oleic estolide 2,2-dimethyl-1-propyl ester

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: oleic estolide 2,2-dimethyl-1-propyl ester
• 英文别名: 2,2-dimethylpropyl 9-[(Z)-octadec-9-enoyl]oxyoctadecanoate
• 化学式: C₄₁H₇₈O₄
• 分子量: 635.068
• InChiKey: UJRMFFNPEGELCS-ZCXUNETKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.4
• 重原子数：
  45
• 可旋转键数：
  36
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  油酸 在 高氯酸 、 磷酸 作用下， 以 甲苯 为溶剂， 反应 24.0h， 生成 oleic estolide 2,2-dimethyl-1-propyl ester
  参考文献：
  名称：

  从顺式-9-十八烯酸雌二醇合成乙内酯

  摘要：

  AbstractOleic acid (cis‐9‐octadecenoic acid) was converted in excellent yield to the estolide, which was then esterified with 2,2‐dimethypropan‐1‐ol (neopentyl alcohol), cis‐9‐octadence‐1‐ol (oleyl alcohol), and 2‐propanol to generate the corresponding estolide esters. Higher‐formula mass estolide esters were synthesized by reaction of the parent estolide with 1,3‐propanediol, 2,2‐dimethyl‐1,3‐propanediol, and 1,5‐pentanediol to give the corresponding diesters of oleic estolide, thus doubling the molecular size of the parent estolide. Pour points and viscosities were determined in order to evaluate these products for possible industrial application.

  DOI：

  10.1007/s11746-001-0248-5

文献信息

• Synthesis of estolide esters from cis-9-octadecenoic acid estolides
  作者：Rogers E. Harry-O kuru、Terry A. Isbell、David Weisleder

  DOI：10.1007/s11746-001-0248-5

  日期：2001.3

  AbstractOleic acid (cis‐9‐octadecenoic acid) was converted in excellent yield to the estolide, which was then esterified with 2,2‐dimethypropan‐1‐ol (neopentyl alcohol), cis‐9‐octadence‐1‐ol (oleyl alcohol), and 2‐propanol to generate the corresponding estolide esters. Higher‐formula mass estolide esters were synthesized by reaction of the parent estolide with 1,3‐propanediol, 2,2‐dimethyl‐1,3‐propanediol, and 1,5‐pentanediol to give the corresponding diesters of oleic estolide, thus doubling the molecular size of the parent estolide. Pour points and viscosities were determined in order to evaluate these products for possible industrial application.