N,N'-dioctyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxylic diimide

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-dioctyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxylic diimide
• 英文别名: 1,6,7,12-tetra(4-fert-butylphenoxy)perytene-3,4,9,10-tetracarboxylic di(octylimide)；N,N'-dioctyl-1,6,7,12-tetrakis(4-t-butylphenoxy)perylene-3,4,9,10-tetracarboxylic acid diimide；TTBP-PBI；N,N-Dioctyl-1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride；11,14,22,26-tetrakis(4-tert-butylphenoxy)-7,18-dioctyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone
• 化学式: C₈₀H₉₀N₂O₈
• 分子量: 1207.6
• InChiKey: MMFQTZXXWBXMLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23.3
• 重原子数：
  90
• 可旋转键数：
  26
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N,N'-dioctyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxylic diimide 在 potassium hydroxide 作用下， 以 异丙醇 为溶剂， 以95%的产率得到1,6,7,12-四叔丁基苯氧基苝-3,4,9,10-四甲酸二酐
  参考文献：
  名称：

  Multichromophoric dye-sensitized solar cells based on supramolecular zinc-porphyrin⋯perylene-imide dyads

  摘要：

  与基于单个染料的多色染料敏化太阳能电池相比，基于二氧化钛薄膜上自组装的锌-卟啉-苝酰亚胺染料的多色染料敏化太阳能电池（DSCs）显示出更高效的光-电能量转换。多色性染料的更高效率可归因于共敏化以及矢量电子传递，从而使装置中的电子-空穴分离更充分。

  DOI：

  10.1039/c2cc33120a
• 作为产物：
  描述：

  4-叔丁基苯酚 、 N,N'-双(正辛基)-1,6,7,12-四氯-3,4,9,10-�p四甲酰二亚胺 在 N-甲基吡咯烷酮 作用下， 反应 10.0h， 以89%的产率得到N,N'-dioctyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxylic diimide
  参考文献：
  名称：

  A facile design of thio-perylenediimides with controllable fluorescent, photodynamic and photothermal effects towards cancer theranostics

  摘要：

  一种具有可控荧光、光动力和光热效应的硫化苝酞酰亚胺系列化合物已通过一锅法合成，用于多种癌症光诊疗。

  DOI：

  10.1039/d1cc05483j

文献信息

• [EN] LIGHT HARVESTING ARRAY<br/>[FR] RÉSEAU COLLECTEUR DE LUMIÈRE
  申请人：FLUROSOL IND PTY LTD

  公开号：WO2015024064A1

  公开（公告）日：2015-02-26

  The invention relates to a light harvesting array or dye comprising an acceptor linked to a donor, wherein at least one of the acceptor or the donor is an oligomeric unit comprising a first optionally substituted rylene linked via a linker group to a second optionally substituted rylene, the first optionally substituted rylene is linked to the acceptor or the donor and the second optionally substituted rylene is capable of energy transfer to at least one of the first optionally substituted rylene, the acceptor or the donor. The invention also relates to compounds which may be used as light harvesting arrays, methods for their manufacture, and devices and materials comprising the light harvesting array or dye, for example, chromophoric materials, light guides, photobioreactors, photoluminescent algae systems, photodetectors, photovoltaic devices and luminescent/fluorescent solar concentrators.

  该发明涉及一种光收集阵列或染料，包括一个与给体相连的受体，其中受体或给体中至少有一个是包含第一可选择取代的芳香烃单元通过连接基团连接到第二可选择取代的芳香烃的寡聚单元，第一可选择取代的芳香烃与受体或给体相连，第二可选择取代的芳香烃能够将能量传递至第一可选择取代的芳香烃、受体或给体中的至少一个。该发明还涉及可用作光收集阵列的化合物，其制造方法，以及包括光收集阵列或染料的设备和材料，例如，色素材料、光导管、光生物反应器、光致发光藻类系统、光探测器、光伏器件和发光/荧光太阳能聚光器。
• Synthesis and aggregation properties of a series of dumbbell polyhedral oligosilsesquioxane-perylene diimide triads
  作者：Ying Zhang、Liangliang Zhang、Heyuan Liu、Di Sun、Xiyou Li

  DOI：10.1039/c4ce02392g

  日期：——

  A series of perylenetetracarboxylic diimide (PDI) derivatives connected with two bulky polyhedral oligosilsesquioxanes (POSSs) were designed and synthesized for the purpose of revealing the effect of bulky and well-defined side groups on the self-aggregation behaviour of PDIs. The properties of these compounds in solution were investigated by UV-vis absorption spectroscopy, fluorescence spectroscopy

