍，丙烯酸混合橡胶包括 (I) 一种丙烯酸橡胶，由以下成分组成 (A) 7.0-69.9%（重量百分比）丙烯酸烷基酯、 (B) 30.0-70.0%(重量)的烷氧基取代的丙烯酸烷基酯、 (C) 0.1-3.0%（重量百分比）的含环氧基的乙烯基不饱和化合物，和 (D) 0-20.0%（重量）可与(A)、(B)和(C)组分共聚的其他乙烯基不饱和化合物和 (II)偏氟乙烯树脂，丙烯酸混炼橡胶(I)/偏氟乙烯树脂(II)在丙烯酸混炼橡胶中的重量比为 85/15 至 75/25、 (b) 主要由 100 份（重量）丙烯酸橡胶（III）和 20-40 份（重量）增塑剂组 成的橡胶复合物[增塑剂的比例等于或大于橡胶复合物（a）中增塑剂的 比例]，丙烯酸橡胶（III）由以下成分组成 (E) 1.0-49.9%（重量百分比）的丙烯酸烷基酯、 (F) 50.0080.0%（重量百分比）的烷氧基取代的丙烯酸烷基酯、 (G) 0.1-3.0%（重量百分比）含环氧基的乙烯基不饱和化合物，及 (H) 0-20.0%（重量）可与(E)、(F)和(G)组分共聚的其他乙烯基不饱和化合物[(F)组分的比例等于或大于丙烯酸橡胶(I)中(B)组分的比例]。 上述层压板具有优异的柔韧性和较高的层间强度。该层压材料的耐热性、耐酸性汽油性和耐含酒精汽油性也很出色，因此非常适合用作汽车燃油软管的材料。
• A method of preparation of foamed articles of polyvinyl chloride resins
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0510521A2

  公开（公告）日：1992-10-28

  Foamed articles of polyvinyl chloride resins are prepared by mixing an organic foaming agent having a temperature of foaming by decomposition of 100°C or above and a plasticizer with a polyvinyl chloride resin containing epoxy group which is formed into particles having an average diameter in the range from 0.05 to 5 µm and has a concentration of the epoxy group at the surface of the particle of 1×10⁻² weight % or more and a concentration of the total epoxy group in the particles of the said resin of 10 weight % or less at a temperature where the organic foaming agent does not decompose and coating or molding the mixed compound with foaming by heating. Foamed articles of polyvinyl chloride resins having excellent physical properties and high expansion ratios can be prepared without utilizing a crosslinking agent at the ambient pressure.

  聚氯乙烯树脂发泡制品的制备方法是将分解发泡温度为 100℃或以上的有机发泡剂和增塑剂与含有环氧基团的聚氯乙烯树脂混合，形成平均直径为 0.05 至 5 微米的颗粒，颗粒表面的环氧基团浓度为 1×10-² 重量％或以上，上述树脂颗粒中的总环氧基团浓度为 1×10-² 重量％或以上。在有机发泡剂不分解的温度下，颗粒表面的环氧基团浓度为 1×10-² 重量％或以上，上述树脂颗粒中的总环氧基团浓度为 10 重量％或以下，并通过加热将混合化合物涂覆或成型发泡。 在环境压力下，无需使用交联剂，即可制备出物理性能优异、膨胀率高的聚氯乙烯树脂发泡制品。

表征谱图