10-undecenyl formate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 10-undecenyl formate
• 英文别名: undec-10-enyl formate
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: YBXNNLWZLUTKHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  14
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  10-十一烯-1-醇 、 N,N-二甲基甲酰胺 在 四溴环己二烯-1-酮 、 三苯基膦 、 zinc dibromide 作用下， 反应 3.0h， 以100%的产率得到10-undecenyl formate
  参考文献：
  名称：

  PREPARATION OF FORMIC ACID ESTERS WITH A PHOSPHONIUM SALT AND ZINC BROMIDE INN,N-DIMETHYLFORMAMIDE

  摘要：

  When primary and secondary alcohols were treated with the phosphonium salt 1 and ZnBr2 in N,N-dimethylformamide, the corresponding formic acid esters were obtained in good yields.

  DOI：

  10.1081/scc-120014038

文献信息

• [EN] PHOTOACTIVE MATERIALS<br/>[FR] MATERIAUX PHOTOACTIFS
  申请人：ROLIC AG

  公开号：WO2004013086A1

  公开（公告）日：2004-02-12

  Diamine compounds, which in particular are useful as precursors for the production of liquid crystal alignment layers, represented by general formula (I), wherein A1 represents an organic group of 1 to 40 carbon atoms; A2 represents a hydrogen atom or an organic group of 1 to 40 carbon atoms.

  二胺化合物，特别是作为液晶取向层生产的前体物而有用，由一般式(I)代表，其中A1代表1至40个碳原子的有机基团；A2代表氢原子或1至40个碳原子的有机基团。
• Compound
  申请人：Rolic AG

  公开号：EP1070731A1

  公开（公告）日：2001-01-24

  The present invention provides a compound comprising a repeating unit of formula (I)    in which: Arepresents a nitrogen atom, a carbon atom, a group -CR1- or an aromatic or alicyclic group, wherein R1 represents a hydrogen atom or lower alkyl, Mrepresents a repeating monomer unit; n1 to n3each independently represent 0 or an integer having a value of from 1 to 3, with the proviso that 1 < n1 + n2 + n3 < 4; P1, P2, P3each independently represent a photoactive group; and B1 to B4each independently represent a residue of general formula II as well as photoactive polymers prepared from such compounds and the use of such compounds in the preparation of liquid crystal orientation layers and structured and unstructured electro-optical elements.

  本发明提供了一种化合物，其包含具有如下式（I）的重复单元：其中：A表示氮原子、碳原子、基团-CR1-或芳香族或脂环基团，其中R1表示氢原子或较低的烷基，M表示重复单体单位；n1至n3分别独立地表示0或取值为1至3的整数，但需满足1 < n1 + n2 + n3 < 4；P1、P2、P3分别独立地表示光活性基团；B1至B4分别独立地表示通式II的残基，以及从这些化合物制备的光活性聚合物以及这些化合物在液晶取向层和结构化和非结构化的电光元件制备中的使用。
• Photoactive polyimides, polyamide acids or esters with side chain photocrosslinkable groups
  申请人：——

  公开号：US20030039768A1

  公开（公告）日：2003-02-27

  A photoactive polymer from the class of polyimides, polyamide acids and esters thereof comprises as a side-chain a photocrosslinkable group of the general formula (I) 1 wherein the broken line indicates the point of linkage to the polyimide main chain and wherein: B is a straight-chain or branched alkyl residue which is optionally substituted, wherein one or more non-adjacent CH 2 groups may independently be replaced by a group Q; D represents an oxygen atom or —NR 1 — wherein R 1 represents a hydrogen atom or lower alkyl; and S 3 represents a spacer unit. The polymers may be used as orientation layers for liquid crystals and in the construction of unstructured and structured optical elements and multi-layer systems.

  一种来自聚酰亚胺、聚酰胺酸及其酯类的光敏聚合物，其侧链包含一个光交联可交联基团，其通用式为（I）1，其中断裂的线表示与聚酰亚胺主链的连接点，并且：B是直链或支链烷基残基，可选地被取代，其中一个或多个非相邻的CH2基团可以独立地被取代为基团Q；D表示氧原子或—NR1—，其中R1表示氢原子或低烷基；S3表示间隔单元。这些聚合物可用作液晶的取向层，并用于构建非结构化和结构化光学元件和多层系统。
• Photoactive materials
  申请人：Marck Guy

  公开号：US20050288480A1

  公开（公告）日：2005-12-29

  Diamine compounds, which in particular are useful as precursors for the production of liquid crystal alignment layers, represented by general formula (I), wherein A 1 represents an organic group of 1 to 40 carbon atoms; A 2 represents a hydrogen atom or an organic group of 1 to 40 carbon atoms.

  Diamine化合物，尤其是作为液晶取向层生产的前体物而有用的，由一般式(I)表示，其中A1表示由1到40个碳原子组成的有机基团；A2表示氢原子或由1到40个碳原子组成的有机基团。
• Photoactive polymer
  申请人：——

  公开号：US20040185215A1

  公开（公告）日：2004-09-23

  A photoactive side-chain polymer from the class of polyimides, polyamide acids and esters thereof, comprising as a side-chain a dentritic block incorporating photoactive groups at its surface. The dentritic block preferably represents a unit of formulae Ia, Ib or a combination of them, for example formulae Ic wherein the broken line symbolizes the linkage to polyimide main chain. The polymer may be used as orientation layer for liquid crystals and in the construction of unstructured and structured optical elements and multi-layer systems.

  一种来自聚酰亚胺、聚酰胺酸和酯类的光致活性侧链聚合物，其包含一个树状分子块作为侧链，在其表面结合了光致活性基团。所述树状分子块优选代表Ia、Ib或其组合单元，例如Ic式，其中断裂线符号表示与聚酰亚胺主链的连接。该聚合物可用作液晶取向层，并用于构建非结构化和结构化光学元件和多层系统。