4-octyl nitrate

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: 4-octyl nitrate
• 英文别名: 4-Octyl nitrate；octan-4-yl nitrate
• 化学式: C₈H₁₇NO₃
• 分子量: 175.228
• InChiKey: KXDZDQGNGXHCGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-辛醇 在 硫酸 、 硝酸 作用下， 生成 4-octyl nitrate
  参考文献：
  名称：

  Schneider, Manfred; Ballschmiter, Karlheinz, Chemistry - A European Journal, 1996, vol. 2, # 5, p. 539 - 544

  摘要：

  DOI：

文献信息

• Anti-Markovnikov hydrochlorination and hydronitrooxylation of α-olefins via visible-light photocatalysis
  作者：Jungwon Kim、Xiang Sun、Boris Alexander van der Worp、Tobias Ritter

  DOI：10.1038/s41929-023-00914-7

  日期：——

  that utilize radical intermediates have been demonstrated, but only for activated alkenes, and the direct use of aqueous mineral acids remains elusive. Here we present anti-Markovnikov addition reactions of aqueous hydrochloric and nitric acid to unactivated alkenes. The transformation is enabled by the in situ generation of photoredox-active ion pairs, derived from acridine and the mineral acid, as

  α-烯烃与无机酸的常规加氢官能化以 Markovnikov 选择性进行，以提供支化异构体。线性结构异构体的直接形成具有挑战性，但反马尔可夫尼科夫加成对合成商品化学品很有价值，例如伯醇，目前只能通过化学计量氧化还原反应获得，完全等量地浪费氧化剂和还原剂。利用自由基中间体的策略已经得到证明，但仅适用于活化的烯烃，直接使用无机酸水溶液仍然难以捉摸。在这里，我们介绍了盐酸和硝酸水溶液与未活化烯烃的反马尔可夫尼科夫加成反应。这种转化是通过原位产生光氧化还原活性离子对实现的，衍生自吖啶和无机酸，作为电荷转移和相转移的组合催化剂。氢原子转移催化剂的引入使我们能够绕过源自高键离解能的盐酸和硝酸具有挑战性的链增长。
• Multifunctional additive compositions enabling middle distillates to be operable in cold conditions
  申请人：——

  公开号：US20030163951A1

  公开（公告）日：2003-09-04

  The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (I) wherein: R 1 and R 2 , and R 4 and R 5 , R 3 and R 6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.

  本发明涉及一种能使燃料在寒冷条件下使用的多功能添加剂，它由至少一种二羧酸化合物与至少一种烯烃的共聚物组成，其中接枝有通式(I)的含氮官能团和/或酯，其中：R 1 和 R 2 和 R 4 和 R 5 , R 3 和 R 6 是氢或烷基，x 选自胺盐和 N-烷基多烯丙基多胺及其单羟基化和多羟基化衍生物、N-烷基多烯丙基多胺烷基酯和酯类，以及烷基胺和 N-烷基多烯丙基多胺。
• Alkyl nitrate formation from the nitrogen oxide (NOx)-air photooxidations of C2-C8 n-alkanes
  作者：Roger Atkinson、Sara M. Aschmann、William P. L. Carter、Arthur M. Winer、James N. Pitts

  DOI：10.1021/j100220a022

  日期：1982.11
• Octane Oxidation into Carboxylic Acids
  作者：N.V. Svetlakov、V.G. Nikitin、E.A. Nikolaeva

  DOI：10.1007/s11178-005-0323-7

  日期：2005.8
• MULTIFUNCTIONAL ADDITIVE COMPOSITIONS ENABLING MIDDLE DISTILLATES TO BE OPERABLE IN COLD CONDITIONS
  申请人：Eydoux Frank G.

  公开号：US20080244964A1

  公开（公告）日：2008-10-09

  The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (1) wherein: R 1 and R 2 , and R 4 and R 5 , R 3 and R 6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.