2-Phenyl-4-(phenyl-hydrazono)-4H-oxazol-5-one

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Phenyl-4-(phenyl-hydrazono)-4H-oxazol-5-one
• 英文别名: (4E)-2-phenyl-4-(phenylhydrazinylidene)-1,3-oxazol-5-one
• 化学式: C₁₅H₁₁N₃O₂
• 分子量: 265.271
• InChiKey: JGUNDRHHCZCUPV-QGOAFFKASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  马尿酸 、 氯化重氮苯 在 sodium acetate 作用下， 以 乙酸酐 为溶剂， 反应 3.0h， 生成 2-Phenyl-4-(phenyl-hydrazono)-4H-oxazol-5-one
  参考文献：
  名称：

  Shawali, Ahmad S.; Abdelhamid, Abdou O.; Ahmad, Nada F., Heterocycles, 1982, vol. 19, # 12, p. 2331 - 2338

  摘要：

  DOI：

文献信息

• 1,5-Diphenyl-1H-1,2,4-triazole-3-carboxamide derivatives and herbicidal composition containing the same
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0282303A1

  公开（公告）日：1988-09-14

  Herbicidal derivatives of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide are represented by the formula (I): wherein R is a straight-chain alkyl group having from 1 to 10 carbon atoms which is unsubstituted or substituted by from 1 to 19 fluorine atoms, a branched alkyl group having from 3 to 10 carbon atoms which is unsubstituted or substituted by from 1 to 19 fluorine atoms, a cycllic alkyl group having from 3 to 10 carbon atoms, an alkyl group having from 1 to 3 carbon atoms which is substituted with an alicyclic structure having from 3 to 7 carbon atoms, a phenyl group or an aralkyl group having from 7 to 9 carbon atoms; X1 is halogen or an alkyl group having from 1 to 3 carbon atoms; X2 is hydrogen, halogen or an alkyl group having from 1 to 3 carbon atoms; Y1 is hydrogen or fluorine; and Y2 is hydrogen or fluorine.

  1,5-二苯基-1H-1,2,4-三唑-3-甲酰胺的除草衍生物由式(I)表示： 其中 R 是具有 1 至 10 个碳原子且未被取代或被 1 至 19 个氟原子取代的直链烷基、具有 3 至 10 个碳原子且未被取代或被 1 至 19 个氟原子取代的支链烷基、具有 3 至 10 个碳原子的环状烷基、具有 1 至 3 个碳原子且被具有 3 至 7 个碳原子的脂环结构取代的烷基、苯基或具有 7 至 9 个碳原子的芳基；X1 是卤素或具有 1 至 3 个碳原子的烷基；X2 是氢、卤素或具有 1 至 3 个碳原子的烷基；Y1 是氢或氟；Y2 是氢或氟。
• Benzyl ether derivatives
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0454182A2

  公开（公告）日：1991-10-30

  Novel benzyl ether derivatives are disdosed of the following formula A: wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms ; X1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X2 is hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; and Z is NH2 or N02. The compounds are useful as intermediates in the preparation of herbicidal 1,5-diphenyl-1H-1,2,4-triazolecarboxamide derivatives.

  新颖的苄基醚衍生物由下式 A 代出： 其中 R 是具有 1 至 10 个碳原子且未被取代或被 1 至 19 个氟原子取代的直链烷基、具有 3 至 10 个碳原子且未被取代或被 1 至 19 个氟原子取代的支链烷基、具有 3 至 10 个碳原子的环状基团、具有 1 至 3 个碳原子且被具有 3 至 7 个碳原子的脂环结构取代的烷基、苯基或具有 7 至 9 个碳原子的芳烷基；X1 是卤素或具有 1 至 3 个碳原子的烷基；X2 是氢、卤素或具有 1 至 3 个碳原子的烷基；Z 是 NH2 或 N02。 这些化合物可用作制备除草剂 1,5-二苯基-1H-1,2,4-三唑甲酰胺衍生物的中间体。
• Herbicidal 1,5-diphenyl-1H-1, 2,4-triazole-3-carboxamide derivatives
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0282669B1

  公开（公告）日：1992-07-01
• A derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide, herbicidal compositions containing the derivative and process for producing the derivative
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0297734B1

  公开（公告）日：1993-03-03
• Process for the manufacture of 2-phenyl-4,5-oxazoledione 4-phenylhydrazones
  申请人：KUREHA CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0493124B1

  公开（公告）日：1996-09-18