6-(4-butoxy-2,3-dicyanophenoxy)hexyl acrylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 6-(4-butoxy-2,3-dicyanophenoxy)hexyl acrylate
• 英文别名: 6-(4-Butoxy-2,3-dicyanophenoxy)hexyl prop-2-enoate；6-(4-butoxy-2,3-dicyanophenoxy)hexyl prop-2-enoate
• 化学式: C₂₁H₂₆N₂O₄
• 分子量: 370.448
• InChiKey: KNEICVOIGIAXEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  27
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  92.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  6-(4-butoxy-2,3-dicyanophenoxy)hexyl acrylate 、 N,N,N,N-四(3-氨基丙基)-1,4-丁二胺 以 四氢呋喃 为溶剂， 反应 168.0h， 以96%的产率得到
  参考文献：
  名称：

  Synthesis and Property of Dendrimers Having Peripherally Mesogenic Units

  摘要：

  Poly(propyleneimine)-based liquid crystalline dendrimers (DCDs) with a relatively flexible dendritic scaffold were successfully prepared by Michael addition reaction of polypropyleneimine)s to 6-(2,3-dicyano-4-butoxyphenyloxy) hexyl acrylate(4). The structure of DCDs were characterized by IR, NMR and MALDI-TOF mass spectroscopies. Liquid crystallinity were examined by DSC, polarized optical microscope, and X-ray diffraction methods. DCDs exhibited a smectic liquid-crystalline phase, The polar terminal 2,3-dicyanophenylene group gave a liquid crystalline properties to DCDs.

  DOI：

  10.1080/10587250108025066
• 作为产物：
  描述：

  3,6-二羟基邻苯二甲腈 在 18-冠醚-6 、 potassium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 15.0h， 生成 6-(4-butoxy-2,3-dicyanophenoxy)hexyl acrylate
  参考文献：
  名称：

  Synthesis and Property of Dendrimers Having Peripherally Mesogenic Units

  摘要：

  Poly(propyleneimine)-based liquid crystalline dendrimers (DCDs) with a relatively flexible dendritic scaffold were successfully prepared by Michael addition reaction of polypropyleneimine)s to 6-(2,3-dicyano-4-butoxyphenyloxy) hexyl acrylate(4). The structure of DCDs were characterized by IR, NMR and MALDI-TOF mass spectroscopies. Liquid crystallinity were examined by DSC, polarized optical microscope, and X-ray diffraction methods. DCDs exhibited a smectic liquid-crystalline phase, The polar terminal 2,3-dicyanophenylene group gave a liquid crystalline properties to DCDs.

  DOI：

  10.1080/10587250108025066

文献信息

• Synthesis and Property of Dendrimers Having Peripherally Mesogenic Units
  作者：Osamu Haba、Ken-Ichi Okuyama、Koichiro Yonetake

  DOI：10.1080/10587250108025066

  日期：2001.8

  Poly(propyleneimine)-based liquid crystalline dendrimers (DCDs) with a relatively flexible dendritic scaffold were successfully prepared by Michael addition reaction of polypropyleneimine)s to 6-(2,3-dicyano-4-butoxyphenyloxy) hexyl acrylate(4). The structure of DCDs were characterized by IR, NMR and MALDI-TOF mass spectroscopies. Liquid crystallinity were examined by DSC, polarized optical microscope, and X-ray diffraction methods. DCDs exhibited a smectic liquid-crystalline phase, The polar terminal 2,3-dicyanophenylene group gave a liquid crystalline properties to DCDs.