5,11-di-m-tolyl-5,11-dihydroindolo[3,2-b]carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5,11-di-m-tolyl-5,11-dihydroindolo[3,2-b]carbazole
• 英文别名: 5,11-bis(3-methylphenyl)indolo[3,2-b]carbazole
• 化学式: C₃₂H₂₄N₂
• 分子量: 436.556
• InChiKey: SEDNZUIHNUMYDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  34
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  cyclohexane-1,4-dione bisphenylhydrazone 在 硫酸 作用下， 以 甲醇 、 溶剂黄146 为溶剂， 生成 5,11-di-m-tolyl-5,11-dihydroindolo[3,2-b]carbazole 、 吲哚并[3,2-b]咔唑
  参考文献：
  名称：

  Indolocarbazole Photoconductors

  摘要：

  公开号：

  EP0908787B1

文献信息

• MATERIAL FOR USE IN PHOSPHORESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：Kai Takahiro

  公开号：US20110315975A1

  公开（公告）日：2011-12-29

  Provided is an organic electroluminescent device (organic EL device), in which the luminous efficiency of the device is improved, driving stability is sufficiently ensured, and the construction of the device is simple. This organic EL device is an organic electroluminescent device, including a light-emitting layer between an anode and a cathode laminated on a substrate, in which the light-emitting layer contains a phosphorescent light-emitting dopant and an indolocarbazole compound as a host material. Examples of the indolocarbazole compound include a compound represented by the following formula (1). It should be noted that in the formulae: a ring A and a ring B are represented by the formulae (1a) and (1b), respectively; Ar's each represent an aromatic hydrocarbon group or an aromatic heterocyclic group; R's each represent a hydrogen atom, an alkyl group, or a cycloalkyl group; X represents a methine group or a nitrogen atom; A represents an aromatic hydrocarbon group, an alkyl group, a cycloalkyl group, or a group represented by the formula (1c); and n represents 0 or 1.

  提供的是一种有机电致发光器件（有机EL器件），其中改善了器件的发光效率，充分确保了驱动稳定性，并且器件的构造简单。这种有机EL器件是一种有机电致发光器件，包括位于基板上的阳极和阴极之间的发光层，其中发光层包含一种磷光发光掺杂剂和一种吲哚并咔唑化合物作为主体材料。吲哚并咔唑化合物的例子包括以下式子（1）表示的化合物。应注意，在式子中：环A和环B分别由式子（1a）和（1b）表示；Ar分别表示芳香族碳氢基团或芳香族杂环基团；R分别表示氢原子、烷基或环烷基；X表示亚甲基或氮原子；A表示芳香族碳氢基团、烷基、环烷基或由式子（1c）表示的基团；n表示0或1。
• Indolocarbazole photoconductors
  申请人：Xerox Corporation

  公开号：US05843607A1

  公开（公告）日：1998-12-01

  A photoconductive imaging member comprised of a charge transport layer comprised of an indolocarbazole represented by the Formulas (Ia), (IIa), (IIIa), (IVa), (Va), or (VIa); or optionally mixtures thereof: ##STR1## wherein R and R' are independently selected from the group consisting of a hydrogen atom, a halogen atom, alkyl, alkoxyl, and aryl; m and n are numbers of from 0 to 4; R.sup.1 and R.sup.2 are independently selected from the group consisting of alkyl, aryl, vinyl, and diarylaminoaryl; R.sup.3 and R.sup.4 are an atom of hydrogen, alkyl, alkoxy, aryl, or halogen, and p is a number of from 1 to 3.

  一种光电成像成员，包括一个电荷传输层，该电荷传输层包括以下式子（Ia）、（IIa）、（IIIa）、（IVa）、（Va）或（VIa）所代表的吲哚并咔唑，或者是它们的混合物：##STR1## 其中，R和R'独立地选自氢原子、卤素原子、烷基、烷氧基和芳基的群体；m和n是从0到4的数字；R.sup.1和R.sup.2独立地选自烷基、芳基、乙烯基和二芳基氨基芳基的群体；R.sup.3和R.sup.4是氢原子、烷基、烷氧基、芳基或卤素的原子，p是从1到3的数字。
• Indolocarbazole electroluminescent devices
  申请人：Xerox Corporation

