diethylaminopropenoic acid ethyl ester

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diethylaminopropenoic acid ethyl ester
• 英文别名: Ethyl 2-(diethylamino)prop-2-enoate
• 化学式: C₉H₁₇NO₂
• 分子量: 171.239
• InChiKey: KOBFVDUIRINIKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  diethylaminopropenoic acid ethyl ester 在 三乙基硅烷 、 叔丁基(氯)汞 、 sodium thiosulfate 作用下， 生成 ethyl 2-diethylaminopropanoate
  参考文献：
  名称：

  Russell, Glen A.; Shi, Bing Zhi; Jiang, Wan, Journal of the American Chemical Society, 1995, vol. 117, # 14, p. 3952 - 3962

  摘要：

  DOI：

文献信息

• ETHERIC (ETHEREAL) OXYGEN ATOM-CONTAINING PERFLUOROALKYL GROUP-SUBSTITUTED PYRIMIDINE RING COMPOUND, AND METHOD FOR ITS PRODUCTION
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20170050934A1

  公开（公告）日：2017-02-23

  To provide a pyrimidine derivative having a fluorinated substituent group, that can be applied to an agricultural chemical or pharmaceutical having excellent pharmacological activities, and a method for producing said derivative. A compound represented by the following formula (A). R f is a group having an etheric (ethereal) oxygen atom inserted between carbon-carbon atoms in a C 2-19 perfluoroalkyl group, wherein the total of the number of carbon atoms and the number of oxygen atoms is from 3 to 20. R 1 is a C 1-6 alkyl group, etc. Q 1 is R 2 C(O)—, R 3 OC(O)—, a carboxy group, R 4 OC(O)NH—, an amino group, or R 5 C(O)NH—(R 2 to R 5 are each independently a C 1-6 alkyl group, etc.).

  提供一种具有氟代取代基的嘧啶衍生物，可应用于具有优异药理活性的农药或药物，并提供一种制备该衍生物的方法。以下是表示的化合物（A）的公式。Rf是一个在C2-19全氟烷基中的碳-碳原子之间插入了醚氧原子的基团，其中碳原子数和氧原子数的总和为3到20。R1是C1-6烷基基团等。Q1是R2C(O)—，R3OC(O)—，一个羧基，R4OC(O)NH—，一个氨基，或R5C(O)NH—（R2到R5分别是独立的C1-6烷基基团等）。
• Photosensitive compositions containing carbonylic halides as activators
  申请人：Dynachem Corporation

  公开号：EP0005379A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component. a photoinitiator, a colorformer capable of changing color upon contact with a suitable activator and a latent activator containing an organic halide will become insoluble and change color under the influence of actinic radiation. The organic halide is a carbonylic compound such as an aliphatic or cycloaliphatic ketone or an ester or amide of a dicarboxylic acid. The compositions are useful to make resists used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、与适当活化剂接触后能变色的着色剂和含有有机卤化物的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并变色。 有机卤化物是一种羰基化合物，如脂肪族或环脂族酮或二羧酸的酯或酰胺。 这些组合物可用于制造电子工业中用于制造印刷电路的抗蚀剂。
• Phototropic photosensitive compositions containing a fluoran colorformer
  申请人：Dynachem Corporation

  公开号：EP0005380A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component, a photoinitiator, a fluoran colorformer and a latent activator that releases or promotes the release of a Lewis acid, will become insoluble and change color under the influence of actinic radiation. These compositions are particularly useful to make dry film photoresists, which are widely used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、荧光显色剂和可释放或促进释放路易斯酸的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并改变颜色。这些成分特别适用于制造干膜光阻，干膜光阻在电子工业中广泛用于制造印刷电路。
• Porous inorganic support material coated with an organic stationary phase, for use in chromatography, and process for its preparation
  申请人：AKZO N.V.

