十五烷二酸单乙酯 | 13757-14-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 十五烷二酸单乙酯
• 中文别名: 五癸二酸,单乙基酯
• 英文名称: 14-Ethoxycarbonyl-teradecansaeure
• 英文别名: pentadecanedioic acid monoethyl ester；Pentadecandisaeure-monoaethylester；15-Ethoxy-15-oxopentadecanoic acid
• CAS: 13757-14-7
• 化学式: C₁₇H₃₂O₄
• 分子量: 300.439
• InChiKey: AKKQEFPXXLRKLT-UHFFFAOYSA-N

物化性质

• 熔点：
  64-65 °C
• 沸点：
  185-187 °C(Press: 1 Torr)
• 密度：
  0.977±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  21
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  十五烷二酸单乙酯 生成 15-羟基十酸
  参考文献：
  名称：

  Process for producing omega-hydroxy fatty acids

  摘要：

  公开号：

  EP0262948B1
• 作为产物：
  描述：

  芥酸 在 镍 吡啶 、 sodium periodate 、 氢气 作用下， 生成 十五烷二酸单乙酯
  参考文献：
  名称：

  Dhekne,V.V. et al., Indian Journal of Chemistry, 1966, vol. 4, p. 524 - 526

  摘要：

  DOI：

文献信息

• Location of hydroperoxide groups in monohydroperoxides formed by chlorophyll-photosensitised oxidation of unsaturated esters
  作者：D. Cobern、J. S. Hobbs、R. A. Lucas、D. J. Mackenzie

  DOI：10.1039/j39660001897

  日期：——

  Monohydroperoxides were isolated from chlorophyll-photosensitised oxidation of methyl oleate, methyl linoleate, methyl linolenate, and ethyl arachidonate. The positions of the hydroperoxide substituent were determined by two methods of analysis of the saturated hydroxy-esters formed by catalytic hydrogenation. Gas–liquid chromatographic analysis of degradation products and mass spectrometric analysis

  从油酸甲酯，亚油酸甲酯，亚油酸甲酯和花生四烯酸乙酯的叶绿素光敏氧化分离出单氢过氧化物。通过两种分析由催化氢化形成的饱和羟基酯的方法确定氢过氧化物取代基的位置。降解产物的气液色谱分析和相应的酮酸酯的质谱分析均证明氢过氧化物基团位于最初形成双键一部分的每个碳原子上。
• Jones, Journal of the American Chemical Society, 1947, vol. 69, p. 2352
  作者：Jones

  DOI：——

  日期：——
• US5191096A
  申请人：——

  公开号：US5191096A

  公开（公告）日：1993-03-02
• [EN] PROCESS FOR PRODUCING SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION<br/>[FR] PROCÉDÉ DE PRODUCTION D'UN COMPOSANT DE CATALYSEUR SOLIDE POUR LA POLYMÉRISATION D'OLÉFINES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2013042797A1

  公开（公告）日：2013-03-28

  An object of the present invention is to provide a process for producing a solid catalyst component for olefin polymerization, a process for producing a solid catalyst for olefin polymerization, and a process for producing an olefin polymer, which give a polymer having a small content of a component which is dissolved out into a low temperature organic solvent such as a low-molecular weight component and an amorphous component. Provided is a process for producing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and a compound represented by formula (I), the process comprising a step of bringing a titanium atom, a magnesium atom, a compound represented by formula (I), and a carboxylic halide into contact with each other, or a step of bringing a solid component containing a titanium atom and a magnesium atom, a compound represented by formula (I), and a carboxylic halide into contact with each other: wherein n is an integer satisfying 10 ≤ n ≤ 20; R1 is a hydrogen atom, a halogen atom, or a hydrocarbyl group having 1 to 10 carbon atoms and R1 groups are the same or different; and X1 is a hydrocarbyloxy group having 1 to 10 carbon atoms and the X1 groups are the same or different.