2-phenyl-2H-tetrazol-5-amine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-phenyl-2H-tetrazol-5-amine
• 英文别名: 2-phenyl-2H-tetrazol-5-ylamine；2-Phenyl-2H-tetrazol-5-ylamin；5-Amino-2-phenyltetrazole；2-phenyltetrazol-5-amine
• 化学式: C₇H₇N₅
• 分子量: 161.166
• InChiKey: CCGRYVAYKAMETC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-phenyl-2H-tetrazol-5-amine 、 2-三氟甲基苯甲酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以59.7 mg的产率得到N-(2-phenyl-2H-tetrazol-5-yl)-2-(trifluoromethyl)benzamide
  参考文献：
  名称：

  HETEROCYCLIC COMPOUNDS AS PESTICIDES

  摘要：

  本申请涉及新颖的杂环化合物，其用于控制包括节肢动物、昆虫和线虫在内的动物害虫，并涉及用于制备这些新化合物的过程和中间体。

  公开号：

  US20170073318A1
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 作用下， 生成 2-phenyl-2H-tetrazol-5-amine
  参考文献：
  名称：

  Stolle; Orth, Chemische Berichte, 1925, vol. 58, # 2103, p. 2104

  摘要：

  DOI：

文献信息

• <i>N</i>-Iodosuccinimide-Promoted [3 + 2] Annulation Reaction of Aryldiazonium Salts with Guanidines To Construct Aminotetrazoles
  作者：Yi-Lin Yang、Shen Li、Fa-Guang Zhang、Jun-An Ma

  DOI：10.1021/acs.orglett.1c03395

  日期：2021.11.19

  A N-iodosuccinimide (NIS)-promoted [3 + 2] annulation reaction of aryldiazonium salts with guanidines has been developed for the construction of previously elusive 2-aryl-5-amino-2H-tetrazoles. This transformation takes advantage of readily available starting materials, proceeds under metal-free, mild, and robust conditions, and holds broad functional group compatibility. The utility of this protocol

  甲Ñ碘代丁二酰亚胺（NIS）促进的[3 + 2]胍芳基重氮盐的环反应已为先前的难以捉摸的2-芳基-5-氨基-2-施工开发ħ -tetrazoles。这种转化利用容易获得的起始材料，在无金属、温和且稳定的条件下进行，并具有广泛的官能团兼容性。该协议的效用通过耦合、环化、脱氨基和脱氮衍生化得到进一步体现。
• KNOWN AND NEW HETEROCYCLIC COMPOUNDS AS PEST CONTROL AGENTS
  申请人：BAYER CROPSCIENCE AKTIENGESELLSCHAFT

  公开号：US20160106102A1

  公开（公告）日：2016-04-21

  The present application relates to the use of known and novel heterocyclic compounds for controlling animal pests, to novel heterocyclic compounds, to processes for preparation thereof and to the use thereof for controlling animal pests.

  本申请涉及使用已知和新型杂环化合物来控制动物害虫，涉及新型杂环化合物，其制备方法以及用于控制动物害虫的使用方法。
• Photopolymerizable resin composition and gold plating method using same
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0372944A2

  公开（公告）日：1990-06-13

  Disclosed is a photopolymerizable resin composition consisting essentially of (A) 40 to 70 parts by weight of a thermoplastic polymer binder obtained by copolymerizing 3 to 30% by weight of a styrene type constituent, 15 to 45% by weight of an acrylate type constituent, 25 to 60% by weight of a methacrylate type constituent, and 15 to 35% by weight of a carboxylic acid type constituent, the thermoplastic polymer binder having a Tg of 60 to 100°C; (B) 25 to 50 parts by weight of a crosslinkable monomer comprising one or more compounds having one or more ethylenically unsaturated groups in the molecule and containing not less than 5% by weight of one or more compounds having one or more hydroxyl groups and two or more ethylenically unsaturated groups in the molecule; and (C) 0 to 10 parts by weight of a photopolymerization initiator; the combined amount of components (A) to (C) being 100 parts by weight.

