含α-氢-ω-羟基聚[氧(甲基-1,2-亚乙基)](氯甲基)环氧乙烷的聚合物

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 含α-氢-ω-羟基聚[氧(甲基-1,2-亚乙基)](氯甲基)环氧乙烷的聚合物
• 中文别名: 聚丙二醇(氯甲基)环氧乙烷聚合物；氯甲基环氧乙烷、环氧丙烷的共聚物
• 英文名称: 2-(Chloromethyl)oxirane;2-methyloxirane
• 英文别名: 2-(chloromethyl)oxirane;2-methyloxirane
• 化学式: C6H11ClO2
• 分子量: 150.6
• InChiKey: NOPSEWPTMVHNOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.03
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Process for producing polyether
  申请人：Miyanaga Seiichi

  公开号：US20050004344A1

  公开（公告）日：2005-01-06

  The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L 1 , L 2 and L 3 are same as or different from each other and each of them represents an oxygen-binding ligand.

  本发明提供了一种高效获得高聚度聚醚的方法，通过简单地聚合很难或迄今为止不能得到高聚度的取代环氧化物来提供高聚度聚醚。也就是说，通过在稀土金属化合物(I)和还原化合物的存在下，开环聚合至少一种取代环氧化物（丙烯酸丙烯酯和环氧氯丙烷除外）来获得聚醚：其中，M代表从Sc、Y和镧系元素中选择的稀土元素，L1、L2和L3相同或不同，每个代表一个氧结合配体。
• Process for cross-linking halogenated polymers
  申请人：HERCULES INCORPORATED

  公开号：EP0184212A2

  公开（公告）日：1986-06-11

  A cure system for halogen-containing polymers that comprises a thiourea derivative, a thiuram sulfide and an inorganic base yields stable cross-linked products with useful properties when incorporated into normal vulcanization procedures.

  含卤聚合物的固化体系由硫脲衍生物、硫酰胺硫化物和无机碱组成，可产生稳定的交联产品，并具有正常硫化程序的有用特性。
• Rubber composition
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0233520A1

  公开（公告）日：1987-08-26

  Disclosed is a rubber composition comprising 85 to 55 wt.% of copolymer rubber and 15 to 45 wt.% of chloroprene rubber, wherein the copolymer rubber comprises 10 to 60 mole % of epichlorohydrin, 30 to 90 mole % of propylene oxide or of propylene oxide and ethylene oxide and 0 to 15 mole % of unsaturated epoxide.

  公开了一种橡胶组合物，它包含 85 至 55 重量份的共聚橡胶和 15 至 45 重量份的氯丁橡胶，其中共聚橡胶包含 10 至 60 摩尔%的环氧氯丙烷、30 至 90 摩尔%的环氧丙烷或环氧丙烷和环氧乙烷以及 0 至 15 摩尔%的不饱和环氧化物。
• Cross-linking halogen-containing polymers
  申请人：HERCULES INCORPORATED

  公开号：EP0247888A1

  公开（公告）日：1987-12-02

  A cure system for halogen-containing polymers that comprises a thiourea, an inorganic activator, an inorganic acid acceptor, and optionally, an organic accelerator, which yields stable cross-linked products when incorporated into normal vulcanization procedures.

  一种用于含卤聚合物的固化体系，由硫脲、无机活化剂、无机酸接受体和有机促进剂组成，在纳入正常硫化程序时可产生稳定的交联产品。
• Electrically conductive rubber composition, transfer roller, and image forming apparatus
  申请人：SUMITOMO RUBBER INDUSTRIES, LTD.

  公开号：US10474068B2

  公开（公告）日：2019-11-12

  An inventive electrically conductive rubber composition contains: a rubber component including SBR and/or NBR, and 20 to 30 parts by mass of epichlorohydrin rubber based on 100 parts by mass of the overall rubber component; a crosslinking component; a foaming component; and a potassium salt of an anion having a fluoro group and a sulfonyl group in its molecule, the potassium salt being present in a proportion of not less than 0.01 part by mass and not greater than 1 part by mass based on 100 parts by mass of the overall rubber component. An inventive transfer roller (1) includes a roller body (2) formed from the electrically conductive rubber composition.

  本发明的导电橡胶组合物包含：橡胶成分，包括丁苯橡胶和/或丁腈橡胶，以及 20 至 30 质量份的环氧氯丙烷橡胶（以整个橡胶成分的 100 质量份为基准）；交联成分；发泡成分；以及分子中含有氟基和磺酰基的阴离子的钾盐，其中钾盐的存在比例不小于 0.01 质量份，但不大于 1 质量份（以整个橡胶成分的 100 质量份为基准）。本发明的转移辊（1）包括由导电橡胶组合物形成的辊体（2）。