4,4',5,5',6,6',7'7'-Tetraphenyldiindeno[1,2,3-cd:1',2',3'-lm]perylene

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 4,4',5,5',6,6',7'7'-Tetraphenyldiindeno[1,2,3-cd:1',2',3'-lm]perylene
• 英文别名: 7,8,9,10,21,22,23,24-Octakis-phenylnonacyclo[17.9.2.22,5.03,15.04,12.06,11.016,29.020,25.026,30]dotriaconta-1(29),2,4,6,8,10,12,14,16,18,20,22,24,26(30),27,31-hexadecaene
• 化学式: C₈₀H₄₈
• 分子量: 1009.26
• InChiKey: QRLXFZHTRIUWPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.5
• 重原子数：
  80
• 可旋转键数：
  8
• 环数：
  17.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  7,8,9,10-Tetraphenyl-fluoranthen 在 三氯化铁 作用下， 以 硝基甲烷 、 二氯甲烷 为溶剂， 反应 0.08h， 以90%的产率得到4,4',5,5',6,6',7'7'-Tetraphenyldiindeno[1,2,3-cd:1',2',3'-lm]perylene
  参考文献：
  名称：

  Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route

  摘要：

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.

  DOI：

  10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g

文献信息

• Organic photoelectric device and image sensor including the same
  申请人：Samsung Electronics Co., Ltd.

  公开号：US09368727B2

  公开（公告）日：2016-06-14

  An organic photoelectric device may include an anode and a cathode facing each other and the active layer between the anode and cathode, wherein the active layer includes a compound represented by Chemical Formula 1 and a compound represented by Chemical Formula 2. Chemical Formula 1 and Chemical Formula 2 are the same as in the detailed description.

  一个有机光电器件可能包括彼此面对的阳极和阴极，以及阳极和阴极之间的活性层，其中活性层包括化学式1代表的化合物和化学式2代表的化合物。化学式1和化学式2与详细说明中相同。
• Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route
  作者：Mike Wehmeier、Manfred Wagner、Klaus Müllen

  DOI：10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g

  日期：2001.5.18

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.