  设计并合成了一系列与两个庞大的多面体低聚倍半硅氧烷（POSS）连接的per四羧酸二亚胺（PDI）衍生物，目的是揭示庞大且定义明确的侧基对PDI的自聚集行为的影响。通过紫外可见吸收光谱，荧光光谱和荧光量子产率测量研究了这些化合物在溶液中的性质。结果表明，POSS基团对溶液中PDI的光谱性质没有显示出大的影响。但是，这些化合物的固态光谱特性会受到庞大的POSS基团的显着影响。庞大的POSS基团的存在改变了固态分子的堆积结构，从而影响了固态发射性能。我们的结果表明，将大的POSS基团引入分子中将不可避免地导致固态荧光量子产率的提高。固态分子的堆积结构决定了固态荧光量子产率。如果庞大的POSS基团的存在导致固态“ J”聚集体的形成，那么固态荧光量子产率将大大提高。否则，如果庞大的POSS基团引起分子的“ H”型聚集，则固态荧光量子产率将很小。固态分子的堆积结构决定了固态荧光量子产率。如果庞大的POSS基团的存在导致固态“
• Organic photoelectric device and image sensor including the same
  申请人：Samsung Electronics Co., Ltd.

  公开号：US09368727B2

  公开（公告）日：2016-06-14

  An organic photoelectric device may include an anode and a cathode facing each other and the active layer between the anode and cathode, wherein the active layer includes a compound represented by Chemical Formula 1 and a compound represented by Chemical Formula 2. Chemical Formula 1 and Chemical Formula 2 are the same as in the detailed description.

  一个有机光电器件可能包括彼此面对的阳极和阴极，以及阳极和阴极之间的活性层，其中活性层包括化学式1代表的化合物和化学式2代表的化合物。化学式1和化学式2与详细说明中相同。
• Synthesis and Characterization of 3,5-Bis(2-hydroxyphenyl)-1,2,4-triazole Functionalized Tetraaryloxy Perylene Bisimide and Metal-Directed Self-Assembly
  作者：Yongjun Li、Ning Wang、Haiyang Gan、Huibiao Liu、Hao Li、Yuliang Li、Xiaorong He、Changshui Huang、Shuang Cui、Shu Wang、Daoben Zhu

  DOI：10.1021/jo051022c

  日期：2005.11.1

  New perylene bisimide dyes bearing 3,5-bis(2-hydroxyphenyl)-1,2,4-triazole receptor units with different spacers have been synthesized and characterized. The fluorescence and electronic properties of these compounds have been studied. MALDI-TOF, UV−vis, and fluorescence titration experiments proved that monotopic perylene bisimide ligands could be assembled into dimmers by FeIII coordination. The coordination

  合成并表征了带有3,5-双（2-羟苯基）-1,2,4-三唑受体单元的新型per双酰亚胺染料。已经研究了这些化合物的荧光和电子性质。MALDI-TOF，UV-vis和荧光滴定实验证明，单峰per双酰亚胺配体可以通过Fe III配位组装成二聚体。还已经初步研究了对位per联双酰亚胺配体的配位性能。此外，SEM图像表明，由于金属离子配位和per环的π-π堆积相互作用以及适当的间隔基的帮助，可以通过自组装来制备定义良好的纳米级结构。
• Multichromophoric dye-sensitized solar cells based on supramolecular zinc-porphyrin⋯perylene-imide dyads
  作者：Dillip K. Panda、Flynt S. Goodson、Shuvasree Ray、Rachel Lowell、Sourav Saha

  DOI：10.1039/c2cc33120a

  日期：——

  Multichromophoric dye-sensitized solar cells (DSCs) based on self-assembled zinc-porphyrin⋯peryleneimide dyads on TiO2 films display more efficient light-to-electrical energy conversion than DSCs based on individual dyes. Higher efficiency of multichromophoric dyes can be attributed to co-sensitization as well as vectorial electron transfer that lead to better electron–hole separation in the device.

  与基于单个染料的多色染料敏化太阳能电池相比，基于二氧化钛薄膜上自组装的锌-卟啉-苝酰亚胺染料的多色染料敏化太阳能电池（DSCs）显示出更高效的光-电能量转换。多色性染料的更高效率可归因于共敏化以及矢量电子传递，从而使装置中的电子-空穴分离更充分。