methoxyphenyl oxime

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methoxyphenyl oxime
• 英文别名: oxime methoxy phenyl；methyl N-hydroxybenzenecarboximidate；methyl N-hydroxybenzene carboximidoate；Methyl benzhydroximate
• 化学式: C₈H₉NO₂
• 分子量: 151.165
• InChiKey: HUYDCTLGGLCUTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  41.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trans-[PtCl4(propiononitrile)2] 、 methoxyphenyl oxime 以 二氯甲烷 为溶剂， 生成 [PtCl4(NH=C(Et)ON=C(OMe)Ph)2]
  参考文献：
  名称：

  The metalla-Pinner reaction between Pt(iv)-bound nitriles and alkylated oxamic and oximic forms of hydroxamic acids

  摘要：

  、N、O、S、P、F、Cl、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I

  DOI：

  10.1039/b406600f
• 作为产物：
  描述：

  来福灵 在 双氧水 作用下， 以 甲醇 、 水 为溶剂， 反应 4.0h， 生成 1-烯丙基-4-氯苯 、 1-氯-4-乙基苯 、 4-氯苯乙醇 、 2-(4-氯苯基)-3-甲基丁酸 、 3-(p-chlorophenyl)-1-butene 、 3-苯氧基苯甲酸 、 4-(氯甲基)苯乙酸 、 间苯氧基苯甲醛 、 4-氯苯甲醇 、 methoxyphenyl oxime
  参考文献：
  名称：

  Screening of By-Products of Esfenvalerate in Aqueous Medium Using SBSE Probe Desorption GC-IT-MS Technique

  摘要：

  The pyrethroids, their metabolites and by-products have been recognized as toxic to environment and human health. Despite several studies about esfenvalerate toxicity and its detection in water and sediments, information about its degradation products is still scanty. In this work, esfenvalerate degradation products were obtained by chemical oxidation with hydrogen peroxide and their structure was elucidated using a procedure known as stir bar sorptive extraction (SBSE) probe desorption gas chromatography-ion trap mass spectrometry (GC-IT-MS) analysis. This procedure consists of the thermal desorption of analytes extracted from a SBSE stir bar introduced by a probe into a gas chromatograph (GC) coupled to an ion trap mass spectrometry (IT-MS) system. Based on IT-MS data, a degradation pathway of esfenvalerate is proposed with ten products of chemical oxidation of esfenvalerate that are fully identified. Among these compounds, 3-phenoxybenzoic acid and 3-phenoxybenzaldehyde were detected, reported as being environmental metabolites of some pyrethroids, with endocrine-disrupting activity.

  DOI：

  10.5935/0103-5053.20150160

文献信息

• 0-(2,3-Epoxypropyl)-hydroximic acid esters
  申请人：Hoechst Aktiengesellschaft

  公开号：US04150043A1

  公开（公告）日：1979-04-17

  Compounds of general formula ##STR1## wherein R.sup.1 represents a radical selected from the group consisting of an alkyl group having from 1 to 6 carbon atoms, an unsubstituted aryl group having 6 carbon atoms, an aryl group having 6 carbon atoms being substituted by at least one radical selected from the group consisting of a chlorine atom, alkyl and alkoxy each having up to 2 carbon atoms; and R.sup.2 represents an alkyl group having from 1 to 6 carbon atoms.

  一般式为##STR1##的化合物，其中R.sup.1代表从以下组中选择的基团：1至6个碳原子的烷基基团，6个碳原子的未取代芳基基团，6个碳原子的芳基基团，被至少一个从以下组中选择的基团取代：氯原子、每个具有最多2个碳原子的烷基和烷氧基；而R.sup.2代表1至6个碳原子的烷基基团。
• A new series of broad-spectrum β-methoxyacrylate fungicides with an oxime ether side-chain
  作者：Paul J. De Fraine、John M. Clough

  DOI：10.1002/ps.2780440112

  日期：1995.5
• [EN] AUXINIC HERBICIDES AND METHODS OF USE THEREOF<br/>[FR] HERBICIDES AUXINIQUES ET LEURS PROCÉDÉS D'UTILISATION
  申请人：[en]CORTEVA AGRISCIENCE LLC

