Cl2CHSC6H4OMe-p

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Cl2CHSC6H4OMe-p
• 英文别名: dichloromethyl-p-methoxyphenylsulfide；1-(Dichloromethylsulfanyl)-4-methoxybenzene
• 化学式: C₈H₈Cl₂OS
• 分子量: 223.123
• InChiKey: RSXWTBCESRFKDC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Cl2CHSC6H4OMe-p 、 Ru(η6-p.cymene)(η4-cycloocta-1,5-diene) 、 三环己基膦 以 苯 为溶剂， 反应 3.0h， 以80%的产率得到RuCl2(=C(H)SC6H4OMe-p)(PCy3)2
  参考文献：
  名称：

  PROCESS FOR SYNTHESIS OF ORGANOMETALLIC COMPOUNDS

  摘要：

  公开号：

  EP1431302B1

文献信息

• Process for synthesis of organometallic compounds
  申请人：Hiraike Hiroshi

  公开号：US20060030723A1

  公开（公告）日：2006-02-09

  A method for synthesizing an organometallic compound, which is usefully utilized as a catalyst for manufacturing polyolefins by ring-opening metathesis polymerization of an olefin having strain in a molecule such as dicyclopentadiene or synthesizing epothilones by ring-dosing metathesis reaction, by an efficient and low cost synthesis method using a starting material which is easily available due to relatively simple chemical structure, and further without any possibility of coexistence of a vinylhetero compound or a vinyl compound exchanged which tends to accompany as an impurity in the system in conventional methods, characterized by reacting a starting material comprising a zero-valent transition metal complex (A) or a polyvalent transition metal complex (A′), a compound (B) or (B′) shown by the following general formula (1) or (4), respectively, and a neutral ligand (C) or (C′), in one step under non-reducing condition or reducing condition. R 1 Y 1 CR 2 X 1 2 (1) R 4 Y 2 CR 5 X 2 2 (4)

  一种有机金属化合物的合成方法，该化合物可用作催化剂，通过分子中具有应变性的烯烃（如二环戊二烯）的开环偏聚合反应制造聚烯烃，或通过环配料偏聚合反应合成表噻吩酮，该方法采用高效、低成本的合成方法，使用的起始原料由于化学结构相对简单而易于获得、在传统方法中，乙烯基杂环化合物或交换的乙烯基化合物往往作为杂质存在于体系中，而本发明不存在这种可能性，其特征在于：使包含零价过渡金属络合物（A）或多价过渡金属络合物（A′）的起始原料发生反应、分别如下通式(1)或(4)所示的化合物(B)或(B′)和中性配体(C)或(C′)，在非还原条件或还原条件下一步反应。 R 1 Y 1 CR 2 X 1 2 (1) R 4 Y 2 CR 5 X 2 2 (4)
• Convenient Route to Fischer-Type Carbene Ruthenium Complexes:  Highly Selective Catalysts for Ring Opening/Cross-Metathesis of Norbornene Derivatives
  作者：Hiroyuki Katayama、Masato Nagao、Fumiyuki Ozawa

  DOI：10.1021/om020772z

  日期：2003.2.1

  The Fischer-type ruthenium carbene complexes RuCl2=C(H)ER}(PCy3)(2) (ER = SPh (1a), SC6H4Me-p (1b), SC6H4Cl-p (1c), SC6H4OMe-p (1d), SePh (1e)) have been prepared by the reactions of Ru(p-cymene)(cod), PCy3, and the corresponding dichloromethyl chalcogenides (Cl2CHER) in 47-80% yields. The starting Ru(p-cymene)(cod) is readily synthesized in high yield from [RuCl2(p-cymene)](2). The X-ray structures of 1b and 1e are reported. Complexes la and le serve as highly selective catalysts for ring opening/cross-metathesis of norbornene derivatives with vinyl chalcogenides.
• US7098355B2
  申请人：——

  公开号：US7098355B2

  公开（公告）日：2006-08-29