1,8-diphenyl-N-methyl-15-oxahexacyclo[6.6.1.1^2,5.1^4,7.0^2,7.0^9,14]heptadeca-9,11,13-triene-4,5-dicarboximide

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,8-diphenyl-N-methyl-15-oxahexacyclo[6.6.1.1^2,5.1^4,7.0^2,7.0^9,14]heptadeca-9,11,13-triene-4,5-dicarboximide
• 化学式: C₃₁H₂₅NO₃
• 分子量: 459.544
• InChiKey: UXRKGIBZYBWNGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.76
• 重原子数：
  35.0
• 可旋转键数：
  2.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  46.61
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  3,7-diiodotricyclo[3.3.0.0^3,7]octane-1,5-dicarboximide 在 叔丁基锂 、 sodium hydride 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 反应 16.0h， 生成 1,8-diphenyl-N-methyl-15-oxahexacyclo[6.6.1.1^2,5.1^4,7.0^2,7.0^9,14]heptadeca-9,11,13-triene-4,5-dicarboximide
  参考文献：
  名称：

  Generation and trapping of tricyclo[3.3.0.03,7]oct-1(5)-ene derivatives containing carbonyl functionalities

  摘要：

  Two new functionalized highly pyramidalized tricyclo[3.3.0.0(3,7)]oct 1(5)-ene derivatives containing carbonyl functionalities have been trapped as Diels-Alder adducts, although they failed to dimerize. An interesting fragmentation of the bisnoradamantane skeleton to norbornane derivatives has also been observed. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.05.074

文献信息

• Generation and trapping of tricyclo[3.3.0.03,7]oct-1(5)-ene derivatives containing carbonyl functionalities
  作者：Pelayo Camps、M. Rosa Muñoz、Santiago Vázquez

  DOI：10.1016/j.tet.2006.05.074

  日期：2006.8

  Two new functionalized highly pyramidalized tricyclo[3.3.0.0(3,7)]oct 1(5)-ene derivatives containing carbonyl functionalities have been trapped as Diels-Alder adducts, although they failed to dimerize. An interesting fragmentation of the bisnoradamantane skeleton to norbornane derivatives has also been observed. (c) 2006 Elsevier Ltd. All rights reserved.