1,2-dichlorodilauroyoxylstannane

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,2-dichlorodilauroyoxylstannane
• 英文别名: [Dichloro(dodecanoyloxy)stannyl] dodecanoate；[dichloro(dodecanoyloxy)stannyl] dodecanoate
• 化学式: C₂₄H₄₆Cl₂O₄Sn
• 分子量: 588.243
• InChiKey: NZOBSPMVBUYLGA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  6.31
• 重原子数：
  31
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,2-dichlorodilauroyoxylstannane 、 dibutylstannane 在 bis-triphenylphosphine-palladium(II) chloride sodium acetate 作用下， 以 正戊烷 为溶剂， 生成 1,1,2,2-Tetrabutyl-1,2-didodecanoyloxy-dizinn
  参考文献：
  名称：

  Air activated organotin catalysts for silicone curing and polyurethane preparation

  摘要：

  Upon exposure to air, 1,2-bis(acyloxy)tetraalkyldistannanes incorporated in mixtures of either silicone oils and curing agent, or of isocyanates and alcohols, are oxidized to 1,3-bis(acyloxy)tetraalkyldistannoxanes which show excellent catalytic properties for curing silicones or for preparing polyurethanes. Under nitrogen, they induce longer pot-lives than the usual bis(acyloxy)dialkylstannane catalysts. Peralkyl-polycyclostannanes, obtained either by the palladium-catalyzed decomposition of dialkylstannanes or by reduction of dichlorodialkylstannanes with metals, are also very good latent catalysts for silicone curing. When incorporated into reactive mixtures under nitrogen, they do not catalyze the condensation. Upon exposure to air, they are oxidized to active catalysts which cure silicones. These di- or polystannanes can be considered air-activated latent organotin catalysts.

  DOI：

  10.1021/om00015a042

文献信息

• Air activated organotin catalysts for silicone curing and polyurethane preparation
  作者：Bernard Jousseaume、Nicolas Noiret、Michel Pereyre、Annie Saux、Jean Marc Frances

  DOI：10.1021/om00015a042

  日期：1994.3

  Upon exposure to air, 1,2-bis(acyloxy)tetraalkyldistannanes incorporated in mixtures of either silicone oils and curing agent, or of isocyanates and alcohols, are oxidized to 1,3-bis(acyloxy)tetraalkyldistannoxanes which show excellent catalytic properties for curing silicones or for preparing polyurethanes. Under nitrogen, they induce longer pot-lives than the usual bis(acyloxy)dialkylstannane catalysts. Peralkyl-polycyclostannanes, obtained either by the palladium-catalyzed decomposition of dialkylstannanes or by reduction of dichlorodialkylstannanes with metals, are also very good latent catalysts for silicone curing. When incorporated into reactive mixtures under nitrogen, they do not catalyze the condensation. Upon exposure to air, they are oxidized to active catalysts which cure silicones. These di- or polystannanes can be considered air-activated latent organotin catalysts.