2-(2-(2-isocyanatoethoxy)ethoxy)ethyl methacrylate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(2-(2-isocyanatoethoxy)ethoxy)ethyl methacrylate
• 英文别名: 2-[2-(2-Isocyanatoethoxy)ethoxy]ethyl 2-methylprop-2-enoate；2-[2-(2-isocyanatoethoxy)ethoxy]ethyl 2-methylprop-2-enoate
• 化学式: C₁₁H₁₇NO₅
• 分子量: 243.26
• InChiKey: OLUCKHHXTBOQGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  74.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(2-(2-isocyanatoethoxy)ethoxy)ethyl methacrylate 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 、 二月桂酸二丁基锡 、 4-甲氧基苯酚 作用下， 反应 17.0h， 生成 4,4-diethoxy-9-oxo-3,8,13,16-tetraoxa-10-aza-4-silaoctadecan-18-yl methacrylate
  参考文献：
  名称：

  SILANE COUPLING COMPOUNDS AND MEDICAL AND/OR DENTAL CURABLE COMPOSITIONS COMPRISING THE SAME

  摘要：

  本发明涉及一种新型硅烷偶联剂以及包括该偶联剂的医用和/或牙科可固化组合物。本发明的目的是提供一种新型硅烷偶联剂，使其对自由基聚合单体具有高亲和力，从而在用于医用和/或牙科可固化组合物时赋予高机械强度、柔韧性和耐久性，并且包括经新型硅烷偶联剂表面处理的无机填料和新型医用和/或牙科可固化组合物。该硅烷偶联剂包括在特定位置具有尿素键和聚乙二醇（醚键）等重复单元。

  公开号：

  US20190300552A1

文献信息

• SILICON-CONTAINING COMPOUND, URETHANE RESIN, STRETCHABLE FILM, AND METHOD FOR FORMING THE SAME
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190112413A1

  公开（公告）日：2019-04-18

  The present invention provides a silicon-containing compound shown by the following formula (1): wherein R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 each independently represent a linear, branched, or cyclic alkyl group having 1 to 6 carbon atoms, a phenyl group, a 3,3,3-trifluoropropyl group, or a group shown by —(OSiR 7 R 8 ) n —OSiR 9 R 10 R 11 ; R 7 , R 8 , R 9 , R 10 , and R 11 have the same meanings as R 1 to R 6 ; “n” is an integer in the range of 0 to 100; and “A” represents a linear or branched alkylene group having 1 to 6 carbon atoms. This provides a stretchable film that has excellent stretchability and strength, with the film surface having excellent repellency, and a method for forming the same; as well as a urethane resin used for the stretchable film; and a silicon-containing compound to be a material of the urethane resin.

  本发明提供了一种含硅化合物，其化学式如下（1）所示：其中R1、R2、R3、R4、R5和R6分别独立表示具有1至6个碳原子的直链、支链或环烷基基团，苯基，3,3,3-三氟丙基基团，或由—(OSiR7R8)n—OSiR9R10R11所示的基团；R7、R8、R9、R10和R11具有与R1至R6相同的含义；“n”是0至100范围内的整数；“A”表示具有1至6个碳原子的直链或支链烷基基团。这提供了一种具有优异的延展性和强度的可拉伸薄膜，薄膜表面具有优异的防水性，以及形成该薄膜的方法；以及用于可拉伸薄膜的聚氨酯树脂；以及用于聚氨酯树脂的硅含量化合物。
• CURABLE COMPOSITION CONTAINING A REACTIVE (METH)ACRYLATE POLYMER AND A CURED PRODUCT THEREOF
  申请人：Showa Denko K.K.

  公开号：EP2295481A1

  公开（公告）日：2011-03-16

  It is an obj ect of the present invention to provide a curable composition capable of forming a heat-resistant cured film which is excellent in surface hardness, is good also in flexibility and bending properties and has strength and flexibility that are compatible with each other, and a cured product (film) of the composition. The curable composition is characterized by comprising a reactive (meth) acrylate polymer (A) having a monomer unit represented by the following formula (1), a polymerization initiator (B) and a reactive monomer(C). In the formula (1), R1 is a hydrogen atom, a methyl group or an ethyl group, R2 is a hydrogen atom or a methyl group, X1 is a straight-chain or branched hydrocarbon group of 2 to 6 carbon atoms or an alcohol residue of polyethylene glycol, polypropylene glycol or caprolactone-modified both-terminal diol, n is an integer of 2 to 4, and m is an integer of 1 to 5.

