diethyl (Z)-pentylmaleate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: diethyl (Z)-pentylmaleate
• 英文别名: diethyl (Z)-2-pentylbut-2-enedioate
• 化学式: C₁₃H₂₂O₄
• 分子量: 242.315
• InChiKey: FOCVPBCYBCRXFC-KHPPLWFESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  乙醇 、 1-庚炔 、 一氧化碳 在 sodium acetate 、 copper dichloride 、 palladium dichloride 作用下， 以 苯 为溶剂， 20.0 ℃ 、101.32 kPa 条件下， 反应 2.0h， 以70.2%的产率得到diethyl (Z)-pentylmaleate
  参考文献：
  名称：

  A Novel Stereoselective Synthesis of Maleate Derivatives via Palladium-Catalyzed Dicarboalkoxylation of Terminal Alkynes

  摘要：

  Alkynes were dicarboalkoxylated efficiently and stereoselectively in high yields reacting for about 2h under atmospheric pressure of carbon monoxide at room temperature using a catalytic amount of PdCl2 and a stoichiometric amount of CuCl2.

  DOI：

  10.1080/00397919908086012

文献信息

• Components and catalysts for the polymerization of olefins
  申请人：——

  公开号：US20040014595A1

  公开（公告）日：2004-01-22

  The present invention relates to a solid catalyst component for the polymerization of olefins CH 2 ═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from maleates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

  本发明涉及一种用于聚合烯烃CH2═CHR的固体催化剂组分，其中R是氢或具有1-12个碳原子的碳氢基团，包括Mg、Ti、卤素和从特定公式的马来酸酯中选择的电子给体。当在聚合烯烃，特别是丙烯的聚合中使用该催化剂组分时，能够以高收率和高异构指数的形式给出聚合物，该异构指数以高二甲苯不溶性表示。
• Internal electron donor compound for preparing α-olefin polymerization catalyst component
  申请人：YINGKOU XIANGYANG CATALYST CO., LTD

  公开号：US10287371B2

  公开（公告）日：2019-05-14

  An internal electron donor compound for preparing α-olefin polymerization catalyst component, including two kinds of electron donors; the proportion of the two kinds of electron donors in the compounding preparation of the catalyst is determined via designed experiments so as to obtain a catalyst component having good comprehensive performance or a particular performance. The electron donor compound of the present invention can be used in the preparation of α-olefin polymerization and co-polymerization catalyst component, particular the preparation of propylene polymerization catalyst component, and is applicable to prepare the propylene polymerization catalyst component by reacting magnesium chloride-ethanols complex compound carrier with titanium tetrachloride and electron donors, or to directly prepare the propylene polymerization catalyst component by reacting magnesium chloride, alcohols, titanium tetrachloride, and internal electron donor. In addition, also provided is a theoretical basis for selecting a proper electron donor combination from a plurality of electron donors.

  一种用于制备α-烯烃聚合催化剂组分的内部电子供体化合物，包括两种电子供体；通过设计实验确定两种电子供体在催化剂复配制备中的比例，以获得综合性能良好或具有特定性能的催化剂组分。本发明的电子供体化合物可用于制备α-烯烃聚合和共聚合催化剂组分，特别是丙烯聚合催化剂组分的制备，适用于氯化镁-乙醇复合物载体与四氯化钛和电子供体反应制备丙烯聚合催化剂组分，或直接由氯化镁、醇类、四氯化钛和内部电子供体反应制备丙烯聚合催化剂组分。此外，还提供了从多种电子供体中选择合适的电子供体组合的理论依据。
• COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
  申请人：Basell Poliolefine Italia S.p.A.

  公开号：EP1425317A1

  公开（公告）日：2004-06-09
• Internal Electron Donor Compound for Preparing Alpha-olefin Polymerization Catalyst Component
  申请人：YINGKOU XIANGYANG CATALYST CO., LTD

  公开号：US20160229935A1

  公开（公告）日：2016-08-11

  An internal electron donor compound for preparing α-olefin polymerization catalyst component, including two kinds of electron donors; the proportion of the two kinds of electron donors in the compounding preparation of the catalyst is determined via designed experiments so as to obtain a catalyst component having good comprehensive performance or a particular performance. The electron donor compound of the present invention can be used in the preparation of α-olefin polymerization and co-polymerization catalyst component, particular the preparation of propylene polymerization catalyst component, and is applicable to prepare the propylene polymerization catalyst component by reacting magnesium chloride-ethanols complex compound carrier with titanium tetrachloride and electron donors, or to directly prepare the propylene polymerization catalyst component by reacting magnesium chloride, alcohols, titanium tetrachloride, and internal electron donor. In addition, also provided is a theoretical basis for selecting a proper electron donor combination from a plurality of electron donors.
• INTERNAL ELECTRON DONOR COMPOUND FOR PREPARING ALPHA-OLEFIN POLYMERIZATION CATALYST COMPONENT
  申请人：YINGKOU XIANGYANG CATALYST CO., LTD

  公开号：US20190218317A1

  公开（公告）日：2019-07-18

  An internal electron donor compound for preparing a-olefin polymerization catalyst component, including two kinds of electron donors; the proportion of the two kinds of electron donors in the compounding preparation of the catalyst is determined via designed experiments so as to obtain a catalyst component having good comprehensive performance or a particular performance. The electron donor compound of the present invention can be used in the preparation of a-olefin polymerization and co-polymerization catalyst component, particular the preparation of propylene polymerization catalyst component, and is applicable to prepare the propylene polymerization catalyst component by reacting magnesium chloride-ethanolscomlex compound carrier with titanium tetrachloride and electron donors, or to directly prepare the propylene polymerization catalyst component by reacting magnesium chloride, alcohols, titanium tetrachloride, and internal electron donor. In addition, also provided is a theoretical basis for selecting a proper electron donor combination from a plurality of electron donors.