N,N-diallyldecanamide

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N,N-diallyldecanamide
• 英文别名: N,N-bis(prop-2-enyl)decanamide
• 化学式: C₁₆H₂₉NO
• 分子量: 251.412
• InChiKey: QMOBKDDFCHVOJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-ethoxydec-1-yne 、 二烯丙基胺 以 甲苯 为溶剂， 反应 0.17h， 以87%的产率得到N,N-diallyldecanamide
  参考文献：
  名称：

  Ketenes在流动中的产生和诱捕。

  摘要：

  酮基是通过在流动条件下热解烷氧基炔烃而生成的，然后用胺和醇截留以干净地得到酰胺和酯。在10分钟的反应时间内，分别需要180、160和140摄氏度的温度才能分别使EtO，iPrO和tBuO烷氧基炔烃的转化率> 95％。温度和流速的变化以及通过红外光谱对输出的在线监测使得可以容易地估计用于1-乙氧基-1-辛炔转化的动力学参数（E a = 105.4 kJ / mol）。用醇捕集原位生成的乙烯酮以得到酯，需要添加叔胺催化剂以防止将乙烯酮竞争性地[2 + 2]加成至烷氧基炔烃前体。

  DOI：

  10.1002/ejoc.201403603

文献信息

• Vernetzung von Styrolpolymeren
  申请人：Luperox GmbH

  公开号：EP0180789A1

  公开（公告）日：1986-05-14

  Gegebenenfalls im Kern substituierte Styrolpolymere werden mit Kombinationen aus Vernetzungsverstärkern, die wenigstens zwei polymerisierbare C-C-Doppel- oder -Dreifachbindungen im Molekül enthalten, und organischen Peroxiden (ausgenommen Hydroperoxide, Persäuren und Ketonperoxide) mit einer 10-Stunden-Halbwertszeit-Temperatur unterhalb 106°C bei Temperaturen über 110°C vernetzt.

  核心部分可能被取代的苯乙烯聚合物在 110°C 以上的温度下，用分子中至少含有两个可聚合的 C-C 双键或三键的交联促进剂和 10 小时半衰期温度低于 106°C 的有机过氧化物（不包括氢过氧化物、过酸和酮过氧化物）的组合进行交联。
• BIOCIDAL AZOLE EMULSION CONCENTRATES HAVING HIGH ACTIVE INGREDIENT CONTENT
  申请人：Phibro-Tech Inc.

  公开号：EP2043446A2

  公开（公告）日：2009-04-08
• Biocidal azole emulsion concentrates having high active ingredient content
  申请人：Pompeo P. Michael

  公开号：US20070270612A1

  公开（公告）日：2007-11-22

  A concentrated stable emulsifiable formulation includes A) an amide, B) a water-soluble non-ionic emulsifier, C) a water-insoluble anionic emulsifier, and D) a water-insoluble biocidal azole, wherein the concentrated stable emulsifiable formulation is a solution containing the water-insoluble biocidal azole in an amount greater than 20% by weight of the formulation. An aqueous wood treatment composition which can be made for example from the concentrated stable emulsifiable formulation includes emulsified droplets containing at least one water-insoluble biocidal azole s and an amide such as N,N-dialkyloctanamide, N,N-dialkyldecanamide, N-alkyloctanamide, N-alkyldecanamide, octanamide, decanamide, or mixture thereof, where the alkyl groups independently comprise between one and three carbon atoms.
• Use of fast-release pristinamycin-type and polyether ionophore type antimicrobial agents in the production of ethanol
  申请人：Bayrock P. Dennis

  公开号：US20080003660A1

  公开（公告）日：2008-01-03

  A method of controlling microorganisms such as lactobacilli metabolism in mash in an ethanol production facility includes adding to the mash an effective amount to control such microorganisms of one or more of a substantially water insoluble pristinamycin-type antimicrobial agent, a substantially water insoluble polyether ionophore antimicrobial agent, or both, wherein the term “substantially water insoluble” means the antimicrobial agent has a solubility in pure water at 20° C. of 0.1 grams per liter or less, and wherein at least a portion of the substantially water insoluble antimicrobial agent(s) is added to the mash in the form of particles comprising said substantially water insoluble antimicrobial agent(s) and having a weight mean average diameter of less than 5 microns. Particles having a weight mean diameter between 0.1 and 1 microns are preferred.
• Use of pre-dissolved pristinamycin-type and polyether ionophore type antimicrobial agents in the production of ethanol
  申请人：Bayrock P. Dennis

  公开号：US20080003215A1

  公开（公告）日：2008-01-03

  A method of controlling microorganisms such as lactobacilli metabolism in mash in an ethanol production facility includes adding to the mash an effective amount to control such microorganisms of one or more of a substantially water insoluble pristinamycin-type antimicrobial agent, a substantially water insoluble polyether ionophore antimicrobial agent, or both, wherein the term “substantially water insoluble” means the antimicrobial agent has a solubility in pure water at 20° C of 0.1 grams per liter or less, and wherein at least a portion of the substantially water insoluble antimicrobial agent(s) is added to the mash in the form of: 1) an organic liquid comprising at least one organic solvent having said substantially water insoluble antimicrobial agent(s) dissolved therein, said organic liquid advantageously comprising more than 1 gram per liter of said antimicrobial agent(s); 2) particles comprising said substantially water insoluble antimicrobial agent(s) and having a weight mean average diameter of less than 5 microns; or 3) both.