  本发明的目的是提供一种能够形成耐热固化膜的固化组合物，该固化组合物的表面硬度极佳，柔韧性和弯曲性能也很好，并且强度和柔韧性相互兼容。该固化组合物的特点是由具有下式（1）表示的单体单元的活性（甲基）丙烯酸酯聚合物（A）、聚合引发剂（B）和活性单体（C）组成。 在式 (1) 中，R1 是氢原子、甲基或乙基，R2 是氢原子或甲基，X1 是 2 至 6 个碳原子的直链或支链烃基或聚乙二醇、聚丙二醇或己内酰胺改性双端二元醇的醇残基，n 是 2 至 4 的整数，m 是 1 至 5 的整数。
• SILICON-CONTAINING COMPOUND, URETHANE RESIN, STRETCHABLE FILM AND METHOD FOR FORMING THE SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3530682A1

  公开（公告）日：2019-08-28

  This is to provide a stretchable film having excellent stretchability and strength and excellent water repellency on the surface of the film, a method for forming the same, a urethane resin used for the stretchable film and a silicon-containing compound as a material of the urethane resin. A silicon-containing compound represented by the following general formula (1), wherein, R1, R2, R3, R4, R5, and R6 each represents a linear, branched or cyclic alkyl group having 1 to 6 carbon atoms, a phenyl group, a 3,3,3-trifluoropropyl group or a group represented by -(OSiR7R8)n-OSiR9R10R11; R7, R8, R9, R10 and R11 are the same as those of R1 to R6; "n" is an integer in the range of 0 to 100; A represents a linear or branched alkylene group having 3 to 6 carbon atoms; and "m" is an integer in the range of 1 to 3.

  本发明旨在提供一种拉伸性和强度优异且薄膜表面防水性优异的拉伸薄膜、形成该薄膜的方法、用于该拉伸薄膜的聚氨酯树脂以及作为聚氨酯树脂材料的含硅化合物。由以下通式（1）表示的含硅化合物、 其中，R1、R2、R3、R4、R5 和 R6 分别代表具有 1 至 6 个碳原子的直链、支链或环状烷基、苯基、3,3,3-三氟丙基或由-(OSiR7R8)n-OSiR9R10R11 所代表的基团；R7、R8、R9、R10 和 R11 与 R1 至 R6 相同；"n "是 0 至 100 范围内的整数；A 代表具有 3 至 6 个碳原子的直链或支链亚烷基；以及 "m "是 1 至 3 范围内的整数。
• Stretchable film and method for forming the stretchable film
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10501585B2

  公开（公告）日：2019-12-10

  The present invention provides a stretchable film that is excellent in stretch and strength and water repellency on the film surface, and a method for forming the stretchable film. The present invention was accomplished by a stretchable film including a resin having a branched siloxane bond having 3 to 11 silicon atoms on a side chain and having a urethane bond on a main chain.

  本发明提供了一种拉伸性和强度优异且薄膜表面防水的可拉伸薄膜，以及形成该可拉伸薄膜的方法。本发明是通过一种可拉伸薄膜实现的，该薄膜包括一种树脂，该树脂具有支链硅氧烷键，侧链上有 3 至 11 个硅原子，主链上有聚氨酯键。
• Silicon-containing compound, urethane resin, stretchable film, and method for forming the same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10696779B2

  公开（公告）日：2020-06-30

  The present invention provides a silicon-containing compound shown by the following formula (1): wherein R1, R2, R3, R4, R5, and R6 each independently represent a linear, branched, or cyclic alkyl group having 1 to 6 carbon atoms, a phenyl group, a 3,3,3-trifluoropropyl group, or a group shown by —(OSiR7R8)n—OSiR9R10R11; R7, R8, R9, R10, and R11 have the same meanings as R1 to R6; “n” is an integer in the range of 0 to 100; and “A” represents a linear or branched alkylene group having 1 to 6 carbon atoms. This provides a stretchable film that has excellent stretchability and strength, with the film surface having excellent repellency, and a method for forming the same; as well as a urethane resin used for the stretchable film; and a silicon-containing compound to be a material of the urethane resin.

  本发明提供了下式（1）所示的含硅化合物： 其中R1、R2、R3、R4、R5和R6各自独立地代表具有1至6个碳原子的直链、支链或环状烷基、苯基、3,3,3-三氟丙基或由-(OSiR7R8)n-OSiR9R10R11所示的基团；R7、R8、R9、R10 和 R11 的含义与 R1 至 R6 相同；"n "是 0 至 100 范围内的整数；"A "代表具有 1 至 6 个碳原子的直链或支链亚烷基。本发明提供了一种具有优异拉伸性和强度的可拉伸薄膜，其薄膜表面具有优异的排斥性，并提供了形成该薄膜的方法；还提供了一种用于该可拉伸薄膜的聚氨酯树脂；以及一种作为聚氨酯树脂材料的含硅化合物。