  本发明公开了一种可光聚合的树脂组合物，其主要成分包括 (A) 40 至 70 份(重量)的热塑性聚合物粘合剂，该粘合剂是由 3 至 30% (重量)的苯乙烯类成分、15 至 45% (重量)的丙烯酸酯类成分、25 至 60% (重量)的甲基丙烯酸酯类成分和 15 至 35% (重量)的羧酸类成分共聚而成，该热塑性聚合物粘合剂的 Tg 为 60 至 100°C； (B) 25 至 50 份(重量)的可交联单体，该单体由分子中含有一个或多个乙 烯不饱和基团的一种或多种化合物组成，并含有不少于 5%(重量)的分子 中含有一个或多个羟基和两个或多个乙烯不饱和基团的一种或多种化 合物；以及 (C) 0 至 10 重量份的光聚合引发剂； 组分(A)至(C)的总用量为 100 重量份。
• Photocross-linkable resin compositions and their use in the manufacture of dry film resists
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0429279A1

  公开（公告）日：1991-05-29

  There is described a photopolymerizable cross-­linkable hardenable resin composition which comprises binder resin, cross-linking monomer and photopolymerization initiator. The compositions of each of these components is such that the resin composition can be used for the production of dry film resists having excellent handling and storage properties using weak aqueous alkali after selective exposure to light. Such resists can be selectively etched or plated for the efficient and economical manufacture of high definition printed circuit boards.

  本文描述了一种可光聚合交联硬化树脂组合物，它由粘合剂树脂、交联单体和光聚合引发剂组成。其中每种成分的组成使得该树脂组合物可用于生产干膜抗蚀剂，这种抗蚀剂在选择性暴露于光线后，可使用弱水碱，具有极佳的处理和储存性能。这种抗蚀剂可以选择性地蚀刻或电镀，从而高效经济地制造高清晰度印刷电路板。
• Crosslinking curable resin composition
  申请人：MITSUBISHI RAYON CO., LTD

  公开号：EP0589109A1

  公开（公告）日：1994-03-30

  A photopolymerizable or radiation polymerizable alkaline developing crosslinking curable resin composition possessing superior antiplating properties and a short stripping period, in which the stripped plate is not easily dissolved in the stripping fluid, and which is comprising: (a) 5-30 parts by weight of at least one compound possessing in one molecule on the average 1.5 or more (meth)acryloyloxy groups, which is obtained by reacting (meth)acrylic acid with a reaction product formed by adding, to a polyatomic alcohol possessing 3 or more OH groups in one molecule, an alkylene oxide containing propylene oxide in an amount of 67% molar or greater in an amount of 5-12 moles per mole of OH group in the aforementioned polyatomic alcohol, (b) 5-30 parts by weight of at least one crosslinkable monomer other than that stated above in (a), possessing in one molecule 2 or more ethylenically unsaturated groups, (c) 45-75 parts by weight of a thermoplastic polymer for use as a binder, the thermoplastic polymer in turn being formed of 15-35 wt % of at least one α,β-unsaturated carboxyl group containing a monomer having 3-15 carbon atoms, and 65-85 wt % of another copolymerizable monomer, and (d) 0-10 parts by weight of a photopolymerization initiator.

  一种可光聚合或可辐射聚合的碱性显影交联固化树脂组合物，具有优异的防电镀性能和较短的剥离周期，剥离后的板材不易溶解在剥离液中，它包括 (a) 5-30 份（按重量计）至少一种化合物，其分子中平均含有 1.5 个或更多的（甲 基）丙烯酰氧基，该化合物是通过将（甲基）丙烯酸与一种反应产物反应而得，该 反应产物是通过向一种分子中含有 3 个或更多羟基的多原子醇中加入一种含氧 化丙烯的环氧烷，其摩尔量为 67%或更高，在上述多原子醇中每摩尔羟基的 含量为 5-12 摩尔、 (b) 5-30 份(重量)除上述(a)所述单体外的至少一种可交联单体，其一个分子中 具有 2 个或 2 个以上乙烯不饱和基团、 (c) 45-75 重量份用作粘合剂的热塑性聚合物，该热塑性聚合物又是由 15-35 重量份含有 3-15 个碳原子的单体的至少一个α，β-不饱和羧基和 65-85 重量份另一种可共聚的单体组成，以及 (d) 0-10 重量份的光聚合引发剂。