  公开号：EP0043159A1

  公开（公告）日：1982-01-06

  The invention relates to support material usable as such in chromatography or as a starting material which, upon linkage to it of compounds containing ionic groups, ligands or biomacromolecules, can be used as ion exchanger, as a medium in affinity chromatography or in enzymatic reactions and consists of porous, inorganic silanized particles onto which there is covalently bonded an organic, stationary phase built up of (co)polymerized vinyl monomers containing amide groups, said inorganic particles having been silanized with an organo silane of the formula I wherein n = 1-5; R, is halogen or alkoxy (1-10 C); R2 and R3 are each halogen, alkoxy (1-10 C), alkyl (1-3 C) or aryl (6-10 C), the halogen and alkoxy group in R1, R2 and R3 being capable of forming an -0-Si-bond between the silane and the inorganic material through its surface hydroxyl groups; and R4 is amino, substituted amino, such as w-amino-alkyl (1-3 C)-amino, mercapto, an ester group or glycidoxy; and the organic stationary phase being a crosslinked (co)polymer obtained by addition polymerization and built up of 0.1 to 140 µmoles vinyl monomers per m2 inorganic surface of the support material, said (co)polymer containing at least 0.1 µmoles amide groups per m2 inorganic surface of the support material, said vinyl monomers consisting wholly or partly of bifunctional vinyl monomers containing amide groups and having the formula II wherein R5 and R6 each are hydrogen or an organic group having up to 18 carbon atoms; R7 is hydrogen or an organic group up to 20 carbon atoms; and m is an integer from 1 to 20.

  本发明涉及可用于色谱法的支撑材料或作为起始材料的支撑材料，在与含有离子基团、配体或生物大分子的化合物连接后，可用作离子交换剂、亲和色谱法或酶反应中的介质，它由多孔的无机硅烷化颗粒组成、无机硅烷化颗粒，其上共价键合了由含酰胺基团的（共）聚合乙烯基单体构成的有机固定相，所述无机颗粒已被式 I 的有机硅烷硅烷化。 其中 n = 1-5；R，是卤素或烷氧基（1-10 C）；R2 和 R3 分别是卤素、烷氧基（1-10 C）、烷基（1-3 C）或芳基（6-10 C），R1、R2 和 R3 中的卤素和烷氧基能通过硅烷表面的羟基在硅烷和无机材料之间形成-0-硅键；而 R4 是氨基、取代氨基，如 w-氨基-烷基（1-3 C）-氨基、巯基、酯基或缩水甘油醚；有机固定相是通过加成聚合得到的交联（共）聚合物，由 0.1 至 140 微摩尔乙烯基单体组成，所述（共）聚合物每平方米无机表面至少含有 0.1 微摩尔酰胺基团，所述乙烯基单体全部或部分由含有酰胺基团的双官能团乙烯基单体组成，具有式 II 其中 R5 和 R6 分别为氢或最多具有 18 个碳原子的有机基团；R7 为氢或最多具有 20 个碳原子的有机基团；m 为 1 至 20 的整数。
• Prepasted wallcoverings
  申请人：ALLIED COLLOIDS LIMITED

  公开号：EP0159132A1

  公开（公告）日：1985-10-23

  A wallcovering comprises a substrate carrying a water-moistenable coating formed of at least two layers. The layer adjacent to the substrate generally comprises unswollen particles of an anionic polymer that is substantially non-swellable in water and that is swellable in aqueous alkali and the upper layer contains an alkali which on contact with water forms an alkaline solution which swells the anionic polymer and a water soluble cationic polymer. The anionic polymer generally comprises beads of cross-linked copolymers of lower alkyl acrylates and methacrylic acid having a molecular weight of about 5 million. Processes for producing the wallcoverings comprise coating the substrate separately with an aqueuous dispersion of the anionic polymer and an aqueous solution containing both the cationic polymer and the alkaline material to give at least two separate layers.

  一种墙面材料包括一个基材，基材上有一层至少由两层组成的水润涂层。与基材相邻的一层一般由阴离子聚合物的未溶胀颗粒组成，这种聚合物在水中基本不溶胀，但在水碱中可溶胀，上层含有碱，与水接触后形成碱性溶液，使阴离子聚合物和水溶性阳离子聚合物溶胀。阴离子聚合物一般由分子量在 500 万左右的低级烷基丙烯酸酯和甲基丙烯酸交联共聚物组成。生产墙衣的工艺包括用阴离子聚合物的水性分散体和含有阳离子聚合物和碱性材料的水溶液分别涂覆基材，以得到至少两层独立的涂层。