1,2-dimethylpropyl 2-methylphenyl ether

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,2-dimethylpropyl 2-methylphenyl ether
• 英文别名: 1-Methyl-2-(3-methylbutan-2-yloxy)benzene
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: YZRPPTPLUPFZIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-甲基-2-丁醇 、 邻甲酚 在 偶氮二甲酸二异丙酯 、 三乙胺 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 以68%的产率得到1,2-dimethylpropyl 2-methylphenyl ether
  参考文献：
  名称：

  Base catalyzed Mitsunobu reactions as a tool for the synthesis of aryl sec-alkyl ethers

  摘要：

  A facile and versatile method for the synthesis of aryl sec-alkyl ethers from phenols with alcohols in the presence of base via a Mitsunobu reaction is described. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.02.072

文献信息

• Herbicidal Composition
  申请人：Plant Andrew

  公开号：US20070259786A1

  公开（公告）日：2007-11-08

  Herbicidal composition comprising a compound of the formula (I) wherein the substituents have the meanings given in claim 1, and a safener.
• HERBICIDAL COMBINATION
  申请人：Kotzian Georg Rudiger

  公开号：US20100048398A1

  公开（公告）日：2010-02-25

  A method of controlling undesired vegetation in crops of useful plants which comprises applying a combination comprising (A) flumioxazin and (B) one or more of prosulfocarb, pinoxaden, pendimethalin, diflufenican, flupyrsulfuron, meso-sulfuron, triasulfuron, flufenacet and pyroxsulam, either simultaneously or in succession in any order, to the locus where control is desired, for example, on the undesired vegetation or the locus thereof.
• US8404618B2
  申请人：——

  公开号：US8404618B2

  公开（公告）日：2013-03-26
• Base catalyzed Mitsunobu reactions as a tool for the synthesis of aryl sec-alkyl ethers
  作者：Pitchai Manivel、Neithnadka Premsai Rai、Vaderapura Puttaramegowda Jayashankara、Pirama Nayagam Arunachalam

  DOI：10.1016/j.tetlet.2007.02.072

  日期：2007.4

  A facile and versatile method for the synthesis of aryl sec-alkyl ethers from phenols with alcohols in the presence of base via a Mitsunobu reaction is described. (c) 2007 Elsevier Ltd. All rights reserved.