  公开号：WO2022170075A1

  公开（公告）日：2022-08-11

  At least some aspects of this disclosure include one or more auxinic herbicides with relatively low volatility. Some of these compounds may be especially useful when used in the process of growing commercially important plants. Methods for using these actives to control the growth and spread of unwanted plants and/or to hasten the growth of desirable plants are also disclosed herein.
• Screening of By-Products of Esfenvalerate in Aqueous Medium Using SBSE Probe Desorption GC-IT-MS Technique
  作者：Renata Colombo、Tanare C. R. Ferreira、Janete H. Yariwake、Marcos R. V. Lanza

  DOI：10.5935/0103-5053.20150160

  日期：——

  The pyrethroids, their metabolites and by-products have been recognized as toxic to environment and human health. Despite several studies about esfenvalerate toxicity and its detection in water and sediments, information about its degradation products is still scanty. In this work, esfenvalerate degradation products were obtained by chemical oxidation with hydrogen peroxide and their structure was elucidated using a procedure known as stir bar sorptive extraction (SBSE) probe desorption gas chromatography-ion trap mass spectrometry (GC-IT-MS) analysis. This procedure consists of the thermal desorption of analytes extracted from a SBSE stir bar introduced by a probe into a gas chromatograph (GC) coupled to an ion trap mass spectrometry (IT-MS) system. Based on IT-MS data, a degradation pathway of esfenvalerate is proposed with ten products of chemical oxidation of esfenvalerate that are fully identified. Among these compounds, 3-phenoxybenzoic acid and 3-phenoxybenzaldehyde were detected, reported as being environmental metabolites of some pyrethroids, with endocrine-disrupting activity.
• The metalla-Pinner reaction between Pt(<scp>iv</scp>)-bound nitriles and alkylated oxamic and oximic forms of hydroxamic acids
  作者：Konstantin V. Luzyanin、Vadim Yu. Kukushkin、Matti Haukka、J. J. R. Fraústo da Silva、Armando J. L. Pombeiro

  DOI：10.1039/b406600f

  日期：——

  The nitrile ligands in the platinum(IV) complexes trans-[PtCl4(RCN)2] (R = Me, Et, CH2Ph) and cis/trans-[PtCl4(MeCN)(Me2O)] are involved in a metalla-Pinner reaction with N-methylbenzohydroxamic acid (N-alkylated form of hydroxamic acid, hydroxamic form; F1), PhC(O)N(Me)OH, to achieve the imino species [PtCl4NHC(R)ON(Me)C(O)Ph}2] (1–3) and [PtCl4NHC(Me)ON(Me)C(O)Ph}(Me2O)] (7), respectively. Treatment of trans-[PtCl4(RCN)2] (R = Me, Et) and cis/trans-[PtCl4(MeCN)(Me2O)] with the O-alkylated form of a hydroxamic acid (hydroximic form), i.e. methyl 2,4,6-trimethylbenzohydroximate, 2,4,6-(Me3C6H2)C(OMe)NOH (F2A), allows the isolation of [PtCl4NHC(R)ONC(OMe)(2,4,6-Me3C6H2)}2] (5, 6) and [PtCl4NHC(Me)ONC(OMe)(2,4,6-Me3C6H2)}(Me2O)] (8), correspondingly. In accord with the latter reaction, the coupling of nitriles in trans-[PtCl4(EtCN)2] with methyl benzohydroximate, PhC(OMe)NOH (F2B), gives [PtCl4NHC(Et)ONC(OMe)Ph}2] (4). The addition proceeds faster with the hydroximicF2, rather than with the hydroxamic form F1. The complexes 1–8 were characterized by C, H, N elemental analyses, FAB+ mass-spectrometry, IR, 1H and 13C1H} NMR spectroscopies. The X-ray structure determinations have been performed for both hydroxamic and hydroximic complexes, i.e. 2 and 6, indicating that the imino ligands are mutually trans and they are in the E-configuration.

  、N、O、S、P、F、Cl、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I、Na、K、Li、Mg、Al、Si、Fe、Ni、Co、Mn、Cu、Zn、Y、Nb、Ta、W、Re、Os、Ir、Pt、Rh、Ru、Ag、Au、Hg、Cd、Te、Bi、Po、Sn、Ge、As、Se、Br、I