1,1-dimethylethyl phenylchlorophosphonite

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-dimethylethyl phenylchlorophosphonite
• 英文别名: Chloro-[(2-methylpropan-2-yl)oxy]-phenoxyphosphane；chloro-[(2-methylpropan-2-yl)oxy]-phenoxyphosphane
• 化学式: C₁₀H₁₄ClO₂P
• 分子量: 232.647
• InChiKey: VLOHMRHMCJTZFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯基二氯化磷 、 叔丁醇 在 正丁基锂 作用下， 以 正己烷 为溶剂， 以58%的产率得到1,1-dimethylethyl phenylchlorophosphonite
  参考文献：
  名称：

  Synthesis and characterisation of severely hindered P-OR compounds

  摘要：

  P-Cl substrates were converted into their P-OR analogues from hindered alcohols using an amine base. Where the system was severely hindered, more forcing conditions were required that necessitated the presence of a metal alkoxide nucleophile before successful reactions were observed. In some instances, the products were thermally unstable and reverted to alkenes by elimination reactions, while others were sensitive to moisture. Here, hydrolysis products prevailed if moisture was not rigorously excluded. Details are presented to obtain the P(III) and P(V) esters, diesters and half esters. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.10.008

文献信息

• Dopant Group-Substituted Semiconductor Precursor Compounds, Compositions Containing the Same, and Methods of Making Such Compounds and Compositions
  申请人：GUO Wenzhuo

  公开号：US20110178321A1

  公开（公告）日：2011-07-21

  Dopant-group substituted (cyclo)silane compounds, liquid-phase compositions containing such compounds, and methods for making the same. Such compounds (and/or ink compositions containing the same) are useful for printing or spin coating a doped silane film onto a substrate that can easily be converted into a doped amorphous or polycrystalline silicon film suitable for electronic devices. Thus, the present invention advantageously provides commercial qualities and quantities of doped semiconductor films from a doped “liquid silicon” composition.
• US7674926B1
  申请人：——

  公开号：US7674926B1

  公开（公告）日：2010-03-09
• US8624049B2
  申请人：——

  公开号：US8624049B2

  公开（公告）日：2014-01-07
• Synthesis and characterisation of severely hindered P-OR compounds
  作者：D. Bradley G. Williams、Takelani E. Netshiozwi

  DOI：10.1016/j.tet.2009.10.008

  日期：2009.11

  P-Cl substrates were converted into their P-OR analogues from hindered alcohols using an amine base. Where the system was severely hindered, more forcing conditions were required that necessitated the presence of a metal alkoxide nucleophile before successful reactions were observed. In some instances, the products were thermally unstable and reverted to alkenes by elimination reactions, while others were sensitive to moisture. Here, hydrolysis products prevailed if moisture was not rigorously excluded. Details are presented to obtain the P(III) and P(V) esters, diesters and half esters. (C) 2009 Elsevier Ltd. All rights reserved.