十一烷-1-醇硝酸盐 | 73377-37-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 中文名称: 十一烷-1-醇硝酸盐
• 英文名称: Undecyl nitrate
• 英文别名: 1-nitrooxy-undecane；nitric acid undecyl ester；Undecylnitrat
• CAS: 73377-37-4
• 化学式: C₁₁H₂₃NO₃
• 分子量: 217.309
• InChiKey: VTALQOYOTZKULH-UHFFFAOYSA-N

物化性质

• 沸点：
  265.6±3.0 °C(Predicted)
• 密度：
  0.947±0.06 g/cm3(Predicted)
• 保留指数：
  1513

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  十一烷醇 在 硫酸 、 硝酸 作用下， 生成 十一烷-1-醇硝酸盐
  参考文献：
  名称：

  Schneider, Manfred; Ballschmiter, Karlheinz, Chemistry - A European Journal, 1996, vol. 2, # 5, p. 539 - 544

  摘要：

  DOI：

文献信息

• Compression ignition fuels, compositions and additive packages for the production thereof and the use thereof
  申请人：ETHYL CORPORATION

  公开号：EP0133375A2

  公开（公告）日：1985-02-20

  Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel into which has been blended suitable concentrations of (a) organic nitrate ignition accelerator, (b) copolymer of an alpha-olefin having from 8 to 30 carbon and an N-substituted maleimide wherein the n-substituents are organic radicals having from 3 to 60 carbons and from 1 to 5 amine nitrogens, said copolymer having from 4 to 20 repeating olefin-maleimide units, and (c) hydrocarbyl amine having from 3 to 60 carbons and from 1 to 10 nitrogens.

  间接喷射压缩点火发动机喷油器喷嘴内部和周围的结焦可以通过馏分燃料来减少，在馏分燃料中掺入适当浓度的以下物质：(a) 有机硝酸盐点火促进剂；(b) 具有 8 至 30 个碳原子的α-烯烃和 N-取代的马来酰亚胺的共聚物，其中 n-取代基是具有 3 至 60 个碳原子和 1 至 5 个硝基胺的有机基，所述共聚物具有 4 至 20 个重复的烯烃-马来酰亚胺单元；(c) 具有 3 至 60 个碳原子和 1 至 10 个硝基的烃基胺。
• Fuel composition and additive concentrates, and their use in inhibiting engine coking
  申请人：ETHYL CORPORATION

  公开号：EP0247706A2

  公开（公告）日：1987-12-02

  Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel into which has been blended suitable concentrations of: (a) organic nitrate ignition accelerator, (b) hydrocarbyl amine having from 3 to 60 carbons and from 1 to 10 nitrogens, and (c) N,Nʹ-disalicylidene-1,2-diaminopropane. Additive concentrates can be formulated using such additive combinations.

  间接喷射压燃式发动机喷油器喷嘴内部和周围结焦的情况，可通过在馏分燃料中掺入适当浓度的焦油来减少： (a) 有机硝酸盐点火促进剂、 (b) 具有 3 至 60 个碳原子和 1 至 10 个硝基的烃胺，以及 (c) N,Nʹ-二水杨醛-1,2-二氨基丙烷。 可使用此类添加剂组合配制浓缩添加剂。
• Extremely stable diesel fuel compositions
  申请人：ETHYL CORPORATION

  公开号：EP1321504A2

  公开（公告）日：2003-06-25

  Diesel fuel compositions that are extremely stable against thermal degradation, sedimentation and discolouration arc devoid or essentially devoid of certain heteroatomic compounds often present in diesel fuel and which have been discovered to cause the thermal degradation in the presence of nitrate-based cetane improver additives. The specific deleterious heteroatomic compounds include pyrroles, indoles, sulfides, disulfides, mercaptans, thioacids, sulfonic acids, and indolines.

  柴油成分对热降解、沉淀和变色具有极高的稳定性，不含或基本上不含柴油中常含有的某些杂原子化合物，而这些杂原子化合物在使用硝酸盐十六烷值改进剂添加剂时会导致热降解。特定的有害杂原子化合物包括吡咯、吲哚、硫化物、二硫化物、硫醇、硫酸、磺酸和吲哚啉。
• Fuel additives for treating internal deposits of fuel injectors
  申请人：Afton Chemical Corporation

  公开号：EP2657322A1

  公开（公告）日：2013-10-30

  A method cleaning up internal components of a fuel injector for a diesel engine. The method includes operating a fuel injected diesel engine on a fuel composition that includes a major amount of diesel fuel and from about 5 to about 500 ppm by weight of a reaction product derived from (a) a hydrocarbyl substituted dicarboxylic acid, anhydride, or ester and (b) an amine compound or salt thereof of the formula wherein R is selected from the group consisting of hydrogen and a hydrocarbyl group containing from about 1 to about 15 carbon atoms, and R1 is selected from the group consisting of hydrogen and a hydrocarbyl group containing from about 1 to about 20 carbon atoms. The reaction product is characterized by a particular FTIR spectrum.

  一种清洁柴油发动机喷油器内部部件的方法。该方法包括使用一种燃料组合物来操作喷射式柴油发动机，该燃料组合物包括主要量的柴油和约 5 至约 500 ppm（按重量计）的反应产物，该反应产物衍生自 (a) 烃基取代的二羧酸、酸酐或酯和 (b) 式中的胺化合物或其盐 其中 R 选自氢和含有约 1 至约 15 个碳原子的烃基组成的组，R1 选自氢和含有约 1 至约 20 个碳原子的烃基组成的组。反应产物具有特定的傅立叶变换红外光谱。
• Alkoxylated quaternary ammonium salts and diesel fuels containing the salts
  申请人：Afton Chemical Corporation

  公开号：EP2796446A1

  公开（公告）日：2014-10-29

  A fuel soluble additive for a diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel soluble additive includes a quaternary ammonium salt derived from an amido amine containing at least one tertiary amino group and an epoxide, in the presence of a proton donor selected from a carboxylic acid and an alkyl phenol. The amido amine is made in a reaction medium that is substantially devoid of an acylating agent.

  一种用于柴油发动机的燃油可溶性添加剂、一种用于提高柴油发动机喷油器性能的方法和一种用于清洗柴油发动机喷油器的方法。该燃料溶解添加剂包括一种季铵盐，该季铵盐来源于含有至少一个叔氨基和一个环氧化物的氨基胺，存在质子供体，该质子供体选自羧酸和烷基酚。氨基胺是在基本上不含酰化剂的反应介质中制成的。