  公开号：US05942340A1

  公开（公告）日：1999-08-24

  An organic electroluminescent device member comprised of a charge transport component of an indolocarbazole represented by Formulas (I), (II), (III), (IV), (V), or (VI); or optionally mixtures thereof ##STR1## wherein R and R' are independently selected from the group consisting of a hydrogen atom, halogen atom, alkyl, alkoxyl, and aryl; m and n are numbers of 0 to 4; R.sup.1 and R.sup.2 are independently selected from the group consisting of alkyl, aryl, and vinyl; R.sup.3 and R.sup.4 are independently selected from the group consisting of a hydrogen atom, halogen atom, alkyl, alkoxy, and aryl, and p is a number from 1 to 3.

  一种有机电致发光器件成员，包括由式(I)、(II)、(III)、(IV)、(V)或(VI)所表示的吲哚并咔唑的电荷传输组分；或可选的它们的混合物 ##STR1## 其中R和R'独立地选自氢原子、卤素原子、烷基、烷氧基和芳基的群；m和n是0到4的数字；R.sup.1和R.sup.2独立地选自烷基、芳基和乙烯基的群；R.sup.3和R.sup.4独立地选自氢原子、卤素原子、烷基、烷氧基和芳基的群，p是1到3的数字。
• MATERIAL FOR PHOSPHORESCENT LIGHT-EMITTING ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2416397A1

  公开（公告）日：2012-02-08

  Provided is an organic electroluminescent device (organic EL device), which has improved luminous efficiency, has sufficient driving stability, and has a simple construction. The organic EL device of the present invention is an organic electroluminescent device, including a light-emitting layer and a hole-transporting layer between an anode and a cathode laminated on a substrate, in which the light-emitting layer contains a phosphorescent light-emitting dopant and an indolocarbazole compound that serves as a host material, or alternatively, the hole-transporting layer contains an indolocarbazole compound. The indolocarbazole compound is represented by the following formula (1). In the formula: A1's each represent an aromatic hydrocarbon group or an aromatic heterocyclic group, provided that at least one of A1's has a fused ring structure; and R1's each represent a hydrogen atom, an alkyl group, an alkoxy group, or an acyl group.

  本发明提供了一种有机电致发光器件（有机 EL 器件），它具有更高的发光效率、足够的驱动稳定性和简单的结构。本发明的有机电致发光器件是一种有机电致发光器件，包括层叠在基底上的阳极和阴极之间的发光层和空穴传输层，其中发光层包含磷光发光掺杂剂和作为宿主材料的吲哚咔唑化合物，或者，空穴传输层包含吲哚咔唑化合物。吲哚咔唑化合物由下式（1）表示。式中A1各自代表芳香烃基团或芳香杂环基团，条件是A1中至少有一个具有融合环结构；R1各自代表氢原子、烷基、烷氧基或酰基。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2521196A1

  公开（公告）日：2012-11-07

  Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. The organic EL device of this invention comprises a light-emitting layer between an anode and a cathode piled one upon another on a substrate and the light-emitting layer contains a phosphorescent dopant and an unsymmetrical indolocarbazole compound as a host material. The unsymmetrical indolocarbazole compound has a structure in which two or more groups having an indolocarbazole structure are linked together by a linking group and at least one of the groups has an isomeric indolocarbazole skeleton different from those of the other groups. Examples of the unsymmetrical indolocarbazole compound include compounds represented by the following formula (2) wherein A is a substituent, each of R1 to R3 is a hydrogen atom or a substituent, and L is a linking group composed of an aromatic group.

  本发明公开了一种有机电致发光器件（organic EL device），其发光效率更高，充分保证了驱动稳定性，而且结构简单。本发明的有机电致发光器件包括一个发光层，发光层位于基底上一个叠着一个的阳极和阴极之间，发光层含有磷光掺杂剂和作为主材料的非对称吲哚咔唑化合物。非对称吲哚咔唑化合物具有这样的结构：两个或多个具有吲哚咔唑结构的基团通过连接基团连接在一起，其中至少一个基团具有不同于其他基团的异构吲哚咔唑骨架。非对称吲哚咔唑化合物的例子包括下式（2）所代表的化合物，其中 A 是取代基，R1 至 R3 中的每一个都是氢原子或取代基，L 是由芳香基团组成的连接基团。